Cargando…
Crystal structure of N,N-diethylbenzene-1,4-diaminium dinitrate
In the structure of the title molecular salt, C(10)H(18)N(2) (2+)·2NO(3) (−), the dinitrate salt of 4-(N,N-diethylamino)aniline, the two ethyl groups lie almost perpendicular to the plane of the benzene ring [the ring-to-ethyl C—C—N—C torsion angles are −59.5 (2) and 67.5 (3)°]. The aminium grou...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257297/ https://www.ncbi.nlm.nih.gov/pubmed/25484823 http://dx.doi.org/10.1107/S1600536814022946 |
Sumario: | In the structure of the title molecular salt, C(10)H(18)N(2) (2+)·2NO(3) (−), the dinitrate salt of 4-(N,N-diethylamino)aniline, the two ethyl groups lie almost perpendicular to the plane of the benzene ring [the ring-to-ethyl C—C—N—C torsion angles are −59.5 (2) and 67.5 (3)°]. The aminium groups of the cation form inter-species N—H⋯O hydrogen bonds with the nitro O-atom acceptors of both anions, giving rise to chain substructures lying along c. The chains are linked via further N—H⋯O hydrogen bonds, forming two-dimensional networks lying parallel to (010). These sheets are linked by C—H⋯O hydrogen bonds, forming a three-dimensional structure. |
---|