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Crystal structure of (Z)-3-benz­yloxy-6-[(2-hy­droxy­anilino)methyl­idene]cyclo­hexa-2,4-dien-1-one

In the title compound, C(20)H(17)NO(3), the methyl­idene­cyclo­hexa-2,4-dienone moiety is approximately planar [maximum deviation = 0.0615 (10) Å] and is oriented at diherdral angles of 69.60 (7) and 1.69 (9)° to the phenyl and hy­droxy­benzene rings, respectively. The amino group links with the car...

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Detalles Bibliográficos
Autores principales: Ghichi, Nadir, Benboudiaf, Ali, Merazig, Hocine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257387/
https://www.ncbi.nlm.nih.gov/pubmed/25553053
http://dx.doi.org/10.1107/S1600536814024568
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author Ghichi, Nadir
Benboudiaf, Ali
Merazig, Hocine
author_facet Ghichi, Nadir
Benboudiaf, Ali
Merazig, Hocine
author_sort Ghichi, Nadir
collection PubMed
description In the title compound, C(20)H(17)NO(3), the methyl­idene­cyclo­hexa-2,4-dienone moiety is approximately planar [maximum deviation = 0.0615 (10) Å] and is oriented at diherdral angles of 69.60 (7) and 1.69 (9)° to the phenyl and hy­droxy­benzene rings, respectively. The amino group links with the carbonyl O atom via an intra­molecular N—H⋯O hydrogen bond, forming an S(6) ring motif. In the crystal, the mol­ecules are linked by O—H⋯O hydrogen bonds and weak C—H⋯O and C—H⋯π inter­actions, forming a three-dimensional supra­molecular architecture.
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spelling pubmed-42573872014-12-31 Crystal structure of (Z)-3-benz­yloxy-6-[(2-hy­droxy­anilino)methyl­idene]cyclo­hexa-2,4-dien-1-one Ghichi, Nadir Benboudiaf, Ali Merazig, Hocine Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(20)H(17)NO(3), the methyl­idene­cyclo­hexa-2,4-dienone moiety is approximately planar [maximum deviation = 0.0615 (10) Å] and is oriented at diherdral angles of 69.60 (7) and 1.69 (9)° to the phenyl and hy­droxy­benzene rings, respectively. The amino group links with the carbonyl O atom via an intra­molecular N—H⋯O hydrogen bond, forming an S(6) ring motif. In the crystal, the mol­ecules are linked by O—H⋯O hydrogen bonds and weak C—H⋯O and C—H⋯π inter­actions, forming a three-dimensional supra­molecular architecture. International Union of Crystallography 2014-11-26 /pmc/articles/PMC4257387/ /pubmed/25553053 http://dx.doi.org/10.1107/S1600536814024568 Text en © Ghichi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ghichi, Nadir
Benboudiaf, Ali
Merazig, Hocine
Crystal structure of (Z)-3-benz­yloxy-6-[(2-hy­droxy­anilino)methyl­idene]cyclo­hexa-2,4-dien-1-one
title Crystal structure of (Z)-3-benz­yloxy-6-[(2-hy­droxy­anilino)methyl­idene]cyclo­hexa-2,4-dien-1-one
title_full Crystal structure of (Z)-3-benz­yloxy-6-[(2-hy­droxy­anilino)methyl­idene]cyclo­hexa-2,4-dien-1-one
title_fullStr Crystal structure of (Z)-3-benz­yloxy-6-[(2-hy­droxy­anilino)methyl­idene]cyclo­hexa-2,4-dien-1-one
title_full_unstemmed Crystal structure of (Z)-3-benz­yloxy-6-[(2-hy­droxy­anilino)methyl­idene]cyclo­hexa-2,4-dien-1-one
title_short Crystal structure of (Z)-3-benz­yloxy-6-[(2-hy­droxy­anilino)methyl­idene]cyclo­hexa-2,4-dien-1-one
title_sort crystal structure of (z)-3-benz­yloxy-6-[(2-hy­droxy­anilino)methyl­idene]cyclo­hexa-2,4-dien-1-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257387/
https://www.ncbi.nlm.nih.gov/pubmed/25553053
http://dx.doi.org/10.1107/S1600536814024568
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