Crystal structure of (4R,5S)-4-methyl-3-methyl­sulfinyl-5-phenyl-1,3-oxazolidin-2-one

The absolute structure of the chiral asymmetric indole precursor title compound, C(11)H(13)NO(3)S, was confirmed by refinement of the Flack and Hooft parameters and is that expected based on the starting materials for the synthesis. The phenyl group subtends a dihedral angle of 56.40 (5)° with the m...

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Autores principales: Silveira, Gustavo Pozza, da Silva, Vinicius Flores, Oliver, Allen G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257383/
https://www.ncbi.nlm.nih.gov/pubmed/25553031
http://dx.doi.org/10.1107/S1600536814024702
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author Silveira, Gustavo Pozza
da Silva, Vinicius Flores
Oliver, Allen G.
author_facet Silveira, Gustavo Pozza
da Silva, Vinicius Flores
Oliver, Allen G.
author_sort Silveira, Gustavo Pozza
collection PubMed
description The absolute structure of the chiral asymmetric indole precursor title compound, C(11)H(13)NO(3)S, was confirmed by refinement of the Flack and Hooft parameters and is that expected based on the starting materials for the synthesis. The phenyl group subtends a dihedral angle of 56.40 (5)° with the mean plane of the oxazolidinone ring, which adopts an envelope conformation, with the C atom bearing the methyl group as the flap. In the crystal, no significant directional inter­actions beyond van der Waals contacts are observed.
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spelling pubmed-42573832014-12-31 Crystal structure of (4R,5S)-4-methyl-3-methyl­sulfinyl-5-phenyl-1,3-oxazolidin-2-one Silveira, Gustavo Pozza da Silva, Vinicius Flores Oliver, Allen G. Acta Crystallogr Sect E Struct Rep Online Data Reports The absolute structure of the chiral asymmetric indole precursor title compound, C(11)H(13)NO(3)S, was confirmed by refinement of the Flack and Hooft parameters and is that expected based on the starting materials for the synthesis. The phenyl group subtends a dihedral angle of 56.40 (5)° with the mean plane of the oxazolidinone ring, which adopts an envelope conformation, with the C atom bearing the methyl group as the flap. In the crystal, no significant directional inter­actions beyond van der Waals contacts are observed. International Union of Crystallography 2014-11-15 /pmc/articles/PMC4257383/ /pubmed/25553031 http://dx.doi.org/10.1107/S1600536814024702 Text en © Silveira et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Silveira, Gustavo Pozza
da Silva, Vinicius Flores
Oliver, Allen G.
Crystal structure of (4R,5S)-4-methyl-3-methyl­sulfinyl-5-phenyl-1,3-oxazolidin-2-one
title Crystal structure of (4R,5S)-4-methyl-3-methyl­sulfinyl-5-phenyl-1,3-oxazolidin-2-one
title_full Crystal structure of (4R,5S)-4-methyl-3-methyl­sulfinyl-5-phenyl-1,3-oxazolidin-2-one
title_fullStr Crystal structure of (4R,5S)-4-methyl-3-methyl­sulfinyl-5-phenyl-1,3-oxazolidin-2-one
title_full_unstemmed Crystal structure of (4R,5S)-4-methyl-3-methyl­sulfinyl-5-phenyl-1,3-oxazolidin-2-one
title_short Crystal structure of (4R,5S)-4-methyl-3-methyl­sulfinyl-5-phenyl-1,3-oxazolidin-2-one
title_sort crystal structure of (4r,5s)-4-methyl-3-methyl­sulfinyl-5-phenyl-1,3-oxazolidin-2-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257383/
https://www.ncbi.nlm.nih.gov/pubmed/25553031
http://dx.doi.org/10.1107/S1600536814024702
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