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Crystal structure of poly[[μ(3)-4,4′-(4,4′-bipyridine-2,6-diyl)dibenzoato]{μ(2)-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-4′-ium-2-yl]benzoato}manganese(II)] hemihydrate]
The title compound, {[Mn(C(24)H(14)N(2)O(4))(C(24)H(16)N(2)O(4))]·0.5H(2)O}(n), was obtained by the reaction of manganese nitrate with the ligand 4,4′-(4,4′-bipyridine-2,6-diyl) dibenzoic acid under hydrothermal conditions. The water O atom is located on a twofold rotation axis. The Mn(2+) ion i...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257299/ https://www.ncbi.nlm.nih.gov/pubmed/25484782 http://dx.doi.org/10.1107/S160053681402279X |
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| author | Li, Yaping Sun, Dajun Ming, Julia Han, Liying Su, Guanfang |
| author_facet | Li, Yaping Sun, Dajun Ming, Julia Han, Liying Su, Guanfang |
| author_sort | Li, Yaping |
| collection | PubMed |
| description | The title compound, {[Mn(C(24)H(14)N(2)O(4))(C(24)H(16)N(2)O(4))]·0.5H(2)O}(n), was obtained by the reaction of manganese nitrate with the ligand 4,4′-(4,4′-bipyridine-2,6-diyl) dibenzoic acid under hydrothermal conditions. The water O atom is located on a twofold rotation axis. The Mn(2+) ion is heptacoordinated by six O atoms and one N atom from the ligands. In this structure, the ligands adopts two different forms, one completely deprotonated and one with a protonated N atom (pyridinium) and a carboxylic acid function. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds consolidate the packing, forming a three-dimensional framework. |
| format | Online Article Text |
| id | pubmed-4257299 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-42572992014-12-05 Crystal structure of poly[[μ(3)-4,4′-(4,4′-bipyridine-2,6-diyl)dibenzoato]{μ(2)-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-4′-ium-2-yl]benzoato}manganese(II)] hemihydrate] Li, Yaping Sun, Dajun Ming, Julia Han, Liying Su, Guanfang Acta Crystallogr Sect E Struct Rep Online Data Reports The title compound, {[Mn(C(24)H(14)N(2)O(4))(C(24)H(16)N(2)O(4))]·0.5H(2)O}(n), was obtained by the reaction of manganese nitrate with the ligand 4,4′-(4,4′-bipyridine-2,6-diyl) dibenzoic acid under hydrothermal conditions. The water O atom is located on a twofold rotation axis. The Mn(2+) ion is heptacoordinated by six O atoms and one N atom from the ligands. In this structure, the ligands adopts two different forms, one completely deprotonated and one with a protonated N atom (pyridinium) and a carboxylic acid function. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds consolidate the packing, forming a three-dimensional framework. International Union of Crystallography 2014-10-24 /pmc/articles/PMC4257299/ /pubmed/25484782 http://dx.doi.org/10.1107/S160053681402279X Text en © Li et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Data Reports Li, Yaping Sun, Dajun Ming, Julia Han, Liying Su, Guanfang Crystal structure of poly[[μ(3)-4,4′-(4,4′-bipyridine-2,6-diyl)dibenzoato]{μ(2)-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-4′-ium-2-yl]benzoato}manganese(II)] hemihydrate] |
| title | Crystal structure of poly[[μ(3)-4,4′-(4,4′-bipyridine-2,6-diyl)dibenzoato]{μ(2)-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-4′-ium-2-yl]benzoato}manganese(II)] hemihydrate] |
| title_full | Crystal structure of poly[[μ(3)-4,4′-(4,4′-bipyridine-2,6-diyl)dibenzoato]{μ(2)-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-4′-ium-2-yl]benzoato}manganese(II)] hemihydrate] |
| title_fullStr | Crystal structure of poly[[μ(3)-4,4′-(4,4′-bipyridine-2,6-diyl)dibenzoato]{μ(2)-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-4′-ium-2-yl]benzoato}manganese(II)] hemihydrate] |
| title_full_unstemmed | Crystal structure of poly[[μ(3)-4,4′-(4,4′-bipyridine-2,6-diyl)dibenzoato]{μ(2)-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-4′-ium-2-yl]benzoato}manganese(II)] hemihydrate] |
| title_short | Crystal structure of poly[[μ(3)-4,4′-(4,4′-bipyridine-2,6-diyl)dibenzoato]{μ(2)-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-4′-ium-2-yl]benzoato}manganese(II)] hemihydrate] |
| title_sort | crystal structure of poly[[μ(3)-4,4′-(4,4′-bipyridine-2,6-diyl)dibenzoato]{μ(2)-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-4′-ium-2-yl]benzoato}manganese(ii)] hemihydrate] |
| topic | Data Reports |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257299/ https://www.ncbi.nlm.nih.gov/pubmed/25484782 http://dx.doi.org/10.1107/S160053681402279X |
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