Crystal structure of 2,2-di­phenyl­hydrazinium chloride

In the title compound, C(12)H(13)N(2) (+)·Cl(−), the chloride salt of 1,1′-di­phenyl­hydrazine, the phenyl rings are inclined to one another by 78.63 (17)°. The N—(+)NH(3) bond lengths is 1.445 (3) Å, and the N—C(phen­yl) bond lengths are 1.435 (3) and 1.447 (4) Å. In the crystal, mol­ecules are lin...

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Autores principales: Paul, Amit Kumal, Mukherjee, Soma, Stoeckli-Evans, Helen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257322/
https://www.ncbi.nlm.nih.gov/pubmed/25484752
http://dx.doi.org/10.1107/S1600536814022879
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author Paul, Amit Kumal
Mukherjee, Soma
Stoeckli-Evans, Helen
author_facet Paul, Amit Kumal
Mukherjee, Soma
Stoeckli-Evans, Helen
author_sort Paul, Amit Kumal
collection PubMed
description In the title compound, C(12)H(13)N(2) (+)·Cl(−), the chloride salt of 1,1′-di­phenyl­hydrazine, the phenyl rings are inclined to one another by 78.63 (17)°. The N—(+)NH(3) bond lengths is 1.445 (3) Å, and the N—C(phen­yl) bond lengths are 1.435 (3) and 1.447 (4) Å. In the crystal, mol­ecules are linked via N—H⋯Cl hydrogen bonds, forming chains along [10-1], which enclose two adjacent R (4) (2)(6) ring motifs. The chains are reinforced by C—H⋯Cl hydrogen bonds.
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spelling pubmed-42573222014-12-05 Crystal structure of 2,2-di­phenyl­hydrazinium chloride Paul, Amit Kumal Mukherjee, Soma Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Research Communications In the title compound, C(12)H(13)N(2) (+)·Cl(−), the chloride salt of 1,1′-di­phenyl­hydrazine, the phenyl rings are inclined to one another by 78.63 (17)°. The N—(+)NH(3) bond lengths is 1.445 (3) Å, and the N—C(phen­yl) bond lengths are 1.435 (3) and 1.447 (4) Å. In the crystal, mol­ecules are linked via N—H⋯Cl hydrogen bonds, forming chains along [10-1], which enclose two adjacent R (4) (2)(6) ring motifs. The chains are reinforced by C—H⋯Cl hydrogen bonds. International Union of Crystallography 2014-10-24 /pmc/articles/PMC4257322/ /pubmed/25484752 http://dx.doi.org/10.1107/S1600536814022879 Text en © Paul et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Paul, Amit Kumal
Mukherjee, Soma
Stoeckli-Evans, Helen
Crystal structure of 2,2-di­phenyl­hydrazinium chloride
title Crystal structure of 2,2-di­phenyl­hydrazinium chloride
title_full Crystal structure of 2,2-di­phenyl­hydrazinium chloride
title_fullStr Crystal structure of 2,2-di­phenyl­hydrazinium chloride
title_full_unstemmed Crystal structure of 2,2-di­phenyl­hydrazinium chloride
title_short Crystal structure of 2,2-di­phenyl­hydrazinium chloride
title_sort crystal structure of 2,2-di­phenyl­hydrazinium chloride
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257322/
https://www.ncbi.nlm.nih.gov/pubmed/25484752
http://dx.doi.org/10.1107/S1600536814022879
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AT stoecklievanshelen crystalstructureof22diphenylhydraziniumchloride

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