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Crystal structure of bis{2-[bis(2-hydroxyethyl)amino]ethanol-κ(3) O,N,O′}zinc terephthalate
In the title salt, [Zn(C(6)H(15)NO(3))(2)](C(8)H(4)O(4)), the Zn(II) cation, located on a centre of inversion, is coordinated by four O atoms and two N atoms from two tridentate 2-[bis(2-hydroxyethyl)amino]ethanol (BHEA) ligands, giving rise to a slightly distorted octahedral geometry. The ter...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257296/ https://www.ncbi.nlm.nih.gov/pubmed/25484775 http://dx.doi.org/10.1107/S1600536814021771 |
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| author | Li, Ya-Ping Zang, Hu Sun, Dajun Ming, Julia Su, Guan-Fang |
| author_facet | Li, Ya-Ping Zang, Hu Sun, Dajun Ming, Julia Su, Guan-Fang |
| author_sort | Li, Ya-Ping |
| collection | PubMed |
| description | In the title salt, [Zn(C(6)H(15)NO(3))(2)](C(8)H(4)O(4)), the Zn(II) cation, located on a centre of inversion, is coordinated by four O atoms and two N atoms from two tridentate 2-[bis(2-hydroxyethyl)amino]ethanol (BHEA) ligands, giving rise to a slightly distorted octahedral geometry. The terephthalate dianion, located about a centre of inversion, is not coordinated to Zn(II) but is connected through O—H⋯O contacts with [Zn(BHEA)(2)](2+) cations, leading to a three-dimensional crystal structure. |
| format | Online Article Text |
| id | pubmed-4257296 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-42572962014-12-05 Crystal structure of bis{2-[bis(2-hydroxyethyl)amino]ethanol-κ(3) O,N,O′}zinc terephthalate Li, Ya-Ping Zang, Hu Sun, Dajun Ming, Julia Su, Guan-Fang Acta Crystallogr Sect E Struct Rep Online Data Reports In the title salt, [Zn(C(6)H(15)NO(3))(2)](C(8)H(4)O(4)), the Zn(II) cation, located on a centre of inversion, is coordinated by four O atoms and two N atoms from two tridentate 2-[bis(2-hydroxyethyl)amino]ethanol (BHEA) ligands, giving rise to a slightly distorted octahedral geometry. The terephthalate dianion, located about a centre of inversion, is not coordinated to Zn(II) but is connected through O—H⋯O contacts with [Zn(BHEA)(2)](2+) cations, leading to a three-dimensional crystal structure. International Union of Crystallography 2014-10-11 /pmc/articles/PMC4257296/ /pubmed/25484775 http://dx.doi.org/10.1107/S1600536814021771 Text en © Li et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Data Reports Li, Ya-Ping Zang, Hu Sun, Dajun Ming, Julia Su, Guan-Fang Crystal structure of bis{2-[bis(2-hydroxyethyl)amino]ethanol-κ(3) O,N,O′}zinc terephthalate |
| title | Crystal structure of bis{2-[bis(2-hydroxyethyl)amino]ethanol-κ(3)
O,N,O′}zinc terephthalate |
| title_full | Crystal structure of bis{2-[bis(2-hydroxyethyl)amino]ethanol-κ(3)
O,N,O′}zinc terephthalate |
| title_fullStr | Crystal structure of bis{2-[bis(2-hydroxyethyl)amino]ethanol-κ(3)
O,N,O′}zinc terephthalate |
| title_full_unstemmed | Crystal structure of bis{2-[bis(2-hydroxyethyl)amino]ethanol-κ(3)
O,N,O′}zinc terephthalate |
| title_short | Crystal structure of bis{2-[bis(2-hydroxyethyl)amino]ethanol-κ(3)
O,N,O′}zinc terephthalate |
| title_sort | crystal structure of bis{2-[bis(2-hydroxyethyl)amino]ethanol-κ(3)
o,n,o′}zinc terephthalate |
| topic | Data Reports |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257296/ https://www.ncbi.nlm.nih.gov/pubmed/25484775 http://dx.doi.org/10.1107/S1600536814021771 |
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