Crystal structure of 2,5-di­methyl­anilinium hydrogen maleate

The crystal structure of the title salt, C(8)H(12)N(+)·C(4)H(3)O(4) (−), consists of a 2,5-di­methyl­anilinium cation and an hydrogen maleate anion. In the anion, a strong intra­molecular O—H⋯O hydrogen bond is observed, leading to an S(7) graph-set motif. In the crystal, the cations and anions pack...

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Autores principales: Mathlouthi, Maha, Janzen, Daron E., Rzaigui, Mohamed, Smirani Sta, Wajda
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257352/
https://www.ncbi.nlm.nih.gov/pubmed/25484819
http://dx.doi.org/10.1107/S160053681402282X
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author Mathlouthi, Maha
Janzen, Daron E.
Rzaigui, Mohamed
Smirani Sta, Wajda
author_facet Mathlouthi, Maha
Janzen, Daron E.
Rzaigui, Mohamed
Smirani Sta, Wajda
author_sort Mathlouthi, Maha
collection PubMed
description The crystal structure of the title salt, C(8)H(12)N(+)·C(4)H(3)O(4) (−), consists of a 2,5-di­methyl­anilinium cation and an hydrogen maleate anion. In the anion, a strong intra­molecular O—H⋯O hydrogen bond is observed, leading to an S(7) graph-set motif. In the crystal, the cations and anions pack in alternating layers parallel to (001). The ammonium group undergoes inter­molecular N—H⋯O hydrogen-bonding inter­actions with the O atoms of three different hydrogen maleate anions. This results in the formation of ribbons extending parallel to [010] with hydrogen-bonding motifs of the types R (4) (4)(12) and R (4) (4)(18).
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spelling pubmed-42573522014-12-05 Crystal structure of 2,5-di­methyl­anilinium hydrogen maleate Mathlouthi, Maha Janzen, Daron E. Rzaigui, Mohamed Smirani Sta, Wajda Acta Crystallogr Sect E Struct Rep Online Data Reports The crystal structure of the title salt, C(8)H(12)N(+)·C(4)H(3)O(4) (−), consists of a 2,5-di­methyl­anilinium cation and an hydrogen maleate anion. In the anion, a strong intra­molecular O—H⋯O hydrogen bond is observed, leading to an S(7) graph-set motif. In the crystal, the cations and anions pack in alternating layers parallel to (001). The ammonium group undergoes inter­molecular N—H⋯O hydrogen-bonding inter­actions with the O atoms of three different hydrogen maleate anions. This results in the formation of ribbons extending parallel to [010] with hydrogen-bonding motifs of the types R (4) (4)(12) and R (4) (4)(18). International Union of Crystallography 2014-10-24 /pmc/articles/PMC4257352/ /pubmed/25484819 http://dx.doi.org/10.1107/S160053681402282X Text en © Mathlouthi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Mathlouthi, Maha
Janzen, Daron E.
Rzaigui, Mohamed
Smirani Sta, Wajda
Crystal structure of 2,5-di­methyl­anilinium hydrogen maleate
title Crystal structure of 2,5-di­methyl­anilinium hydrogen maleate
title_full Crystal structure of 2,5-di­methyl­anilinium hydrogen maleate
title_fullStr Crystal structure of 2,5-di­methyl­anilinium hydrogen maleate
title_full_unstemmed Crystal structure of 2,5-di­methyl­anilinium hydrogen maleate
title_short Crystal structure of 2,5-di­methyl­anilinium hydrogen maleate
title_sort crystal structure of 2,5-di­methyl­anilinium hydrogen maleate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257352/
https://www.ncbi.nlm.nih.gov/pubmed/25484819
http://dx.doi.org/10.1107/S160053681402282X
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