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Crystal structure of aquachloridobis(2-ethoxy-6-formylphenolato-κ(2) O (1),O (6))iron(III) acetonitrile hemisolvate
In the title compound, [Fe(L)(2)Cl(H(2)O)]·0.5CH(3)CN, (HL is 3-ethoxy-2-hydroxy-benzaldehyde, C(9)H(10)O(3)), there are two independent complex molecules and one acetonitrile solvent molecule in the asymmetric unit. In each complex molecule, the Fe(III) ion has a distorted O(5)Cl octahedral...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257307/ https://www.ncbi.nlm.nih.gov/pubmed/25484720 http://dx.doi.org/10.1107/S1600536814021205 |
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author | Jiang, Xi-Fu Zhao, Ru-Xia Zhang, Shu-Hua |
author_facet | Jiang, Xi-Fu Zhao, Ru-Xia Zhang, Shu-Hua |
author_sort | Jiang, Xi-Fu |
collection | PubMed |
description | In the title compound, [Fe(L)(2)Cl(H(2)O)]·0.5CH(3)CN, (HL is 3-ethoxy-2-hydroxy-benzaldehyde, C(9)H(10)O(3)), there are two independent complex molecules and one acetonitrile solvent molecule in the asymmetric unit. In each complex molecule, the Fe(III) ion has a distorted O(5)Cl octahedral coordination environment defined by two bidentate 2-ethoxy-6-formylphenolato ligands, one Cl atom and one water molecule. In the crystal, O—H⋯O hydrogen bonds link the two independent molecules to form a dimer. The solvent molecule is linked to the complex molecule by a weak C—H⋯O hydrogen bond. Further weak C—H⋯O interactions along with weak C—H⋯Cl hydrogen bonds link the components into chains parallel to [001]. |
format | Online Article Text |
id | pubmed-4257307 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42573072014-12-05 Crystal structure of aquachloridobis(2-ethoxy-6-formylphenolato-κ(2) O (1),O (6))iron(III) acetonitrile hemisolvate Jiang, Xi-Fu Zhao, Ru-Xia Zhang, Shu-Hua Acta Crystallogr Sect E Struct Rep Online Research Communications In the title compound, [Fe(L)(2)Cl(H(2)O)]·0.5CH(3)CN, (HL is 3-ethoxy-2-hydroxy-benzaldehyde, C(9)H(10)O(3)), there are two independent complex molecules and one acetonitrile solvent molecule in the asymmetric unit. In each complex molecule, the Fe(III) ion has a distorted O(5)Cl octahedral coordination environment defined by two bidentate 2-ethoxy-6-formylphenolato ligands, one Cl atom and one water molecule. In the crystal, O—H⋯O hydrogen bonds link the two independent molecules to form a dimer. The solvent molecule is linked to the complex molecule by a weak C—H⋯O hydrogen bond. Further weak C—H⋯O interactions along with weak C—H⋯Cl hydrogen bonds link the components into chains parallel to [001]. International Union of Crystallography 2014-10-04 /pmc/articles/PMC4257307/ /pubmed/25484720 http://dx.doi.org/10.1107/S1600536814021205 Text en © Jiang et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Jiang, Xi-Fu Zhao, Ru-Xia Zhang, Shu-Hua Crystal structure of aquachloridobis(2-ethoxy-6-formylphenolato-κ(2) O (1),O (6))iron(III) acetonitrile hemisolvate |
title | Crystal structure of aquachloridobis(2-ethoxy-6-formylphenolato-κ(2)
O
(1),O
(6))iron(III) acetonitrile hemisolvate |
title_full | Crystal structure of aquachloridobis(2-ethoxy-6-formylphenolato-κ(2)
O
(1),O
(6))iron(III) acetonitrile hemisolvate |
title_fullStr | Crystal structure of aquachloridobis(2-ethoxy-6-formylphenolato-κ(2)
O
(1),O
(6))iron(III) acetonitrile hemisolvate |
title_full_unstemmed | Crystal structure of aquachloridobis(2-ethoxy-6-formylphenolato-κ(2)
O
(1),O
(6))iron(III) acetonitrile hemisolvate |
title_short | Crystal structure of aquachloridobis(2-ethoxy-6-formylphenolato-κ(2)
O
(1),O
(6))iron(III) acetonitrile hemisolvate |
title_sort | crystal structure of aquachloridobis(2-ethoxy-6-formylphenolato-κ(2)
o
(1),o
(6))iron(iii) acetonitrile hemisolvate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257307/ https://www.ncbi.nlm.nih.gov/pubmed/25484720 http://dx.doi.org/10.1107/S1600536814021205 |
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