Crystal structure of [propane-1,3-diylbis(piperidine-4,1-di­yl)]bis­[(pyridin-4-yl)methanone]–isophthalic acid (1/1)

In the crystal structure of the title co-crystal, C(25)H(32)N(4)O(2)·C(8)H(6)O(4), isophthalic acid and [propane-1,3-diylbis(piperidine-4,1-di­yl)]bis­(pyridin-4-yl­methanone) mol­ecules are connected into supra­molecular chains aligned along the c axis by O—H⋯N hydrogen bonding. These aggregate int...

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Detalles Bibliográficos
Autores principales: Murray, Nathan H., Biros, Shannon M., LaDuca, Robert L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257304/
https://www.ncbi.nlm.nih.gov/pubmed/25484727
http://dx.doi.org/10.1107/S1600536814021679
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author Murray, Nathan H.
Biros, Shannon M.
LaDuca, Robert L.
author_facet Murray, Nathan H.
Biros, Shannon M.
LaDuca, Robert L.
author_sort Murray, Nathan H.
collection PubMed
description In the crystal structure of the title co-crystal, C(25)H(32)N(4)O(2)·C(8)H(6)O(4), isophthalic acid and [propane-1,3-diylbis(piperidine-4,1-di­yl)]bis­(pyridin-4-yl­methanone) mol­ecules are connected into supra­molecular chains aligned along the c axis by O—H⋯N hydrogen bonding. These aggregate into supra­molecular layers oriented parallel to the ac plane by C—H⋯O inter­actions. These layers then stack in an ABCD pattern along the b-axis direction by additional C—H⋯O inter­actions to give the full three-dimensional crystal structure. The central chain in the di­pyridyl­amide molecule has an anti–gauche conformation.
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spelling pubmed-42573042014-12-05 Crystal structure of [propane-1,3-diylbis(piperidine-4,1-di­yl)]bis­[(pyridin-4-yl)methanone]–isophthalic acid (1/1) Murray, Nathan H. Biros, Shannon M. LaDuca, Robert L. Acta Crystallogr Sect E Struct Rep Online Research Communications In the crystal structure of the title co-crystal, C(25)H(32)N(4)O(2)·C(8)H(6)O(4), isophthalic acid and [propane-1,3-diylbis(piperidine-4,1-di­yl)]bis­(pyridin-4-yl­methanone) mol­ecules are connected into supra­molecular chains aligned along the c axis by O—H⋯N hydrogen bonding. These aggregate into supra­molecular layers oriented parallel to the ac plane by C—H⋯O inter­actions. These layers then stack in an ABCD pattern along the b-axis direction by additional C—H⋯O inter­actions to give the full three-dimensional crystal structure. The central chain in the di­pyridyl­amide molecule has an anti–gauche conformation. International Union of Crystallography 2014-10-04 /pmc/articles/PMC4257304/ /pubmed/25484727 http://dx.doi.org/10.1107/S1600536814021679 Text en © Murray et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Murray, Nathan H.
Biros, Shannon M.
LaDuca, Robert L.
Crystal structure of [propane-1,3-diylbis(piperidine-4,1-di­yl)]bis­[(pyridin-4-yl)methanone]–isophthalic acid (1/1)
title Crystal structure of [propane-1,3-diylbis(piperidine-4,1-di­yl)]bis­[(pyridin-4-yl)methanone]–isophthalic acid (1/1)
title_full Crystal structure of [propane-1,3-diylbis(piperidine-4,1-di­yl)]bis­[(pyridin-4-yl)methanone]–isophthalic acid (1/1)
title_fullStr Crystal structure of [propane-1,3-diylbis(piperidine-4,1-di­yl)]bis­[(pyridin-4-yl)methanone]–isophthalic acid (1/1)
title_full_unstemmed Crystal structure of [propane-1,3-diylbis(piperidine-4,1-di­yl)]bis­[(pyridin-4-yl)methanone]–isophthalic acid (1/1)
title_short Crystal structure of [propane-1,3-diylbis(piperidine-4,1-di­yl)]bis­[(pyridin-4-yl)methanone]–isophthalic acid (1/1)
title_sort crystal structure of [propane-1,3-diylbis(piperidine-4,1-di­yl)]bis­[(pyridin-4-yl)methanone]–isophthalic acid (1/1)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257304/
https://www.ncbi.nlm.nih.gov/pubmed/25484727
http://dx.doi.org/10.1107/S1600536814021679
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