Crystal structure of N-(quinolin-6-yl)hydroxyl­amine

The title compound, C(9)H(8)N(2)O, crystallized with four independent mol­ecules in the asymmetric unit. The four mol­ecules are linked via one O—H⋯N and two N—H⋯N hydrogen bonds, forming a tetra­mer-like unit. In the crystal, mol­ecules are further linked by O—H⋯N and N—H⋯O hydrogen bonds forming l...

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Autores principales: Rajapakse, Anuruddha, Hillebrand, Roman, Lewis, Sarah M., Parsons, Zachary D., Barnes, Charles L., Gates, Kent S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257318/
https://www.ncbi.nlm.nih.gov/pubmed/25484734
http://dx.doi.org/10.1107/S160053681402193X
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author Rajapakse, Anuruddha
Hillebrand, Roman
Lewis, Sarah M.
Parsons, Zachary D.
Barnes, Charles L.
Gates, Kent S.
author_facet Rajapakse, Anuruddha
Hillebrand, Roman
Lewis, Sarah M.
Parsons, Zachary D.
Barnes, Charles L.
Gates, Kent S.
author_sort Rajapakse, Anuruddha
collection PubMed
description The title compound, C(9)H(8)N(2)O, crystallized with four independent mol­ecules in the asymmetric unit. The four mol­ecules are linked via one O—H⋯N and two N—H⋯N hydrogen bonds, forming a tetra­mer-like unit. In the crystal, mol­ecules are further linked by O—H⋯N and N—H⋯O hydrogen bonds forming layers parallel to (001). These layers are linked via C—H⋯O hydrogen bonds and a number of weak C—H⋯π inter­actions, forming a three-dimensional structure. The crystal was refined as a non-merohedral twin with a minor twin component of 0.319.
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spelling pubmed-42573182014-12-05 Crystal structure of N-(quinolin-6-yl)hydroxyl­amine Rajapakse, Anuruddha Hillebrand, Roman Lewis, Sarah M. Parsons, Zachary D. Barnes, Charles L. Gates, Kent S. Acta Crystallogr Sect E Struct Rep Online Research Communications The title compound, C(9)H(8)N(2)O, crystallized with four independent mol­ecules in the asymmetric unit. The four mol­ecules are linked via one O—H⋯N and two N—H⋯N hydrogen bonds, forming a tetra­mer-like unit. In the crystal, mol­ecules are further linked by O—H⋯N and N—H⋯O hydrogen bonds forming layers parallel to (001). These layers are linked via C—H⋯O hydrogen bonds and a number of weak C—H⋯π inter­actions, forming a three-dimensional structure. The crystal was refined as a non-merohedral twin with a minor twin component of 0.319. International Union of Crystallography 2014-10-11 /pmc/articles/PMC4257318/ /pubmed/25484734 http://dx.doi.org/10.1107/S160053681402193X Text en © Rajapakse et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Rajapakse, Anuruddha
Hillebrand, Roman
Lewis, Sarah M.
Parsons, Zachary D.
Barnes, Charles L.
Gates, Kent S.
Crystal structure of N-(quinolin-6-yl)hydroxyl­amine
title Crystal structure of N-(quinolin-6-yl)hydroxyl­amine
title_full Crystal structure of N-(quinolin-6-yl)hydroxyl­amine
title_fullStr Crystal structure of N-(quinolin-6-yl)hydroxyl­amine
title_full_unstemmed Crystal structure of N-(quinolin-6-yl)hydroxyl­amine
title_short Crystal structure of N-(quinolin-6-yl)hydroxyl­amine
title_sort crystal structure of n-(quinolin-6-yl)hydroxyl­amine
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257318/
https://www.ncbi.nlm.nih.gov/pubmed/25484734
http://dx.doi.org/10.1107/S160053681402193X
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