Cargando…
Crystal structure of poly[μ-acetato-bis[μ-2-oxo-2-(quinolin-8-yl)ethanoato]trisodium]
The title compound [Na(3)(C(11)H(6)NO(3))(2)(C(2)H(3)O(2))](n), crystallized through diffusion of diethyl ether into methanol as needles. There are three crystallographically independent Na(+) cations present, each exhibiting a distorted octahedral coordination geometry, two through coordination...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257345/ https://www.ncbi.nlm.nih.gov/pubmed/25484788 http://dx.doi.org/10.1107/S1600536814023423 |
_version_ | 1782347732969586688 |
---|---|
author | Nicholls, Rachel L. Pask, Christopher M. Nguyen, Bao |
author_facet | Nicholls, Rachel L. Pask, Christopher M. Nguyen, Bao |
author_sort | Nicholls, Rachel L. |
collection | PubMed |
description | The title compound [Na(3)(C(11)H(6)NO(3))(2)(C(2)H(3)O(2))](n), crystallized through diffusion of diethyl ether into methanol as needles. There are three crystallographically independent Na(+) cations present, each exhibiting a distorted octahedral coordination geometry, two through coordination by five O atoms and one N atom, and one through coordination by six O atoms. A series of intermolecular O⋯Na and N⋯Na contacts leads to the formation of chains along the a-axis direction. |
format | Online Article Text |
id | pubmed-4257345 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42573452014-12-05 Crystal structure of poly[μ-acetato-bis[μ-2-oxo-2-(quinolin-8-yl)ethanoato]trisodium] Nicholls, Rachel L. Pask, Christopher M. Nguyen, Bao Acta Crystallogr Sect E Struct Rep Online Data Reports The title compound [Na(3)(C(11)H(6)NO(3))(2)(C(2)H(3)O(2))](n), crystallized through diffusion of diethyl ether into methanol as needles. There are three crystallographically independent Na(+) cations present, each exhibiting a distorted octahedral coordination geometry, two through coordination by five O atoms and one N atom, and one through coordination by six O atoms. A series of intermolecular O⋯Na and N⋯Na contacts leads to the formation of chains along the a-axis direction. International Union of Crystallography 2014-10-31 /pmc/articles/PMC4257345/ /pubmed/25484788 http://dx.doi.org/10.1107/S1600536814023423 Text en © Nicholls et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Nicholls, Rachel L. Pask, Christopher M. Nguyen, Bao Crystal structure of poly[μ-acetato-bis[μ-2-oxo-2-(quinolin-8-yl)ethanoato]trisodium] |
title | Crystal structure of poly[μ-acetato-bis[μ-2-oxo-2-(quinolin-8-yl)ethanoato]trisodium] |
title_full | Crystal structure of poly[μ-acetato-bis[μ-2-oxo-2-(quinolin-8-yl)ethanoato]trisodium] |
title_fullStr | Crystal structure of poly[μ-acetato-bis[μ-2-oxo-2-(quinolin-8-yl)ethanoato]trisodium] |
title_full_unstemmed | Crystal structure of poly[μ-acetato-bis[μ-2-oxo-2-(quinolin-8-yl)ethanoato]trisodium] |
title_short | Crystal structure of poly[μ-acetato-bis[μ-2-oxo-2-(quinolin-8-yl)ethanoato]trisodium] |
title_sort | crystal structure of poly[μ-acetato-bis[μ-2-oxo-2-(quinolin-8-yl)ethanoato]trisodium] |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257345/ https://www.ncbi.nlm.nih.gov/pubmed/25484788 http://dx.doi.org/10.1107/S1600536814023423 |
work_keys_str_mv | AT nichollsrachell crystalstructureofpolymacetatobism2oxo2quinolin8ylethanoatotrisodium AT paskchristopherm crystalstructureofpolymacetatobism2oxo2quinolin8ylethanoatotrisodium AT nguyenbao crystalstructureofpolymacetatobism2oxo2quinolin8ylethanoatotrisodium |