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Crystal structure of poly[μ-acetato-bis­[μ-2-oxo-2-(quinolin-8-yl)ethano­ato]tris­odium]

The title compound [Na(3)(C(11)H(6)NO(3))(2)(C(2)H(3)O(2))](n), crystallized through diffusion of diethyl ether into methanol as needles. There are three crystallographically independent Na(+) cations present, each exhib­it­ing a distorted octa­hedral coordination geometry, two through coordination...

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Detalles Bibliográficos
Autores principales: Nicholls, Rachel L., Pask, Christopher M., Nguyen, Bao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257345/
https://www.ncbi.nlm.nih.gov/pubmed/25484788
http://dx.doi.org/10.1107/S1600536814023423
Descripción
Sumario:The title compound [Na(3)(C(11)H(6)NO(3))(2)(C(2)H(3)O(2))](n), crystallized through diffusion of diethyl ether into methanol as needles. There are three crystallographically independent Na(+) cations present, each exhib­it­ing a distorted octa­hedral coordination geometry, two through coordination by five O atoms and one N atom, and one through coordination by six O atoms. A series of inter­molecular O⋯Na and N⋯Na contacts leads to the formation of chains along the a-axis direction.