Crystal structure of 2-(di­phenyl­phos­phanyl)phenyl 4-(hy­droxy­meth­yl)benzoate

The title compound, C(26)H(21)O(3)P, was obtained as by-product due to the hydrolysis of the desired tosyl­ated compound. The dihedral angles between the three aromatic rings attached to the P atom lie in the range 78.1 (1)–87.6 (1)°. The hy­droxy­methyl group is disordered between two conformations...

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Detalles Bibliográficos
Autores principales: Mamat, Constantin, Flemming, Anke, Köckerling, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257391/
https://www.ncbi.nlm.nih.gov/pubmed/25553051
http://dx.doi.org/10.1107/S1600536814024623
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author Mamat, Constantin
Flemming, Anke
Köckerling, Martin
author_facet Mamat, Constantin
Flemming, Anke
Köckerling, Martin
author_sort Mamat, Constantin
collection PubMed
description The title compound, C(26)H(21)O(3)P, was obtained as by-product due to the hydrolysis of the desired tosyl­ated compound. The dihedral angles between the three aromatic rings attached to the P atom lie in the range 78.1 (1)–87.6 (1)°. The hy­droxy­methyl group is disordered between two conformations in a 0.719 (9):0.281 (9) ratio. The hy­droxy H atom is not involved in inter­molecular inter­actions, while the hy­droxy O atom serves as a donor for weak C—H⋯O hydrogen bonds, which link the mol­ecules into chains propagating in [0-11].
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spelling pubmed-42573912014-12-31 Crystal structure of 2-(di­phenyl­phos­phanyl)phenyl 4-(hy­droxy­meth­yl)benzoate Mamat, Constantin Flemming, Anke Köckerling, Martin Acta Crystallogr Sect E Struct Rep Online Data Reports The title compound, C(26)H(21)O(3)P, was obtained as by-product due to the hydrolysis of the desired tosyl­ated compound. The dihedral angles between the three aromatic rings attached to the P atom lie in the range 78.1 (1)–87.6 (1)°. The hy­droxy­methyl group is disordered between two conformations in a 0.719 (9):0.281 (9) ratio. The hy­droxy H atom is not involved in inter­molecular inter­actions, while the hy­droxy O atom serves as a donor for weak C—H⋯O hydrogen bonds, which link the mol­ecules into chains propagating in [0-11]. International Union of Crystallography 2014-11-26 /pmc/articles/PMC4257391/ /pubmed/25553051 http://dx.doi.org/10.1107/S1600536814024623 Text en © Mamat et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Mamat, Constantin
Flemming, Anke
Köckerling, Martin
Crystal structure of 2-(di­phenyl­phos­phanyl)phenyl 4-(hy­droxy­meth­yl)benzoate
title Crystal structure of 2-(di­phenyl­phos­phanyl)phenyl 4-(hy­droxy­meth­yl)benzoate
title_full Crystal structure of 2-(di­phenyl­phos­phanyl)phenyl 4-(hy­droxy­meth­yl)benzoate
title_fullStr Crystal structure of 2-(di­phenyl­phos­phanyl)phenyl 4-(hy­droxy­meth­yl)benzoate
title_full_unstemmed Crystal structure of 2-(di­phenyl­phos­phanyl)phenyl 4-(hy­droxy­meth­yl)benzoate
title_short Crystal structure of 2-(di­phenyl­phos­phanyl)phenyl 4-(hy­droxy­meth­yl)benzoate
title_sort crystal structure of 2-(di­phenyl­phos­phanyl)phenyl 4-(hy­droxy­meth­yl)benzoate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257391/
https://www.ncbi.nlm.nih.gov/pubmed/25553051
http://dx.doi.org/10.1107/S1600536814024623
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