Crystal structure of chlorido­{4,5-dimeth­oxy-2-[(2,3-η)-2-prop-2-en-1-yl]phenyl-κC (1)}(piperidine-κN)platinum(II) ethanol monosolvate

In the title compound, [Pt(C(11)H(13)O(2))Cl(C(5)H(11)N)]·C(2)H(5)OH, the Pt(II) cation is penta­coordinated in a distorted square-planar geometry. In the crystal, inversion dimers showing C—H⋯Cl and C—H⋯π inter­actions are further stacked in columns along the a axis via C—H⋯π inter­actions. The eth...

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Autores principales: Mangwala Kimpende, Peter, Thi Da, Tran, Nguyen Huu, Dinh, Van Meervelt, Luc
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257290/
https://www.ncbi.nlm.nih.gov/pubmed/25484767
http://dx.doi.org/10.1107/S1600536814023575
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author Mangwala Kimpende, Peter
Thi Da, Tran
Nguyen Huu, Dinh
Van Meervelt, Luc
author_facet Mangwala Kimpende, Peter
Thi Da, Tran
Nguyen Huu, Dinh
Van Meervelt, Luc
author_sort Mangwala Kimpende, Peter
collection PubMed
description In the title compound, [Pt(C(11)H(13)O(2))Cl(C(5)H(11)N)]·C(2)H(5)OH, the Pt(II) cation is penta­coordinated in a distorted square-planar geometry. In the crystal, inversion dimers showing C—H⋯Cl and C—H⋯π inter­actions are further stacked in columns along the a axis via C—H⋯π inter­actions. The ethanol solvate mol­ecule inter­acts with neighbouring meth­oxy groups of methyl­eugenol through O—H⋯O hydrogen bonds.
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spelling pubmed-42572902014-12-05 Crystal structure of chlorido­{4,5-dimeth­oxy-2-[(2,3-η)-2-prop-2-en-1-yl]phenyl-κC (1)}(piperidine-κN)platinum(II) ethanol monosolvate Mangwala Kimpende, Peter Thi Da, Tran Nguyen Huu, Dinh Van Meervelt, Luc Acta Crystallogr Sect E Struct Rep Online Research Communications In the title compound, [Pt(C(11)H(13)O(2))Cl(C(5)H(11)N)]·C(2)H(5)OH, the Pt(II) cation is penta­coordinated in a distorted square-planar geometry. In the crystal, inversion dimers showing C—H⋯Cl and C—H⋯π inter­actions are further stacked in columns along the a axis via C—H⋯π inter­actions. The ethanol solvate mol­ecule inter­acts with neighbouring meth­oxy groups of methyl­eugenol through O—H⋯O hydrogen bonds. International Union of Crystallography 2014-10-31 /pmc/articles/PMC4257290/ /pubmed/25484767 http://dx.doi.org/10.1107/S1600536814023575 Text en © Mangwala Kimpende et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Mangwala Kimpende, Peter
Thi Da, Tran
Nguyen Huu, Dinh
Van Meervelt, Luc
Crystal structure of chlorido­{4,5-dimeth­oxy-2-[(2,3-η)-2-prop-2-en-1-yl]phenyl-κC (1)}(piperidine-κN)platinum(II) ethanol monosolvate
title Crystal structure of chlorido­{4,5-dimeth­oxy-2-[(2,3-η)-2-prop-2-en-1-yl]phenyl-κC (1)}(piperidine-κN)platinum(II) ethanol monosolvate
title_full Crystal structure of chlorido­{4,5-dimeth­oxy-2-[(2,3-η)-2-prop-2-en-1-yl]phenyl-κC (1)}(piperidine-κN)platinum(II) ethanol monosolvate
title_fullStr Crystal structure of chlorido­{4,5-dimeth­oxy-2-[(2,3-η)-2-prop-2-en-1-yl]phenyl-κC (1)}(piperidine-κN)platinum(II) ethanol monosolvate
title_full_unstemmed Crystal structure of chlorido­{4,5-dimeth­oxy-2-[(2,3-η)-2-prop-2-en-1-yl]phenyl-κC (1)}(piperidine-κN)platinum(II) ethanol monosolvate
title_short Crystal structure of chlorido­{4,5-dimeth­oxy-2-[(2,3-η)-2-prop-2-en-1-yl]phenyl-κC (1)}(piperidine-κN)platinum(II) ethanol monosolvate
title_sort crystal structure of chlorido­{4,5-dimeth­oxy-2-[(2,3-η)-2-prop-2-en-1-yl]phenyl-κc (1)}(piperidine-κn)platinum(ii) ethanol monosolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257290/
https://www.ncbi.nlm.nih.gov/pubmed/25484767
http://dx.doi.org/10.1107/S1600536814023575
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