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Crystal structure of chlorido(η(2)-phenyl isothiocyanate-κ(2) C,S)-mer-tris(trimethylphosphane-κP)iridium(I)
The molecule of the title compound, [IrCl(C(7)H(5)NS)(C(3)H(9)P)(3)], is a distorted octahedral iridium complex with three PMe(3) ligands arranged in a meridional geometry, a chloride ion cis to all three PMe(3) groups and the phenyl isothiocyanate ligand bonded in an η(2)-fashion through the C a...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257346/ https://www.ncbi.nlm.nih.gov/pubmed/25484743 http://dx.doi.org/10.1107/S160053681402162X |
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| author | Merola, Joseph S. Grieb, Arthur W. |
| author_facet | Merola, Joseph S. Grieb, Arthur W. |
| author_sort | Merola, Joseph S. |
| collection | PubMed |
| description | The molecule of the title compound, [IrCl(C(7)H(5)NS)(C(3)H(9)P)(3)], is a distorted octahedral iridium complex with three PMe(3) ligands arranged in a meridional geometry, a chloride ion cis to all three PMe(3) groups and the phenyl isothiocyanate ligand bonded in an η(2)-fashion through the C and S atoms. The C atom is trans to the chloride ion and the S atom is responsible for a significant deviation from an ideal octahedral geometry. The geometric parameters for the metal-complexing phenyl isothiocyanate group are compared with other metal-complexed phenyl isothiocyanates, as well as with examples of uncomplexed aryl isothiocyanates. |
| format | Online Article Text |
| id | pubmed-4257346 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-42573462014-12-05 Crystal structure of chlorido(η(2)-phenyl isothiocyanate-κ(2) C,S)-mer-tris(trimethylphosphane-κP)iridium(I) Merola, Joseph S. Grieb, Arthur W. Acta Crystallogr Sect E Struct Rep Online Research Communications The molecule of the title compound, [IrCl(C(7)H(5)NS)(C(3)H(9)P)(3)], is a distorted octahedral iridium complex with three PMe(3) ligands arranged in a meridional geometry, a chloride ion cis to all three PMe(3) groups and the phenyl isothiocyanate ligand bonded in an η(2)-fashion through the C and S atoms. The C atom is trans to the chloride ion and the S atom is responsible for a significant deviation from an ideal octahedral geometry. The geometric parameters for the metal-complexing phenyl isothiocyanate group are compared with other metal-complexed phenyl isothiocyanates, as well as with examples of uncomplexed aryl isothiocyanates. International Union of Crystallography 2014-10-18 /pmc/articles/PMC4257346/ /pubmed/25484743 http://dx.doi.org/10.1107/S160053681402162X Text en © Merola and Grieb 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Merola, Joseph S. Grieb, Arthur W. Crystal structure of chlorido(η(2)-phenyl isothiocyanate-κ(2) C,S)-mer-tris(trimethylphosphane-κP)iridium(I) |
| title | Crystal structure of chlorido(η(2)-phenyl isothiocyanate-κ(2)
C,S)-mer-tris(trimethylphosphane-κP)iridium(I) |
| title_full | Crystal structure of chlorido(η(2)-phenyl isothiocyanate-κ(2)
C,S)-mer-tris(trimethylphosphane-κP)iridium(I) |
| title_fullStr | Crystal structure of chlorido(η(2)-phenyl isothiocyanate-κ(2)
C,S)-mer-tris(trimethylphosphane-κP)iridium(I) |
| title_full_unstemmed | Crystal structure of chlorido(η(2)-phenyl isothiocyanate-κ(2)
C,S)-mer-tris(trimethylphosphane-κP)iridium(I) |
| title_short | Crystal structure of chlorido(η(2)-phenyl isothiocyanate-κ(2)
C,S)-mer-tris(trimethylphosphane-κP)iridium(I) |
| title_sort | crystal structure of chlorido(η(2)-phenyl isothiocyanate-κ(2)
c,s)-mer-tris(trimethylphosphane-κp)iridium(i) |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257346/ https://www.ncbi.nlm.nih.gov/pubmed/25484743 http://dx.doi.org/10.1107/S160053681402162X |
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