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Crystal structure of (Z)-3-benzyloxy-6-[(2-hydroxyanilino)methylidene]cyclohexa-2,4-dien-1-one
In the title compound, C(20)H(17)NO(3), the methylidenecyclohexa-2,4-dienone moiety is approximately planar [maximum deviation = 0.0615 (10) Å] and is oriented at diherdral angles of 69.60 (7) and 1.69 (9)° to the phenyl and hydroxybenzene rings, respectively. The amino group links with the car...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257387/ https://www.ncbi.nlm.nih.gov/pubmed/25553053 http://dx.doi.org/10.1107/S1600536814024568 |
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author | Ghichi, Nadir Benboudiaf, Ali Merazig, Hocine |
author_facet | Ghichi, Nadir Benboudiaf, Ali Merazig, Hocine |
author_sort | Ghichi, Nadir |
collection | PubMed |
description | In the title compound, C(20)H(17)NO(3), the methylidenecyclohexa-2,4-dienone moiety is approximately planar [maximum deviation = 0.0615 (10) Å] and is oriented at diherdral angles of 69.60 (7) and 1.69 (9)° to the phenyl and hydroxybenzene rings, respectively. The amino group links with the carbonyl O atom via an intramolecular N—H⋯O hydrogen bond, forming an S(6) ring motif. In the crystal, the molecules are linked by O—H⋯O hydrogen bonds and weak C—H⋯O and C—H⋯π interactions, forming a three-dimensional supramolecular architecture. |
format | Online Article Text |
id | pubmed-4257387 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42573872014-12-31 Crystal structure of (Z)-3-benzyloxy-6-[(2-hydroxyanilino)methylidene]cyclohexa-2,4-dien-1-one Ghichi, Nadir Benboudiaf, Ali Merazig, Hocine Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(20)H(17)NO(3), the methylidenecyclohexa-2,4-dienone moiety is approximately planar [maximum deviation = 0.0615 (10) Å] and is oriented at diherdral angles of 69.60 (7) and 1.69 (9)° to the phenyl and hydroxybenzene rings, respectively. The amino group links with the carbonyl O atom via an intramolecular N—H⋯O hydrogen bond, forming an S(6) ring motif. In the crystal, the molecules are linked by O—H⋯O hydrogen bonds and weak C—H⋯O and C—H⋯π interactions, forming a three-dimensional supramolecular architecture. International Union of Crystallography 2014-11-26 /pmc/articles/PMC4257387/ /pubmed/25553053 http://dx.doi.org/10.1107/S1600536814024568 Text en © Ghichi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Ghichi, Nadir Benboudiaf, Ali Merazig, Hocine Crystal structure of (Z)-3-benzyloxy-6-[(2-hydroxyanilino)methylidene]cyclohexa-2,4-dien-1-one |
title | Crystal structure of (Z)-3-benzyloxy-6-[(2-hydroxyanilino)methylidene]cyclohexa-2,4-dien-1-one |
title_full | Crystal structure of (Z)-3-benzyloxy-6-[(2-hydroxyanilino)methylidene]cyclohexa-2,4-dien-1-one |
title_fullStr | Crystal structure of (Z)-3-benzyloxy-6-[(2-hydroxyanilino)methylidene]cyclohexa-2,4-dien-1-one |
title_full_unstemmed | Crystal structure of (Z)-3-benzyloxy-6-[(2-hydroxyanilino)methylidene]cyclohexa-2,4-dien-1-one |
title_short | Crystal structure of (Z)-3-benzyloxy-6-[(2-hydroxyanilino)methylidene]cyclohexa-2,4-dien-1-one |
title_sort | crystal structure of (z)-3-benzyloxy-6-[(2-hydroxyanilino)methylidene]cyclohexa-2,4-dien-1-one |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257387/ https://www.ncbi.nlm.nih.gov/pubmed/25553053 http://dx.doi.org/10.1107/S1600536814024568 |
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