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Crystal structure of (5-methylimidazo[1,2-a]pyridin-2-yl)methanol
In the title compound, C(9)H(10)N(2)O, the imidazo[1,2-a]pyridine moiety is approximately planar (r.m.s. deviation = 0.024 Å). The methanol group is nearly perpendicular to its mean plane as indicated by the C—C—C—O and N—C—C—O torsion angles of 80.04 (16) and −96.30 (17)°, respectively. In the crys...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257347/ https://www.ncbi.nlm.nih.gov/pubmed/25484822 http://dx.doi.org/10.1107/S1600536814023022 |
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author | Elaatiaoui, Abdelmalik Koudad, Mohammed Saddik, Rafik Benchat, Noureddine El Ammari, Lahcen |
author_facet | Elaatiaoui, Abdelmalik Koudad, Mohammed Saddik, Rafik Benchat, Noureddine El Ammari, Lahcen |
author_sort | Elaatiaoui, Abdelmalik |
collection | PubMed |
description | In the title compound, C(9)H(10)N(2)O, the imidazo[1,2-a]pyridine moiety is approximately planar (r.m.s. deviation = 0.024 Å). The methanol group is nearly perpendicular to its mean plane as indicated by the C—C—C—O and N—C—C—O torsion angles of 80.04 (16) and −96.30 (17)°, respectively. In the crystal, molecules are linked by O—H⋯N hydrogen bonds, forming inversion dimers with an R (2) (2)(10) ring motif. The dimers are liked via C—H⋯O hydrogen bonds, enclosing R (2) (2)(10) ring motifs and forming ribbons along [201]. The ribbons are linked via a number of π–π interactions [centroid–centroid distances vary from 3.4819 (8) to 3.7212 (8) Å], forming a three-dimensional structure. |
format | Online Article Text |
id | pubmed-4257347 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42573472014-12-05 Crystal structure of (5-methylimidazo[1,2-a]pyridin-2-yl)methanol Elaatiaoui, Abdelmalik Koudad, Mohammed Saddik, Rafik Benchat, Noureddine El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(9)H(10)N(2)O, the imidazo[1,2-a]pyridine moiety is approximately planar (r.m.s. deviation = 0.024 Å). The methanol group is nearly perpendicular to its mean plane as indicated by the C—C—C—O and N—C—C—O torsion angles of 80.04 (16) and −96.30 (17)°, respectively. In the crystal, molecules are linked by O—H⋯N hydrogen bonds, forming inversion dimers with an R (2) (2)(10) ring motif. The dimers are liked via C—H⋯O hydrogen bonds, enclosing R (2) (2)(10) ring motifs and forming ribbons along [201]. The ribbons are linked via a number of π–π interactions [centroid–centroid distances vary from 3.4819 (8) to 3.7212 (8) Å], forming a three-dimensional structure. International Union of Crystallography 2014-10-24 /pmc/articles/PMC4257347/ /pubmed/25484822 http://dx.doi.org/10.1107/S1600536814023022 Text en © Elaatiaoui et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Elaatiaoui, Abdelmalik Koudad, Mohammed Saddik, Rafik Benchat, Noureddine El Ammari, Lahcen Crystal structure of (5-methylimidazo[1,2-a]pyridin-2-yl)methanol |
title | Crystal structure of (5-methylimidazo[1,2-a]pyridin-2-yl)methanol |
title_full | Crystal structure of (5-methylimidazo[1,2-a]pyridin-2-yl)methanol |
title_fullStr | Crystal structure of (5-methylimidazo[1,2-a]pyridin-2-yl)methanol |
title_full_unstemmed | Crystal structure of (5-methylimidazo[1,2-a]pyridin-2-yl)methanol |
title_short | Crystal structure of (5-methylimidazo[1,2-a]pyridin-2-yl)methanol |
title_sort | crystal structure of (5-methylimidazo[1,2-a]pyridin-2-yl)methanol |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257347/ https://www.ncbi.nlm.nih.gov/pubmed/25484822 http://dx.doi.org/10.1107/S1600536814023022 |
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