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Crystal structure of (E)-N-[(E)-3-(4-methoxyphenyl)allylidene]naphthalen-1-amine
In the title compound, C(20)H(17)NO, the dihedral angle between the mean planes of the 4-methoxyphenyl ring and the naphthalene ring is 69.50 (7)°. The methoxy group is almost coplanar with the benzene ring to which it is connected [Cb—Cb—Om—Cm torsion angle of −7.9 (2)°; b = benzene and m = meth...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257298/ https://www.ncbi.nlm.nih.gov/pubmed/25484813 http://dx.doi.org/10.1107/S1600536814022521 |
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author | Lee, Jae Kyun Cha, Joo Hwan Cho, Yong Seo Min, Sun-Joon Lee, Joon Kyun |
author_facet | Lee, Jae Kyun Cha, Joo Hwan Cho, Yong Seo Min, Sun-Joon Lee, Joon Kyun |
author_sort | Lee, Jae Kyun |
collection | PubMed |
description | In the title compound, C(20)H(17)NO, the dihedral angle between the mean planes of the 4-methoxyphenyl ring and the naphthalene ring is 69.50 (7)°. The methoxy group is almost coplanar with the benzene ring to which it is connected [Cb—Cb—Om—Cm torsion angle of −7.9 (2)°; b = benzene and m = methoxy] and the imine group displays a C—C—N=C torsion angle is −57.2 (2)°. The imine (C=N) group has an E conformation. In the crystal, weak π–π interactions between the benzene rings [centroid–centroid distance = 3.7781 (10) Å] are observed. |
format | Online Article Text |
id | pubmed-4257298 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42572982014-12-05 Crystal structure of (E)-N-[(E)-3-(4-methoxyphenyl)allylidene]naphthalen-1-amine Lee, Jae Kyun Cha, Joo Hwan Cho, Yong Seo Min, Sun-Joon Lee, Joon Kyun Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(20)H(17)NO, the dihedral angle between the mean planes of the 4-methoxyphenyl ring and the naphthalene ring is 69.50 (7)°. The methoxy group is almost coplanar with the benzene ring to which it is connected [Cb—Cb—Om—Cm torsion angle of −7.9 (2)°; b = benzene and m = methoxy] and the imine group displays a C—C—N=C torsion angle is −57.2 (2)°. The imine (C=N) group has an E conformation. In the crystal, weak π–π interactions between the benzene rings [centroid–centroid distance = 3.7781 (10) Å] are observed. International Union of Crystallography 2014-10-24 /pmc/articles/PMC4257298/ /pubmed/25484813 http://dx.doi.org/10.1107/S1600536814022521 Text en © Lee et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Lee, Jae Kyun Cha, Joo Hwan Cho, Yong Seo Min, Sun-Joon Lee, Joon Kyun Crystal structure of (E)-N-[(E)-3-(4-methoxyphenyl)allylidene]naphthalen-1-amine |
title | Crystal structure of (E)-N-[(E)-3-(4-methoxyphenyl)allylidene]naphthalen-1-amine |
title_full | Crystal structure of (E)-N-[(E)-3-(4-methoxyphenyl)allylidene]naphthalen-1-amine |
title_fullStr | Crystal structure of (E)-N-[(E)-3-(4-methoxyphenyl)allylidene]naphthalen-1-amine |
title_full_unstemmed | Crystal structure of (E)-N-[(E)-3-(4-methoxyphenyl)allylidene]naphthalen-1-amine |
title_short | Crystal structure of (E)-N-[(E)-3-(4-methoxyphenyl)allylidene]naphthalen-1-amine |
title_sort | crystal structure of (e)-n-[(e)-3-(4-methoxyphenyl)allylidene]naphthalen-1-amine |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257298/ https://www.ncbi.nlm.nih.gov/pubmed/25484813 http://dx.doi.org/10.1107/S1600536814022521 |
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