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Crystal structure of (5-methyl­imidazo[1,2-a]pyridin-2-yl)methanol

In the title compound, C(9)H(10)N(2)O, the imidazo[1,2-a]pyridine moiety is approximately planar (r.m.s. deviation = 0.024 Å). The methanol group is nearly perpendicular to its mean plane as indicated by the C—C—C—O and N—C—C—O torsion angles of 80.04 (16) and −96.30 (17)°, respectively. In the crys...

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Autores principales: Elaatiaoui, Abdelmalik, Koudad, Mohammed, Saddik, Rafik, Benchat, Noureddine, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257347/
https://www.ncbi.nlm.nih.gov/pubmed/25484822
http://dx.doi.org/10.1107/S1600536814023022
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author Elaatiaoui, Abdelmalik
Koudad, Mohammed
Saddik, Rafik
Benchat, Noureddine
El Ammari, Lahcen
author_facet Elaatiaoui, Abdelmalik
Koudad, Mohammed
Saddik, Rafik
Benchat, Noureddine
El Ammari, Lahcen
author_sort Elaatiaoui, Abdelmalik
collection PubMed
description In the title compound, C(9)H(10)N(2)O, the imidazo[1,2-a]pyridine moiety is approximately planar (r.m.s. deviation = 0.024 Å). The methanol group is nearly perpendicular to its mean plane as indicated by the C—C—C—O and N—C—C—O torsion angles of 80.04 (16) and −96.30 (17)°, respectively. In the crystal, mol­ecules are linked by O—H⋯N hydrogen bonds, forming inversion dimers with an R (2) (2)(10) ring motif. The dimers are liked via C—H⋯O hydrogen bonds, enclosing R (2) (2)(10) ring motifs and forming ribbons along [201]. The ribbons are linked via a number of π–π inter­actions [centroid–centroid distances vary from 3.4819 (8) to 3.7212 (8) Å], forming a three-dimensional structure.
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spelling pubmed-42573472014-12-05 Crystal structure of (5-methyl­imidazo[1,2-a]pyridin-2-yl)methanol Elaatiaoui, Abdelmalik Koudad, Mohammed Saddik, Rafik Benchat, Noureddine El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(9)H(10)N(2)O, the imidazo[1,2-a]pyridine moiety is approximately planar (r.m.s. deviation = 0.024 Å). The methanol group is nearly perpendicular to its mean plane as indicated by the C—C—C—O and N—C—C—O torsion angles of 80.04 (16) and −96.30 (17)°, respectively. In the crystal, mol­ecules are linked by O—H⋯N hydrogen bonds, forming inversion dimers with an R (2) (2)(10) ring motif. The dimers are liked via C—H⋯O hydrogen bonds, enclosing R (2) (2)(10) ring motifs and forming ribbons along [201]. The ribbons are linked via a number of π–π inter­actions [centroid–centroid distances vary from 3.4819 (8) to 3.7212 (8) Å], forming a three-dimensional structure. International Union of Crystallography 2014-10-24 /pmc/articles/PMC4257347/ /pubmed/25484822 http://dx.doi.org/10.1107/S1600536814023022 Text en © Elaatiaoui et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Elaatiaoui, Abdelmalik
Koudad, Mohammed
Saddik, Rafik
Benchat, Noureddine
El Ammari, Lahcen
Crystal structure of (5-methyl­imidazo[1,2-a]pyridin-2-yl)methanol
title Crystal structure of (5-methyl­imidazo[1,2-a]pyridin-2-yl)methanol
title_full Crystal structure of (5-methyl­imidazo[1,2-a]pyridin-2-yl)methanol
title_fullStr Crystal structure of (5-methyl­imidazo[1,2-a]pyridin-2-yl)methanol
title_full_unstemmed Crystal structure of (5-methyl­imidazo[1,2-a]pyridin-2-yl)methanol
title_short Crystal structure of (5-methyl­imidazo[1,2-a]pyridin-2-yl)methanol
title_sort crystal structure of (5-methyl­imidazo[1,2-a]pyridin-2-yl)methanol
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257347/
https://www.ncbi.nlm.nih.gov/pubmed/25484822
http://dx.doi.org/10.1107/S1600536814023022
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