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Crystal structure of N,N-diethylbenzene-1,4-diaminium dinitrate
In the structure of the title molecular salt, C(10)H(18)N(2) (2+)·2NO(3) (−), the dinitrate salt of 4-(N,N-diethylamino)aniline, the two ethyl groups lie almost perpendicular to the plane of the benzene ring [the ring-to-ethyl C—C—N—C torsion angles are −59.5 (2) and 67.5 (3)°]. The aminium grou...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257297/ https://www.ncbi.nlm.nih.gov/pubmed/25484823 http://dx.doi.org/10.1107/S1600536814022946 |
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author | Bouaoud, Yasmina Smith, Graham Merazig, Hocine Setifi, Zouaoui |
author_facet | Bouaoud, Yasmina Smith, Graham Merazig, Hocine Setifi, Zouaoui |
author_sort | Bouaoud, Yasmina |
collection | PubMed |
description | In the structure of the title molecular salt, C(10)H(18)N(2) (2+)·2NO(3) (−), the dinitrate salt of 4-(N,N-diethylamino)aniline, the two ethyl groups lie almost perpendicular to the plane of the benzene ring [the ring-to-ethyl C—C—N—C torsion angles are −59.5 (2) and 67.5 (3)°]. The aminium groups of the cation form inter-species N—H⋯O hydrogen bonds with the nitro O-atom acceptors of both anions, giving rise to chain substructures lying along c. The chains are linked via further N—H⋯O hydrogen bonds, forming two-dimensional networks lying parallel to (010). These sheets are linked by C—H⋯O hydrogen bonds, forming a three-dimensional structure. |
format | Online Article Text |
id | pubmed-4257297 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42572972014-12-05 Crystal structure of N,N-diethylbenzene-1,4-diaminium dinitrate Bouaoud, Yasmina Smith, Graham Merazig, Hocine Setifi, Zouaoui Acta Crystallogr Sect E Struct Rep Online Data Reports In the structure of the title molecular salt, C(10)H(18)N(2) (2+)·2NO(3) (−), the dinitrate salt of 4-(N,N-diethylamino)aniline, the two ethyl groups lie almost perpendicular to the plane of the benzene ring [the ring-to-ethyl C—C—N—C torsion angles are −59.5 (2) and 67.5 (3)°]. The aminium groups of the cation form inter-species N—H⋯O hydrogen bonds with the nitro O-atom acceptors of both anions, giving rise to chain substructures lying along c. The chains are linked via further N—H⋯O hydrogen bonds, forming two-dimensional networks lying parallel to (010). These sheets are linked by C—H⋯O hydrogen bonds, forming a three-dimensional structure. International Union of Crystallography 2014-10-24 /pmc/articles/PMC4257297/ /pubmed/25484823 http://dx.doi.org/10.1107/S1600536814022946 Text en © Bouaoud et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Bouaoud, Yasmina Smith, Graham Merazig, Hocine Setifi, Zouaoui Crystal structure of N,N-diethylbenzene-1,4-diaminium dinitrate |
title | Crystal structure of N,N-diethylbenzene-1,4-diaminium dinitrate |
title_full | Crystal structure of N,N-diethylbenzene-1,4-diaminium dinitrate |
title_fullStr | Crystal structure of N,N-diethylbenzene-1,4-diaminium dinitrate |
title_full_unstemmed | Crystal structure of N,N-diethylbenzene-1,4-diaminium dinitrate |
title_short | Crystal structure of N,N-diethylbenzene-1,4-diaminium dinitrate |
title_sort | crystal structure of n,n-diethylbenzene-1,4-diaminium dinitrate |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257297/ https://www.ncbi.nlm.nih.gov/pubmed/25484823 http://dx.doi.org/10.1107/S1600536814022946 |
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