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Crystal structure of hexakis(μ(2)-4-tert-butoxy-4-oxobut-2-en-2-olato)trizinc
The title complex, systematic name hexakis(μ(2)-4-tert-butoxy-4-oxobut-2-en-2-olato)-1:2κ(9) O (2),O (4):O (2);2:3κ(9) O (2),O (4):O (2)-trizinc, [Zn(3)(C(8)H(13)O(3))(6)], synthesized from tert-butyl acetoacetate and diethylzinc, consists of trinuclear centrosymmetric molecules of an appro...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257390/ https://www.ncbi.nlm.nih.gov/pubmed/25552972 http://dx.doi.org/10.1107/S1600536814024337 |
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author | Shtokvish, Olgerd O. Koval, Lyudmila I. Pekhnyo, Vasyl I. |
author_facet | Shtokvish, Olgerd O. Koval, Lyudmila I. Pekhnyo, Vasyl I. |
author_sort | Shtokvish, Olgerd O. |
collection | PubMed |
description | The title complex, systematic name hexakis(μ(2)-4-tert-butoxy-4-oxobut-2-en-2-olato)-1:2κ(9) O (2),O (4):O (2);2:3κ(9) O (2),O (4):O (2)-trizinc, [Zn(3)(C(8)H(13)O(3))(6)], synthesized from tert-butyl acetoacetate and diethylzinc, consists of trinuclear centrosymmetric molecules of an approximate C (3i) symmetry. The three metal cations are arranged in a linear fashion, with the central Zn(II) atom located on a centre of symmetry. All three metal cations exhibit a distorted octahedral coordination geometry. The terminal Zn(II) cations are chelated by three tert-butyl acetoacetate ligands and these units are connected to the central Zn(II) atom by the bridging enolate O atoms. |
format | Online Article Text |
id | pubmed-4257390 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42573902014-12-31 Crystal structure of hexakis(μ(2)-4-tert-butoxy-4-oxobut-2-en-2-olato)trizinc Shtokvish, Olgerd O. Koval, Lyudmila I. Pekhnyo, Vasyl I. Acta Crystallogr Sect E Struct Rep Online Research Communications The title complex, systematic name hexakis(μ(2)-4-tert-butoxy-4-oxobut-2-en-2-olato)-1:2κ(9) O (2),O (4):O (2);2:3κ(9) O (2),O (4):O (2)-trizinc, [Zn(3)(C(8)H(13)O(3))(6)], synthesized from tert-butyl acetoacetate and diethylzinc, consists of trinuclear centrosymmetric molecules of an approximate C (3i) symmetry. The three metal cations are arranged in a linear fashion, with the central Zn(II) atom located on a centre of symmetry. All three metal cations exhibit a distorted octahedral coordination geometry. The terminal Zn(II) cations are chelated by three tert-butyl acetoacetate ligands and these units are connected to the central Zn(II) atom by the bridging enolate O atoms. International Union of Crystallography 2014-11-12 /pmc/articles/PMC4257390/ /pubmed/25552972 http://dx.doi.org/10.1107/S1600536814024337 Text en © Shtokvish et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Shtokvish, Olgerd O. Koval, Lyudmila I. Pekhnyo, Vasyl I. Crystal structure of hexakis(μ(2)-4-tert-butoxy-4-oxobut-2-en-2-olato)trizinc |
title | Crystal structure of hexakis(μ(2)-4-tert-butoxy-4-oxobut-2-en-2-olato)trizinc |
title_full | Crystal structure of hexakis(μ(2)-4-tert-butoxy-4-oxobut-2-en-2-olato)trizinc |
title_fullStr | Crystal structure of hexakis(μ(2)-4-tert-butoxy-4-oxobut-2-en-2-olato)trizinc |
title_full_unstemmed | Crystal structure of hexakis(μ(2)-4-tert-butoxy-4-oxobut-2-en-2-olato)trizinc |
title_short | Crystal structure of hexakis(μ(2)-4-tert-butoxy-4-oxobut-2-en-2-olato)trizinc |
title_sort | crystal structure of hexakis(μ(2)-4-tert-butoxy-4-oxobut-2-en-2-olato)trizinc |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257390/ https://www.ncbi.nlm.nih.gov/pubmed/25552972 http://dx.doi.org/10.1107/S1600536814024337 |
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