Crystal structure of 1,6-di­thia­cyclo­deca-cis-3,cis-8-diene (DTCDD)

The title compound, C(8)H(12)S(2) (trivial name DTCDD), was obtained as a side product of the reaction between cis-1,4-di­chloro­but-2-ene and sodium sulfide. The asymmetric unit consists of one-quarter of the mol­ecule (S site symmetry 2) and the complete mol­ecule has 2/m (C (2h)) point symmetry w...

Descripción completa

Detalles Bibliográficos
Autores principales: Baughman, Russell G., Delanty, Molly C., Ortwerth, Michael F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257335/
https://www.ncbi.nlm.nih.gov/pubmed/25484838
http://dx.doi.org/10.1107/S1600536814023319
_version_ 1782347730614484992
author Baughman, Russell G.
Delanty, Molly C.
Ortwerth, Michael F.
author_facet Baughman, Russell G.
Delanty, Molly C.
Ortwerth, Michael F.
author_sort Baughman, Russell G.
collection PubMed
description The title compound, C(8)H(12)S(2) (trivial name DTCDD), was obtained as a side product of the reaction between cis-1,4-di­chloro­but-2-ene and sodium sulfide. The asymmetric unit consists of one-quarter of the mol­ecule (S site symmetry 2) and the complete mol­ecule has 2/m (C (2h)) point symmetry with the C=C bond in an E conformation. The geometry of the title compound is compared to those of a chloro derivative and a mercury complex.
format Online
Article
Text
id pubmed-4257335
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-42573352014-12-05 Crystal structure of 1,6-di­thia­cyclo­deca-cis-3,cis-8-diene (DTCDD) Baughman, Russell G. Delanty, Molly C. Ortwerth, Michael F. Acta Crystallogr Sect E Struct Rep Online Data Reports The title compound, C(8)H(12)S(2) (trivial name DTCDD), was obtained as a side product of the reaction between cis-1,4-di­chloro­but-2-ene and sodium sulfide. The asymmetric unit consists of one-quarter of the mol­ecule (S site symmetry 2) and the complete mol­ecule has 2/m (C (2h)) point symmetry with the C=C bond in an E conformation. The geometry of the title compound is compared to those of a chloro derivative and a mercury complex. International Union of Crystallography 2014-10-31 /pmc/articles/PMC4257335/ /pubmed/25484838 http://dx.doi.org/10.1107/S1600536814023319 Text en © Baughman et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Baughman, Russell G.
Delanty, Molly C.
Ortwerth, Michael F.
Crystal structure of 1,6-di­thia­cyclo­deca-cis-3,cis-8-diene (DTCDD)
title Crystal structure of 1,6-di­thia­cyclo­deca-cis-3,cis-8-diene (DTCDD)
title_full Crystal structure of 1,6-di­thia­cyclo­deca-cis-3,cis-8-diene (DTCDD)
title_fullStr Crystal structure of 1,6-di­thia­cyclo­deca-cis-3,cis-8-diene (DTCDD)
title_full_unstemmed Crystal structure of 1,6-di­thia­cyclo­deca-cis-3,cis-8-diene (DTCDD)
title_short Crystal structure of 1,6-di­thia­cyclo­deca-cis-3,cis-8-diene (DTCDD)
title_sort crystal structure of 1,6-di­thia­cyclo­deca-cis-3,cis-8-diene (dtcdd)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257335/
https://www.ncbi.nlm.nih.gov/pubmed/25484838
http://dx.doi.org/10.1107/S1600536814023319
work_keys_str_mv AT baughmanrussellg crystalstructureof16dithiacyclodecacis3cis8dienedtcdd
AT delantymollyc crystalstructureof16dithiacyclodecacis3cis8dienedtcdd
AT ortwerthmichaelf crystalstructureof16dithiacyclodecacis3cis8dienedtcdd

Ejemplares similares