Crystal structure of 1,1′-bis[1,7-dicarba-closo-dodeca­borane(11)]

In the title compound, C(4)H(22)B(20), the two {1,7-closo-C(2)B(10)H(11)} cages are linked across a centre of inversion, with C—C = 1.5401 (16) Å. The position of the second non-linking cage C atom was established unambiguously by geometric and crystallographic methods and there is no evidence of C/...

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Detalles Bibliográficos
Autores principales: Elrick, Lisa, Rosair, Georgina M., Welch, Alan J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257294/
https://www.ncbi.nlm.nih.gov/pubmed/25484750
http://dx.doi.org/10.1107/S1600536814022132
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author Elrick, Lisa
Rosair, Georgina M.
Welch, Alan J.
author_facet Elrick, Lisa
Rosair, Georgina M.
Welch, Alan J.
author_sort Elrick, Lisa
collection PubMed
description In the title compound, C(4)H(22)B(20), the two {1,7-closo-C(2)B(10)H(11)} cages are linked across a centre of inversion, with C—C = 1.5401 (16) Å. The position of the second non-linking cage C atom was established unambiguously by geometric and crystallographic methods and there is no evidence of C/B disorder.
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spelling pubmed-42572942014-12-05 Crystal structure of 1,1′-bis[1,7-dicarba-closo-dodeca­borane(11)] Elrick, Lisa Rosair, Georgina M. Welch, Alan J. Acta Crystallogr Sect E Struct Rep Online Research Communications In the title compound, C(4)H(22)B(20), the two {1,7-closo-C(2)B(10)H(11)} cages are linked across a centre of inversion, with C—C = 1.5401 (16) Å. The position of the second non-linking cage C atom was established unambiguously by geometric and crystallographic methods and there is no evidence of C/B disorder. International Union of Crystallography 2014-10-24 /pmc/articles/PMC4257294/ /pubmed/25484750 http://dx.doi.org/10.1107/S1600536814022132 Text en © Elrick et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Elrick, Lisa
Rosair, Georgina M.
Welch, Alan J.
Crystal structure of 1,1′-bis[1,7-dicarba-closo-dodeca­borane(11)]
title Crystal structure of 1,1′-bis[1,7-dicarba-closo-dodeca­borane(11)]
title_full Crystal structure of 1,1′-bis[1,7-dicarba-closo-dodeca­borane(11)]
title_fullStr Crystal structure of 1,1′-bis[1,7-dicarba-closo-dodeca­borane(11)]
title_full_unstemmed Crystal structure of 1,1′-bis[1,7-dicarba-closo-dodeca­borane(11)]
title_short Crystal structure of 1,1′-bis[1,7-dicarba-closo-dodeca­borane(11)]
title_sort crystal structure of 1,1′-bis[1,7-dicarba-closo-dodeca­borane(11)]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257294/
https://www.ncbi.nlm.nih.gov/pubmed/25484750
http://dx.doi.org/10.1107/S1600536814022132
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AT rosairgeorginam crystalstructureof11bis17dicarbaclosododecaborane11
AT welchalanj crystalstructureof11bis17dicarbaclosododecaborane11

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