Crystal structure of 2-(di­phenyl­phos­phanyl)phenyl 4-(hy­droxy­meth­yl)benzoate

The title compound, C(26)H(21)O(3)P, was obtained as by-product due to the hydrolysis of the desired tosyl­ated compound. The dihedral angles between the three aromatic rings attached to the P atom lie in the range 78.1 (1)–87.6 (1)°. The hy­droxy­methyl group is disordered between two conformations...

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Detalles Bibliográficos
Autores principales: Mamat, Constantin, Flemming, Anke, Köckerling, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257391/
https://www.ncbi.nlm.nih.gov/pubmed/25553051
http://dx.doi.org/10.1107/S1600536814024623
Descripción
Sumario:The title compound, C(26)H(21)O(3)P, was obtained as by-product due to the hydrolysis of the desired tosyl­ated compound. The dihedral angles between the three aromatic rings attached to the P atom lie in the range 78.1 (1)–87.6 (1)°. The hy­droxy­methyl group is disordered between two conformations in a 0.719 (9):0.281 (9) ratio. The hy­droxy H atom is not involved in inter­molecular inter­actions, while the hy­droxy O atom serves as a donor for weak C—H⋯O hydrogen bonds, which link the mol­ecules into chains propagating in [0-11].

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