Crystal structure of tert-butyl-N-phenyl­carbonitrilium tetra­chlorido­aluminate

In the title compound, (C(11)H(14)N)[AlCl(4)], the nitrilium (systematic name: 2,2-dimethyl-N-phenyl­propane­nitrilium) ion adopts a slightly distorted linear configuration [C—N C = 178.87 (16) and N C—C = 179.13 (17)°]. In the crystal, while there are no inter­molecular hydrogen bonds, pairs of nit...

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Autores principales: van Dijk, Tom, Zant, Dirk W., Wolf, Robert, Lammertsma, Koop, Slootweg, J. Chris
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257323/
https://www.ncbi.nlm.nih.gov/pubmed/25484737
http://dx.doi.org/10.1107/S1600536814022028
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author van Dijk, Tom
Zant, Dirk W.
Wolf, Robert
Lammertsma, Koop
Slootweg, J. Chris
author_facet van Dijk, Tom
Zant, Dirk W.
Wolf, Robert
Lammertsma, Koop
Slootweg, J. Chris
author_sort van Dijk, Tom
collection PubMed
description In the title compound, (C(11)H(14)N)[AlCl(4)], the nitrilium (systematic name: 2,2-dimethyl-N-phenyl­propane­nitrilium) ion adopts a slightly distorted linear configuration [C—N C = 178.87 (16) and N C—C = 179.13 (17)°]. In the crystal, while there are no inter­molecular hydrogen bonds, pairs of nitrilium ions are linked through π–π inter­actions [inter–centroid distance = 3.8091 (13) Å].
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spelling pubmed-42573232014-12-05 Crystal structure of tert-butyl-N-phenyl­carbonitrilium tetra­chlorido­aluminate van Dijk, Tom Zant, Dirk W. Wolf, Robert Lammertsma, Koop Slootweg, J. Chris Acta Crystallogr Sect E Struct Rep Online Research Communications In the title compound, (C(11)H(14)N)[AlCl(4)], the nitrilium (systematic name: 2,2-dimethyl-N-phenyl­propane­nitrilium) ion adopts a slightly distorted linear configuration [C—N C = 178.87 (16) and N C—C = 179.13 (17)°]. In the crystal, while there are no inter­molecular hydrogen bonds, pairs of nitrilium ions are linked through π–π inter­actions [inter–centroid distance = 3.8091 (13) Å]. International Union of Crystallography 2014-10-11 /pmc/articles/PMC4257323/ /pubmed/25484737 http://dx.doi.org/10.1107/S1600536814022028 Text en © Dijk et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
van Dijk, Tom
Zant, Dirk W.
Wolf, Robert
Lammertsma, Koop
Slootweg, J. Chris
Crystal structure of tert-butyl-N-phenyl­carbonitrilium tetra­chlorido­aluminate
title Crystal structure of tert-butyl-N-phenyl­carbonitrilium tetra­chlorido­aluminate
title_full Crystal structure of tert-butyl-N-phenyl­carbonitrilium tetra­chlorido­aluminate
title_fullStr Crystal structure of tert-butyl-N-phenyl­carbonitrilium tetra­chlorido­aluminate
title_full_unstemmed Crystal structure of tert-butyl-N-phenyl­carbonitrilium tetra­chlorido­aluminate
title_short Crystal structure of tert-butyl-N-phenyl­carbonitrilium tetra­chlorido­aluminate
title_sort crystal structure of tert-butyl-n-phenyl­carbonitrilium tetra­chlorido­aluminate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257323/
https://www.ncbi.nlm.nih.gov/pubmed/25484737
http://dx.doi.org/10.1107/S1600536814022028
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