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Crystal structure of 2-phenylethylaminium 4-nitrophenolate monohydrate
In the title hydrated molecular salt, C(8)H(12)N(+)·C(6)H(4)NO(3) (−)·H(2)O, the conformation of the side chain in the cation is anti [C—C—C—N = 179.62 (12)°] and the dihedral angle between the aromatic ring and the nitro group in the anion is 3.34 (11)°. In the crystal, the components are linked b...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257380/ https://www.ncbi.nlm.nih.gov/pubmed/25553045 http://dx.doi.org/10.1107/S1600536814025318 |
Sumario: | In the title hydrated molecular salt, C(8)H(12)N(+)·C(6)H(4)NO(3) (−)·H(2)O, the conformation of the side chain in the cation is anti [C—C—C—N = 179.62 (12)°] and the dihedral angle between the aromatic ring and the nitro group in the anion is 3.34 (11)°. In the crystal, the components are linked by O—H⋯O and N—H⋯O hydrogen bonds, generating (10-1) sheets, which feature R (4) (4)(21) loops. The sheets interact by weak aromatic π–π stacking interactions [centroid–centroid distance = 3.896 (3) Å], forming a three-dimensional network. |
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