Crystal structure of bis­(di­methyl­ammonium) hexa­aqua­nickel(II) bis­(sulfate) dihydrate

In the title salt, (C(2)H(8)N)(2)[Ni(H(2)O)(6))](SO(4))(2)·2H(2)O, the Ni(II) cation is located on a centre of inversion and exhibits a slightly distorted octa­hedral arrangement of water mol­ecules. The Ni—O bond lengths in the complex [Ni(H(2)O)(6)](2+) cation show a distribution as in the related...

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Detalles Bibliográficos
Autor principal: Held, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257308/
https://www.ncbi.nlm.nih.gov/pubmed/25484758
http://dx.doi.org/10.1107/S160053681402234X
Descripción
Sumario:In the title salt, (C(2)H(8)N)(2)[Ni(H(2)O)(6))](SO(4))(2)·2H(2)O, the Ni(II) cation is located on a centre of inversion and exhibits a slightly distorted octa­hedral arrangement of water mol­ecules. The Ni—O bond lengths in the complex [Ni(H(2)O)(6)](2+) cation show a distribution as in the related Tutton salt (NH(4))(2)[Ni(H(2)O)(6)](SO(4))(2), but are longer in average [2.056 (13) versus 2.037 (12) Å]. The noncoordinating water mol­ecules and di­methyl­ammonium cations connect the sulfate and [Ni(H(2)O)(6)](2+) octa­hedra via O—H⋯O and N—H⋯O hydrogen bonds from weak up to medium strength into a three-dimensional framework whereby the complex metal cations and sulfate anions are arranged in sheets parallel (001).

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