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Crystal structure of (E)-N-[(E)-3-(4-meth­oxy­phen­yl)allyl­idene]naphthalen-1-amine

In the title compound, C(20)H(17)NO, the dihedral angle between the mean planes of the 4-meth­oxy­phenyl ring and the naphthalene ring is 69.50 (7)°. The meth­oxy group is almost coplanar with the benzene ring to which it is connected [Cb—Cb—Om—Cm torsion angle of −7.9 (2)°; b = benzene and m = meth...

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Autores principales: Lee, Jae Kyun, Cha, Joo Hwan, Cho, Yong Seo, Min, Sun-Joon, Lee, Joon Kyun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257298/
https://www.ncbi.nlm.nih.gov/pubmed/25484813
http://dx.doi.org/10.1107/S1600536814022521
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author Lee, Jae Kyun
Cha, Joo Hwan
Cho, Yong Seo
Min, Sun-Joon
Lee, Joon Kyun
author_facet Lee, Jae Kyun
Cha, Joo Hwan
Cho, Yong Seo
Min, Sun-Joon
Lee, Joon Kyun
author_sort Lee, Jae Kyun
collection PubMed
description In the title compound, C(20)H(17)NO, the dihedral angle between the mean planes of the 4-meth­oxy­phenyl ring and the naphthalene ring is 69.50 (7)°. The meth­oxy group is almost coplanar with the benzene ring to which it is connected [Cb—Cb—Om—Cm torsion angle of −7.9 (2)°; b = benzene and m = meth­oxy] and the imine group displays a C—C—N=C torsion angle is −57.2 (2)°. The imine (C=N) group has an E conformation. In the crystal, weak π–π inter­actions between the benzene rings [centroid–centroid distance = 3.7781 (10) Å] are observed.
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spelling pubmed-42572982014-12-05 Crystal structure of (E)-N-[(E)-3-(4-meth­oxy­phen­yl)allyl­idene]naphthalen-1-amine Lee, Jae Kyun Cha, Joo Hwan Cho, Yong Seo Min, Sun-Joon Lee, Joon Kyun Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(20)H(17)NO, the dihedral angle between the mean planes of the 4-meth­oxy­phenyl ring and the naphthalene ring is 69.50 (7)°. The meth­oxy group is almost coplanar with the benzene ring to which it is connected [Cb—Cb—Om—Cm torsion angle of −7.9 (2)°; b = benzene and m = meth­oxy] and the imine group displays a C—C—N=C torsion angle is −57.2 (2)°. The imine (C=N) group has an E conformation. In the crystal, weak π–π inter­actions between the benzene rings [centroid–centroid distance = 3.7781 (10) Å] are observed. International Union of Crystallography 2014-10-24 /pmc/articles/PMC4257298/ /pubmed/25484813 http://dx.doi.org/10.1107/S1600536814022521 Text en © Lee et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Lee, Jae Kyun
Cha, Joo Hwan
Cho, Yong Seo
Min, Sun-Joon
Lee, Joon Kyun
Crystal structure of (E)-N-[(E)-3-(4-meth­oxy­phen­yl)allyl­idene]naphthalen-1-amine
title Crystal structure of (E)-N-[(E)-3-(4-meth­oxy­phen­yl)allyl­idene]naphthalen-1-amine
title_full Crystal structure of (E)-N-[(E)-3-(4-meth­oxy­phen­yl)allyl­idene]naphthalen-1-amine
title_fullStr Crystal structure of (E)-N-[(E)-3-(4-meth­oxy­phen­yl)allyl­idene]naphthalen-1-amine
title_full_unstemmed Crystal structure of (E)-N-[(E)-3-(4-meth­oxy­phen­yl)allyl­idene]naphthalen-1-amine
title_short Crystal structure of (E)-N-[(E)-3-(4-meth­oxy­phen­yl)allyl­idene]naphthalen-1-amine
title_sort crystal structure of (e)-n-[(e)-3-(4-meth­oxy­phen­yl)allyl­idene]naphthalen-1-amine
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257298/
https://www.ncbi.nlm.nih.gov/pubmed/25484813
http://dx.doi.org/10.1107/S1600536814022521
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