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Crystal structure of hexa­kis­(μ(2)-4-tert-but­oxy-4-oxobut-2-en-2-olato)trizinc

The title complex, systematic name hexa­kis­(μ(2)-4-tert-but­oxy-4-oxobut-2-en-2-olato)-1:2κ(9) O (2),O (4):O (2);2:3κ(9) O (2),O (4):O (2)-trizinc, [Zn(3)(C(8)H(13)O(3))(6)], syn­the­sized from tert-butyl aceto­acetate and di­ethyl­zinc, consists of trinuclear centrosymmetric mol­ecules of an appro...

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Autores principales: Shtokvish, Olgerd O., Koval, Lyudmila I., Pekhnyo, Vasyl I.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257390/
https://www.ncbi.nlm.nih.gov/pubmed/25552972
http://dx.doi.org/10.1107/S1600536814024337
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author Shtokvish, Olgerd O.
Koval, Lyudmila I.
Pekhnyo, Vasyl I.
author_facet Shtokvish, Olgerd O.
Koval, Lyudmila I.
Pekhnyo, Vasyl I.
author_sort Shtokvish, Olgerd O.
collection PubMed
description The title complex, systematic name hexa­kis­(μ(2)-4-tert-but­oxy-4-oxobut-2-en-2-olato)-1:2κ(9) O (2),O (4):O (2);2:3κ(9) O (2),O (4):O (2)-trizinc, [Zn(3)(C(8)H(13)O(3))(6)], syn­the­sized from tert-butyl aceto­acetate and di­ethyl­zinc, consists of trinuclear centrosymmetric mol­ecules of an approximate C (3i) symmetry. The three metal cations are arranged in a linear fashion, with the central Zn(II) atom located on a centre of symmetry. All three metal cations exhibit a distorted octa­hedral coordination geometry. The terminal Zn(II) cations are chelated by three tert-butyl aceto­acetate ligands and these units are connected to the central Zn(II) atom by the bridging enolate O atoms.
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spelling pubmed-42573902014-12-31 Crystal structure of hexa­kis­(μ(2)-4-tert-but­oxy-4-oxobut-2-en-2-olato)trizinc Shtokvish, Olgerd O. Koval, Lyudmila I. Pekhnyo, Vasyl I. Acta Crystallogr Sect E Struct Rep Online Research Communications The title complex, systematic name hexa­kis­(μ(2)-4-tert-but­oxy-4-oxobut-2-en-2-olato)-1:2κ(9) O (2),O (4):O (2);2:3κ(9) O (2),O (4):O (2)-trizinc, [Zn(3)(C(8)H(13)O(3))(6)], syn­the­sized from tert-butyl aceto­acetate and di­ethyl­zinc, consists of trinuclear centrosymmetric mol­ecules of an approximate C (3i) symmetry. The three metal cations are arranged in a linear fashion, with the central Zn(II) atom located on a centre of symmetry. All three metal cations exhibit a distorted octa­hedral coordination geometry. The terminal Zn(II) cations are chelated by three tert-butyl aceto­acetate ligands and these units are connected to the central Zn(II) atom by the bridging enolate O atoms. International Union of Crystallography 2014-11-12 /pmc/articles/PMC4257390/ /pubmed/25552972 http://dx.doi.org/10.1107/S1600536814024337 Text en © Shtokvish et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Shtokvish, Olgerd O.
Koval, Lyudmila I.
Pekhnyo, Vasyl I.
Crystal structure of hexa­kis­(μ(2)-4-tert-but­oxy-4-oxobut-2-en-2-olato)trizinc
title Crystal structure of hexa­kis­(μ(2)-4-tert-but­oxy-4-oxobut-2-en-2-olato)trizinc
title_full Crystal structure of hexa­kis­(μ(2)-4-tert-but­oxy-4-oxobut-2-en-2-olato)trizinc
title_fullStr Crystal structure of hexa­kis­(μ(2)-4-tert-but­oxy-4-oxobut-2-en-2-olato)trizinc
title_full_unstemmed Crystal structure of hexa­kis­(μ(2)-4-tert-but­oxy-4-oxobut-2-en-2-olato)trizinc
title_short Crystal structure of hexa­kis­(μ(2)-4-tert-but­oxy-4-oxobut-2-en-2-olato)trizinc
title_sort crystal structure of hexa­kis­(μ(2)-4-tert-but­oxy-4-oxobut-2-en-2-olato)trizinc
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257390/
https://www.ncbi.nlm.nih.gov/pubmed/25552972
http://dx.doi.org/10.1107/S1600536814024337
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