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Crystal structure of aqua­chlorido­bis­(2-eth­oxy-6-formyl­phenolato-κ(2) O (1),O (6))iron(III) aceto­nitrile hemisolvate

In the title compound, [Fe(L)(2)Cl(H(2)O)]·0.5CH(3)CN, (HL is 3-eth­oxy-2-hy­droxy-benzaldehyde, C(9)H(10)O(3)), there are two independent complex mol­ecules and one aceto­nitrile solvent mol­ecule in the asymmetric unit. In each complex mol­ecule, the Fe(III) ion has a distorted O(5)Cl octa­hedral...

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Detalles Bibliográficos
Autores principales: Jiang, Xi-Fu, Zhao, Ru-Xia, Zhang, Shu-Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257307/
https://www.ncbi.nlm.nih.gov/pubmed/25484720
http://dx.doi.org/10.1107/S1600536814021205
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author Jiang, Xi-Fu
Zhao, Ru-Xia
Zhang, Shu-Hua
author_facet Jiang, Xi-Fu
Zhao, Ru-Xia
Zhang, Shu-Hua
author_sort Jiang, Xi-Fu
collection PubMed
description In the title compound, [Fe(L)(2)Cl(H(2)O)]·0.5CH(3)CN, (HL is 3-eth­oxy-2-hy­droxy-benzaldehyde, C(9)H(10)O(3)), there are two independent complex mol­ecules and one aceto­nitrile solvent mol­ecule in the asymmetric unit. In each complex mol­ecule, the Fe(III) ion has a distorted O(5)Cl octa­hedral coordination environment defined by two bidentate 2-eth­oxy-6-formyl­phenolato ligands, one Cl atom and one water mol­ecule. In the crystal, O—H⋯O hydrogen bonds link the two independent mol­ecules to form a dimer. The solvent mol­ecule is linked to the complex mol­ecule by a weak C—H⋯O hydrogen bond. Further weak C—H⋯O inter­actions along with weak C—H⋯Cl hydrogen bonds link the components into chains parallel to [001].
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spelling pubmed-42573072014-12-05 Crystal structure of aqua­chlorido­bis­(2-eth­oxy-6-formyl­phenolato-κ(2) O (1),O (6))iron(III) aceto­nitrile hemisolvate Jiang, Xi-Fu Zhao, Ru-Xia Zhang, Shu-Hua Acta Crystallogr Sect E Struct Rep Online Research Communications In the title compound, [Fe(L)(2)Cl(H(2)O)]·0.5CH(3)CN, (HL is 3-eth­oxy-2-hy­droxy-benzaldehyde, C(9)H(10)O(3)), there are two independent complex mol­ecules and one aceto­nitrile solvent mol­ecule in the asymmetric unit. In each complex mol­ecule, the Fe(III) ion has a distorted O(5)Cl octa­hedral coordination environment defined by two bidentate 2-eth­oxy-6-formyl­phenolato ligands, one Cl atom and one water mol­ecule. In the crystal, O—H⋯O hydrogen bonds link the two independent mol­ecules to form a dimer. The solvent mol­ecule is linked to the complex mol­ecule by a weak C—H⋯O hydrogen bond. Further weak C—H⋯O inter­actions along with weak C—H⋯Cl hydrogen bonds link the components into chains parallel to [001]. International Union of Crystallography 2014-10-04 /pmc/articles/PMC4257307/ /pubmed/25484720 http://dx.doi.org/10.1107/S1600536814021205 Text en © Jiang et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Jiang, Xi-Fu
Zhao, Ru-Xia
Zhang, Shu-Hua
Crystal structure of aqua­chlorido­bis­(2-eth­oxy-6-formyl­phenolato-κ(2) O (1),O (6))iron(III) aceto­nitrile hemisolvate
title Crystal structure of aqua­chlorido­bis­(2-eth­oxy-6-formyl­phenolato-κ(2) O (1),O (6))iron(III) aceto­nitrile hemisolvate
title_full Crystal structure of aqua­chlorido­bis­(2-eth­oxy-6-formyl­phenolato-κ(2) O (1),O (6))iron(III) aceto­nitrile hemisolvate
title_fullStr Crystal structure of aqua­chlorido­bis­(2-eth­oxy-6-formyl­phenolato-κ(2) O (1),O (6))iron(III) aceto­nitrile hemisolvate
title_full_unstemmed Crystal structure of aqua­chlorido­bis­(2-eth­oxy-6-formyl­phenolato-κ(2) O (1),O (6))iron(III) aceto­nitrile hemisolvate
title_short Crystal structure of aqua­chlorido­bis­(2-eth­oxy-6-formyl­phenolato-κ(2) O (1),O (6))iron(III) aceto­nitrile hemisolvate
title_sort crystal structure of aqua­chlorido­bis­(2-eth­oxy-6-formyl­phenolato-κ(2) o (1),o (6))iron(iii) aceto­nitrile hemisolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257307/
https://www.ncbi.nlm.nih.gov/pubmed/25484720
http://dx.doi.org/10.1107/S1600536814021205
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