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Crystal structure of dichlorido{2-[(2-hydroxyethyl)(pyridin-2-ylmethyl)amino]ethanolato-κ(4) N,N′,O,O′}iron(III) dihydrate from synchrotron data
In the title compound, [Fe(C(10)H(15)N(2)O(2))Cl(2)]·2H(2)O, the Fe(III) ion is coordinated by two N and two O atoms of the tetradentate 2-{(2-hydroxyethyl)(pyridin-2-ylmethyl)amino}ethanolate ligand and by two chloride anions, resulting in a distorted octahedral coordination sphere. The ave...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257339/ https://www.ncbi.nlm.nih.gov/pubmed/25484738 http://dx.doi.org/10.1107/S1600536814022089 |
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author | Shin, Jong Won Kim, Dae-Woong Moon, Dohyun |
author_facet | Shin, Jong Won Kim, Dae-Woong Moon, Dohyun |
author_sort | Shin, Jong Won |
collection | PubMed |
description | In the title compound, [Fe(C(10)H(15)N(2)O(2))Cl(2)]·2H(2)O, the Fe(III) ion is coordinated by two N and two O atoms of the tetradentate 2-{(2-hydroxyethyl)(pyridin-2-ylmethyl)amino}ethanolate ligand and by two chloride anions, resulting in a distorted octahedral coordination sphere. The average Fe—X (X = ligand N and O atoms) and Fe—Cl bond lengths are 2.10 and 2.32 Å, respectively. In the crystal, duplex O—H⋯O hydrogen bonds between the hydroxyl and ethoxy groups of two neighbouring complexes give rise to a dimeric unit. The dimers are connected to the lattice water molecules (one of which is equally disordered over two sets of sites) through O—H⋯Cl hydrogen bonds, forming undulating sheets parallel to (010). Weak C—H⋯Cl hydrogen bonds are also observed. |
format | Online Article Text |
id | pubmed-4257339 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42573392014-12-05 Crystal structure of dichlorido{2-[(2-hydroxyethyl)(pyridin-2-ylmethyl)amino]ethanolato-κ(4) N,N′,O,O′}iron(III) dihydrate from synchrotron data Shin, Jong Won Kim, Dae-Woong Moon, Dohyun Acta Crystallogr Sect E Struct Rep Online Research Communications In the title compound, [Fe(C(10)H(15)N(2)O(2))Cl(2)]·2H(2)O, the Fe(III) ion is coordinated by two N and two O atoms of the tetradentate 2-{(2-hydroxyethyl)(pyridin-2-ylmethyl)amino}ethanolate ligand and by two chloride anions, resulting in a distorted octahedral coordination sphere. The average Fe—X (X = ligand N and O atoms) and Fe—Cl bond lengths are 2.10 and 2.32 Å, respectively. In the crystal, duplex O—H⋯O hydrogen bonds between the hydroxyl and ethoxy groups of two neighbouring complexes give rise to a dimeric unit. The dimers are connected to the lattice water molecules (one of which is equally disordered over two sets of sites) through O—H⋯Cl hydrogen bonds, forming undulating sheets parallel to (010). Weak C—H⋯Cl hydrogen bonds are also observed. International Union of Crystallography 2014-10-11 /pmc/articles/PMC4257339/ /pubmed/25484738 http://dx.doi.org/10.1107/S1600536814022089 Text en © Shin et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Shin, Jong Won Kim, Dae-Woong Moon, Dohyun Crystal structure of dichlorido{2-[(2-hydroxyethyl)(pyridin-2-ylmethyl)amino]ethanolato-κ(4) N,N′,O,O′}iron(III) dihydrate from synchrotron data |
title | Crystal structure of dichlorido{2-[(2-hydroxyethyl)(pyridin-2-ylmethyl)amino]ethanolato-κ(4)
N,N′,O,O′}iron(III) dihydrate from synchrotron data |
title_full | Crystal structure of dichlorido{2-[(2-hydroxyethyl)(pyridin-2-ylmethyl)amino]ethanolato-κ(4)
N,N′,O,O′}iron(III) dihydrate from synchrotron data |
title_fullStr | Crystal structure of dichlorido{2-[(2-hydroxyethyl)(pyridin-2-ylmethyl)amino]ethanolato-κ(4)
N,N′,O,O′}iron(III) dihydrate from synchrotron data |
title_full_unstemmed | Crystal structure of dichlorido{2-[(2-hydroxyethyl)(pyridin-2-ylmethyl)amino]ethanolato-κ(4)
N,N′,O,O′}iron(III) dihydrate from synchrotron data |
title_short | Crystal structure of dichlorido{2-[(2-hydroxyethyl)(pyridin-2-ylmethyl)amino]ethanolato-κ(4)
N,N′,O,O′}iron(III) dihydrate from synchrotron data |
title_sort | crystal structure of dichlorido{2-[(2-hydroxyethyl)(pyridin-2-ylmethyl)amino]ethanolato-κ(4)
n,n′,o,o′}iron(iii) dihydrate from synchrotron data |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257339/ https://www.ncbi.nlm.nih.gov/pubmed/25484738 http://dx.doi.org/10.1107/S1600536814022089 |
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