Crystal structure of (Z)-1-(ferrocenylethyn­yl)-10-(phenyl­imino)­anthracen-9(10H)-one from synchrotron X-ray powder diffraction

In the title compound, [Fe(C(5)H(5))(C(27)H(16)NO)], designed and synthesized to explore a new electron-donor (D) and -acceptor (A) conjugated complex, the two cyclo­penta­dienyl rings adopt an eclipsed conformation. The anthracene tricycle is distorted towards a butterfly conformation and the mean...

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Autores principales: Nishibori, Eiji, Aoyagi, Shinobu, Sakata, Makoto, Sakamoto, Ryota, Nishihara, Hiroshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257377/
https://www.ncbi.nlm.nih.gov/pubmed/25552995
http://dx.doi.org/10.1107/S1600536814025252
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author Nishibori, Eiji
Aoyagi, Shinobu
Sakata, Makoto
Sakamoto, Ryota
Nishihara, Hiroshi
author_facet Nishibori, Eiji
Aoyagi, Shinobu
Sakata, Makoto
Sakamoto, Ryota
Nishihara, Hiroshi
author_sort Nishibori, Eiji
collection PubMed
description In the title compound, [Fe(C(5)H(5))(C(27)H(16)NO)], designed and synthesized to explore a new electron-donor (D) and -acceptor (A) conjugated complex, the two cyclo­penta­dienyl rings adopt an eclipsed conformation. The anthracene tricycle is distorted towards a butterfly conformation and the mean planes of the outer benzene rings are inclined each to other at 22.7 (3)°. In the crystal, mol­ecules are paired into inversion dimers via π–π inter­actions. Weak inter­molecular C—H⋯π inter­actions link further these dimers into one-dimensional columns along the b axis, with the ferrocenylethynyl arms arranged between the stacks to fill the voids.
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spelling pubmed-42573772014-12-31 Crystal structure of (Z)-1-(ferrocenylethyn­yl)-10-(phenyl­imino)­anthracen-9(10H)-one from synchrotron X-ray powder diffraction Nishibori, Eiji Aoyagi, Shinobu Sakata, Makoto Sakamoto, Ryota Nishihara, Hiroshi Acta Crystallogr Sect E Struct Rep Online Research Communications In the title compound, [Fe(C(5)H(5))(C(27)H(16)NO)], designed and synthesized to explore a new electron-donor (D) and -acceptor (A) conjugated complex, the two cyclo­penta­dienyl rings adopt an eclipsed conformation. The anthracene tricycle is distorted towards a butterfly conformation and the mean planes of the outer benzene rings are inclined each to other at 22.7 (3)°. In the crystal, mol­ecules are paired into inversion dimers via π–π inter­actions. Weak inter­molecular C—H⋯π inter­actions link further these dimers into one-dimensional columns along the b axis, with the ferrocenylethynyl arms arranged between the stacks to fill the voids. International Union of Crystallography 2014-11-26 /pmc/articles/PMC4257377/ /pubmed/25552995 http://dx.doi.org/10.1107/S1600536814025252 Text en © Nishibori et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Nishibori, Eiji
Aoyagi, Shinobu
Sakata, Makoto
Sakamoto, Ryota
Nishihara, Hiroshi
Crystal structure of (Z)-1-(ferrocenylethyn­yl)-10-(phenyl­imino)­anthracen-9(10H)-one from synchrotron X-ray powder diffraction
title Crystal structure of (Z)-1-(ferrocenylethyn­yl)-10-(phenyl­imino)­anthracen-9(10H)-one from synchrotron X-ray powder diffraction
title_full Crystal structure of (Z)-1-(ferrocenylethyn­yl)-10-(phenyl­imino)­anthracen-9(10H)-one from synchrotron X-ray powder diffraction
title_fullStr Crystal structure of (Z)-1-(ferrocenylethyn­yl)-10-(phenyl­imino)­anthracen-9(10H)-one from synchrotron X-ray powder diffraction
title_full_unstemmed Crystal structure of (Z)-1-(ferrocenylethyn­yl)-10-(phenyl­imino)­anthracen-9(10H)-one from synchrotron X-ray powder diffraction
title_short Crystal structure of (Z)-1-(ferrocenylethyn­yl)-10-(phenyl­imino)­anthracen-9(10H)-one from synchrotron X-ray powder diffraction
title_sort crystal structure of (z)-1-(ferrocenylethyn­yl)-10-(phenyl­imino)­anthracen-9(10h)-one from synchrotron x-ray powder diffraction
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257377/
https://www.ncbi.nlm.nih.gov/pubmed/25552995
http://dx.doi.org/10.1107/S1600536814025252
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