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Crystal structure of N,N-di­ethyl­benzene-1,4-diaminium dinitrate

In the structure of the title mol­ecular salt, C(10)H(18)N(2) (2+)·2NO(3) (−), the dinitrate salt of 4-(N,N-di­ethyl­amino)­aniline, the two ethyl groups lie almost perpendicular to the plane of the benzene ring [the ring-to-ethyl C—C—N—C torsion angles are −59.5 (2) and 67.5 (3)°]. The aminium grou...

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Autores principales: Bouaoud, Yasmina, Smith, Graham, Merazig, Hocine, Setifi, Zouaoui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257297/
https://www.ncbi.nlm.nih.gov/pubmed/25484823
http://dx.doi.org/10.1107/S1600536814022946
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author Bouaoud, Yasmina
Smith, Graham
Merazig, Hocine
Setifi, Zouaoui
author_facet Bouaoud, Yasmina
Smith, Graham
Merazig, Hocine
Setifi, Zouaoui
author_sort Bouaoud, Yasmina
collection PubMed
description In the structure of the title mol­ecular salt, C(10)H(18)N(2) (2+)·2NO(3) (−), the dinitrate salt of 4-(N,N-di­ethyl­amino)­aniline, the two ethyl groups lie almost perpendicular to the plane of the benzene ring [the ring-to-ethyl C—C—N—C torsion angles are −59.5 (2) and 67.5 (3)°]. The aminium groups of the cation form inter-species N—H⋯O hydrogen bonds with the nitro O-atom acceptors of both anions, giving rise to chain substructures lying along c. The chains are linked via further N—H⋯O hydrogen bonds, forming two-dimensional networks lying parallel to (010). These sheets are linked by C—H⋯O hydrogen bonds, forming a three-dimensional structure.
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spelling pubmed-42572972014-12-05 Crystal structure of N,N-di­ethyl­benzene-1,4-diaminium dinitrate Bouaoud, Yasmina Smith, Graham Merazig, Hocine Setifi, Zouaoui Acta Crystallogr Sect E Struct Rep Online Data Reports In the structure of the title mol­ecular salt, C(10)H(18)N(2) (2+)·2NO(3) (−), the dinitrate salt of 4-(N,N-di­ethyl­amino)­aniline, the two ethyl groups lie almost perpendicular to the plane of the benzene ring [the ring-to-ethyl C—C—N—C torsion angles are −59.5 (2) and 67.5 (3)°]. The aminium groups of the cation form inter-species N—H⋯O hydrogen bonds with the nitro O-atom acceptors of both anions, giving rise to chain substructures lying along c. The chains are linked via further N—H⋯O hydrogen bonds, forming two-dimensional networks lying parallel to (010). These sheets are linked by C—H⋯O hydrogen bonds, forming a three-dimensional structure. International Union of Crystallography 2014-10-24 /pmc/articles/PMC4257297/ /pubmed/25484823 http://dx.doi.org/10.1107/S1600536814022946 Text en © Bouaoud et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Bouaoud, Yasmina
Smith, Graham
Merazig, Hocine
Setifi, Zouaoui
Crystal structure of N,N-di­ethyl­benzene-1,4-diaminium dinitrate
title Crystal structure of N,N-di­ethyl­benzene-1,4-diaminium dinitrate
title_full Crystal structure of N,N-di­ethyl­benzene-1,4-diaminium dinitrate
title_fullStr Crystal structure of N,N-di­ethyl­benzene-1,4-diaminium dinitrate
title_full_unstemmed Crystal structure of N,N-di­ethyl­benzene-1,4-diaminium dinitrate
title_short Crystal structure of N,N-di­ethyl­benzene-1,4-diaminium dinitrate
title_sort crystal structure of n,n-di­ethyl­benzene-1,4-diaminium dinitrate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257297/
https://www.ncbi.nlm.nih.gov/pubmed/25484823
http://dx.doi.org/10.1107/S1600536814022946
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