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Crystal structure of 1,1′-bis[1,7-dicarba-closo-dodeca­borane(11)]

In the title compound, C(4)H(22)B(20), the two {1,7-closo-C(2)B(10)H(11)} cages are linked across a centre of inversion, with C—C = 1.5401 (16) Å. The position of the second non-linking cage C atom was established unambiguously by geometric and crystallographic methods and there is no evidence of C/...

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Detalles Bibliográficos
Autores principales: Elrick, Lisa, Rosair, Georgina M., Welch, Alan J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257294/
https://www.ncbi.nlm.nih.gov/pubmed/25484750
http://dx.doi.org/10.1107/S1600536814022132
Descripción
Sumario:In the title compound, C(4)H(22)B(20), the two {1,7-closo-C(2)B(10)H(11)} cages are linked across a centre of inversion, with C—C = 1.5401 (16) Å. The position of the second non-linking cage C atom was established unambiguously by geometric and crystallographic methods and there is no evidence of C/B disorder.