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Crystal structure of di­chlorido­{2-[(2-hy­droxyeth­yl)(pyridin-2-ylmeth­yl)amino]­ethano­lato-κ(4) N,N′,O,O′}iron(III) dihydrate from synchrotron data

In the title compound, [Fe(C(10)H(15)N(2)O(2))Cl(2)]·2H(2)O, the Fe(III) ion is coordinated by two N and two O atoms of the tetra­dentate 2-{(2-hy­droxy­eth­yl)(pyridin-2-ylmeth­yl)amino}­ethano­late ligand and by two chloride anions, resulting in a distorted octa­hedral coordination sphere. The ave...

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Autores principales: Shin, Jong Won, Kim, Dae-Woong, Moon, Dohyun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257339/
https://www.ncbi.nlm.nih.gov/pubmed/25484738
http://dx.doi.org/10.1107/S1600536814022089
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author Shin, Jong Won
Kim, Dae-Woong
Moon, Dohyun
author_facet Shin, Jong Won
Kim, Dae-Woong
Moon, Dohyun
author_sort Shin, Jong Won
collection PubMed
description In the title compound, [Fe(C(10)H(15)N(2)O(2))Cl(2)]·2H(2)O, the Fe(III) ion is coordinated by two N and two O atoms of the tetra­dentate 2-{(2-hy­droxy­eth­yl)(pyridin-2-ylmeth­yl)amino}­ethano­late ligand and by two chloride anions, resulting in a distorted octa­hedral coordination sphere. The average Fe—X (X = ligand N and O atoms) and Fe—Cl bond lengths are 2.10 and 2.32 Å, respectively. In the crystal, duplex O—H⋯O hydrogen bonds between the hydroxyl and eth­oxy groups of two neighbouring complexes give rise to a dimeric unit. The dimers are connected to the lattice water mol­ecules (one of which is equally disordered over two sets of sites) through O—H⋯Cl hydrogen bonds, forming undulating sheets parallel to (010). Weak C—H⋯Cl hydrogen bonds are also observed.
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spelling pubmed-42573392014-12-05 Crystal structure of di­chlorido­{2-[(2-hy­droxyeth­yl)(pyridin-2-ylmeth­yl)amino]­ethano­lato-κ(4) N,N′,O,O′}iron(III) dihydrate from synchrotron data Shin, Jong Won Kim, Dae-Woong Moon, Dohyun Acta Crystallogr Sect E Struct Rep Online Research Communications In the title compound, [Fe(C(10)H(15)N(2)O(2))Cl(2)]·2H(2)O, the Fe(III) ion is coordinated by two N and two O atoms of the tetra­dentate 2-{(2-hy­droxy­eth­yl)(pyridin-2-ylmeth­yl)amino}­ethano­late ligand and by two chloride anions, resulting in a distorted octa­hedral coordination sphere. The average Fe—X (X = ligand N and O atoms) and Fe—Cl bond lengths are 2.10 and 2.32 Å, respectively. In the crystal, duplex O—H⋯O hydrogen bonds between the hydroxyl and eth­oxy groups of two neighbouring complexes give rise to a dimeric unit. The dimers are connected to the lattice water mol­ecules (one of which is equally disordered over two sets of sites) through O—H⋯Cl hydrogen bonds, forming undulating sheets parallel to (010). Weak C—H⋯Cl hydrogen bonds are also observed. International Union of Crystallography 2014-10-11 /pmc/articles/PMC4257339/ /pubmed/25484738 http://dx.doi.org/10.1107/S1600536814022089 Text en © Shin et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Shin, Jong Won
Kim, Dae-Woong
Moon, Dohyun
Crystal structure of di­chlorido­{2-[(2-hy­droxyeth­yl)(pyridin-2-ylmeth­yl)amino]­ethano­lato-κ(4) N,N′,O,O′}iron(III) dihydrate from synchrotron data
title Crystal structure of di­chlorido­{2-[(2-hy­droxyeth­yl)(pyridin-2-ylmeth­yl)amino]­ethano­lato-κ(4) N,N′,O,O′}iron(III) dihydrate from synchrotron data
title_full Crystal structure of di­chlorido­{2-[(2-hy­droxyeth­yl)(pyridin-2-ylmeth­yl)amino]­ethano­lato-κ(4) N,N′,O,O′}iron(III) dihydrate from synchrotron data
title_fullStr Crystal structure of di­chlorido­{2-[(2-hy­droxyeth­yl)(pyridin-2-ylmeth­yl)amino]­ethano­lato-κ(4) N,N′,O,O′}iron(III) dihydrate from synchrotron data
title_full_unstemmed Crystal structure of di­chlorido­{2-[(2-hy­droxyeth­yl)(pyridin-2-ylmeth­yl)amino]­ethano­lato-κ(4) N,N′,O,O′}iron(III) dihydrate from synchrotron data
title_short Crystal structure of di­chlorido­{2-[(2-hy­droxyeth­yl)(pyridin-2-ylmeth­yl)amino]­ethano­lato-κ(4) N,N′,O,O′}iron(III) dihydrate from synchrotron data
title_sort crystal structure of di­chlorido­{2-[(2-hy­droxyeth­yl)(pyridin-2-ylmeth­yl)amino]­ethano­lato-κ(4) n,n′,o,o′}iron(iii) dihydrate from synchrotron data
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257339/
https://www.ncbi.nlm.nih.gov/pubmed/25484738
http://dx.doi.org/10.1107/S1600536814022089
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