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Crystal structure of meso-tetra­kis­(4-nitro­phen­yl)porphyrin nitro­benzene disolvate

The porphyrin core of the title centrosymmetric compound, C(44)H(26)N(8)O(8)·2C(6)H(5)NO(2), is approximately planar, the maximum deviation being 0.069 (3) Å. The planes of the benzene rings of the nitro­phenyl substituents are almost perpendicular to the porphyrin mean plane, making dihedral angles...

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Autores principales: Seredyuk, Maksym, Gumienna–Kontecka, Elzbieta, Brzuszkiewicz, Anna, Iskenderov, Turganbay S., Kalibabchuk, Valentina A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257332/
https://www.ncbi.nlm.nih.gov/pubmed/25484793
http://dx.doi.org/10.1107/S1600536814021503
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author Seredyuk, Maksym
Gumienna–Kontecka, Elzbieta
Brzuszkiewicz, Anna
Iskenderov, Turganbay S.
Kalibabchuk, Valentina A.
author_facet Seredyuk, Maksym
Gumienna–Kontecka, Elzbieta
Brzuszkiewicz, Anna
Iskenderov, Turganbay S.
Kalibabchuk, Valentina A.
author_sort Seredyuk, Maksym
collection PubMed
description The porphyrin core of the title centrosymmetric compound, C(44)H(26)N(8)O(8)·2C(6)H(5)NO(2), is approximately planar, the maximum deviation being 0.069 (3) Å. The planes of the benzene rings of the nitro­phenyl substituents are almost perpendicular to the porphyrin mean plane, making dihedral angles of 73.89 (9) and 89.24 (9)°. The two pyrrole ring H atoms are equally disordered over the four pyrrole ring N atoms. In the crystal, weak C—H⋯O and C—H⋯N hydrogen bonds link the porphyrin mol­ecules into a three-dimensional supra­molecular network. The nitro­benzene solvent mol­ecules are linked by weak C—H⋯O hydrogen bonds into supra­molecular chains propagating along the a-axis direction.
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spelling pubmed-42573322014-12-05 Crystal structure of meso-tetra­kis­(4-nitro­phen­yl)porphyrin nitro­benzene disolvate Seredyuk, Maksym Gumienna–Kontecka, Elzbieta Brzuszkiewicz, Anna Iskenderov, Turganbay S. Kalibabchuk, Valentina A. Acta Crystallogr Sect E Struct Rep Online Data Reports The porphyrin core of the title centrosymmetric compound, C(44)H(26)N(8)O(8)·2C(6)H(5)NO(2), is approximately planar, the maximum deviation being 0.069 (3) Å. The planes of the benzene rings of the nitro­phenyl substituents are almost perpendicular to the porphyrin mean plane, making dihedral angles of 73.89 (9) and 89.24 (9)°. The two pyrrole ring H atoms are equally disordered over the four pyrrole ring N atoms. In the crystal, weak C—H⋯O and C—H⋯N hydrogen bonds link the porphyrin mol­ecules into a three-dimensional supra­molecular network. The nitro­benzene solvent mol­ecules are linked by weak C—H⋯O hydrogen bonds into supra­molecular chains propagating along the a-axis direction. International Union of Crystallography 2014-10-04 /pmc/articles/PMC4257332/ /pubmed/25484793 http://dx.doi.org/10.1107/S1600536814021503 Text en © Seredyuk et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Seredyuk, Maksym
Gumienna–Kontecka, Elzbieta
Brzuszkiewicz, Anna
Iskenderov, Turganbay S.
Kalibabchuk, Valentina A.
Crystal structure of meso-tetra­kis­(4-nitro­phen­yl)porphyrin nitro­benzene disolvate
title Crystal structure of meso-tetra­kis­(4-nitro­phen­yl)porphyrin nitro­benzene disolvate
title_full Crystal structure of meso-tetra­kis­(4-nitro­phen­yl)porphyrin nitro­benzene disolvate
title_fullStr Crystal structure of meso-tetra­kis­(4-nitro­phen­yl)porphyrin nitro­benzene disolvate
title_full_unstemmed Crystal structure of meso-tetra­kis­(4-nitro­phen­yl)porphyrin nitro­benzene disolvate
title_short Crystal structure of meso-tetra­kis­(4-nitro­phen­yl)porphyrin nitro­benzene disolvate
title_sort crystal structure of meso-tetra­kis­(4-nitro­phen­yl)porphyrin nitro­benzene disolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257332/
https://www.ncbi.nlm.nih.gov/pubmed/25484793
http://dx.doi.org/10.1107/S1600536814021503
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