Crystal structure of 1,6-di­thia­cyclo­deca-cis-3,cis-8-diene (DTCDD)

The title compound, C(8)H(12)S(2) (trivial name DTCDD), was obtained as a side product of the reaction between cis-1,4-di­chloro­but-2-ene and sodium sulfide. The asymmetric unit consists of one-quarter of the mol­ecule (S site symmetry 2) and the complete mol­ecule has 2/m (C (2h)) point symmetry w...

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Detalles Bibliográficos
Autores principales: Baughman, Russell G., Delanty, Molly C., Ortwerth, Michael F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257335/
https://www.ncbi.nlm.nih.gov/pubmed/25484838
http://dx.doi.org/10.1107/S1600536814023319
Descripción
Sumario:The title compound, C(8)H(12)S(2) (trivial name DTCDD), was obtained as a side product of the reaction between cis-1,4-di­chloro­but-2-ene and sodium sulfide. The asymmetric unit consists of one-quarter of the mol­ecule (S site symmetry 2) and the complete mol­ecule has 2/m (C (2h)) point symmetry with the C=C bond in an E conformation. The geometry of the title compound is compared to those of a chloro derivative and a mercury complex.

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