Cargando…

Crystal structure of (−)-(2R,3S,4R,5R)-5-(1,3-dithian-2-yl)-3-methyl-1-(triisopropylsilyloxy)hexane-2,4-diol

The title compound, C(20)H(42)O(3)S(2)Si, crystallized with two independent molecules (A and B) in the asymmetric unit. They consist of syn,anti,anti-stereotetrads with a 1,3-dithiane motif and a primary alcohol protected as the triisopropyl silyl ether. The 1,3-dithiane ring adopts a chair conf...

Descripción completa

Detalles Bibliográficos
Autores principales:	Cruz-Montanez, Alejandra, Piñero Cruz, Dalice M., Prieto, Jose A.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2014
Materias:	Data Reports
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257393/ https://www.ncbi.nlm.nih.gov/pubmed/25553049 http://dx.doi.org/10.1107/S160053681402443X

Ejemplares similares

Crystal structure of 5-(1,3-dithian-2-yl)-2H-1,3-benzodioxole
por: Zukerman-Schpector, Julio, et al.
Publicado: (2015)

Crystal structure of 2-(3-nitrophenyl)-1,3-dithiane
por: Caracelli, Ignez, et al.
Publicado: (2015)

Crystal structure of 2-(3-bromophenyl)-1,3-dithiane
por: Zukerman-Schpector, Julio, et al.
Publicado: (2015)

Crystal structure of ethyl 2-cyano-2-(1,3-dithian-2-ylidene)acetate
por: Boukhedena, Wafia, et al.
Publicado: (2018)

C—H⋯O contacts in the crystal structure of 1,3-dithiane 1,1,3,3-tetraoxide
por: Harlow, Richard L., et al.
Publicado: (2021)

(S)-5-(l-Menthyloxy)-5-[(2R,3R)-2-(l-menthyloxy)-5-oxotetrahydrofuran-3-yl]furan-2(5H)-one
por: Zhang, Bing-Bing, et al.
Publicado: (2009)

2-(1,3-Dithian-2-yl)-1,3-dithiane-2-carbaldehyde
por: Fun, Hoong-Kun, et al.
Publicado: (2008)

(1R,3S,5R,6S)-6-Acetoxy-8-methyl-3-(p-tolylsulfonyloxy)-8-azoniabicyclo[3.2.1]octane (2R,3R)-2,3-bis(benzoyloxy)-3-carboxypropanoate
por: Yang, Li-Min, et al.
Publicado: (2009)

5-[(tert-Butyldiphenylsilyloxy)methyl]pyridazin-3(2H)-one
por: Costas-Lago, María Carmen, et al.
Publicado: (2013)

[(1R,3S)-3-(1,3-Dithian-2-yl)-2,2-dimethylcyclopropyl]diphenylmethanol
por: Na, Risong, et al.
Publicado: (2009)

Crystal structure of a one-dimensional coordination polymer of tin(IV) bromide with 1,4-dithiane
por: Reuter, Hans, et al.
Publicado: (2015)

Crystal structures of 2-bromo-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane and 2-bromo-1,1,1,3,3,3-hexaisopropyl-2-(triisopropylsilyl)trisilane
por: Gulotty, Eva M., et al.
Publicado: (2018)

(1R*,2R*,4S*,5R*,6R*,8S*)-4,8-Dimethyl-2,6-diphenylbicyclo[3.3.1]nonane-2,6-diol
por: Nguyen, Vi T., et al.
Publicado: (2009)

(2R,3R,4S,5R)-2-(4-Amino-5-iodo-7H-pyrrolo[2,3-d]pyrimidin-7-yl)-5-methyltetrahydrofuran-3,4-diol
por: Flörke, Ulrich, et al.
Publicado: (2013)

1,3-Dithian-2-one azine
por: Wang, Yan-Bo, et al.
Publicado: (2010)

5-{(2S,3R,4S,5S,6R)-3,4-Dihydroxy-6-hydroxymethyl-3-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyltetrahydropyran-2-yloxy]tetrahydropyran-2-yloxy}-7-hydroxy-2-(4-hydroxyphenyl)chromen-4-one monohydrate
por: Chen, Yuzhen, et al.
Publicado: (2008)

3-Chloro-4-dimethylamino-5-[(1R,2S,5R)-2-isopropyl-5-methylcyclohexyloxy]furan-2(5H)-one
por: Song, Xiu-Mei, et al.
Publicado: (2011)

(S)-3-Bromo-4-diallylamino-5-[(1R,2S,5R)-2-isopropyl-5-methylcyclohexyloxy]furan-2(5H)-one
por: Fu, Jian-Hua, et al.
Publicado: (2010)

(5S)-3-Chloro-4-diallylamino-5-[(1R,2S,5R)-2-isopropyl-5-methylcyclohexyloxy]furan-2(5H)-one
por: Huang, Dong-Na, et al.
Publicado: (2011)

Triethylammonium (2R,3R)-2,3-bis(benzoyloxy)-3-carboxypropanoate
por: Li, Shang-Ju, et al.
Publicado: (2012)

4-(5-tert-Butyl-1,3-dithian-2-yl)-5-chloro-2-phenyl-1,3-oxazole
por: Cui, Yongliang, et al.
Publicado: (2008)

2-(Pyrene-1-yl)-1,3-dithiane
por: Fun, Hoong-Kun, et al.
Publicado: (2009)

Steviamine, a new class of indolizidine alkaloid [(1R,2S,3R,5R,8aR)-3-hydroxymethyl-5-methyloctahydroindolizine-1,2-diol hydrobromide]
por: Thompson, Amber L., et al.
Publicado: (2009)

2-Methyl-2-(3-nitrophenyl)-1,3-dithiane
por: Mirošová, Pavla, et al.
Publicado: (2012)

(±)-(4aR,5R,8S,8aR)-8-(tert-Butyldimethylsilyloxy)-2,5,8a-trimethyl-4a,5,8,8a-tetrahydronaphthalene-1,4-dione
por: Delling, Felix N., et al.
Publicado: (2013)

(1R,3S,5R,6S)-6-Acetoxy-3-(4-methylphenylsulfonyloxy)tropane
por: Yang, Li-Min, et al.
Publicado: (2008)

(5S)-3-Chloro-5-[(1R,2S,5R)-2-isopropyl-5-methylcyclohexyloxy]-4-(4-methylpiperidin-1-yl)furan-2(5H)-one
por: Wang, Xiao-Mei, et al.
Publicado: (2011)

(S)-3-Chloro-4-(4-ethylpiperazin-1-yl)-5-[(1R,2S,5R)-2-isopropyl-5-methylcyclohexyloxy]furan-2(5H)-one
por: Fu, Jian-Hua, et al.
Publicado: (2010)

Crystal structure of [(2R,3R,4S)-3,4-bis(acetyloxy)-5-iodo-3,4-dihydro-2H-pyran-2-yl]methyl acetate
por: Zukerman-Schpector, Julio, et al.
Publicado: (2015)

Comparison of the C—H⋯O bonding in two crystalline phases of 1,4-dithiane 1,1,4,4-tetraoxide
por: Harlow, Richard L., et al.
Publicado: (2019)

7-(tert-Butyldiphenylsilyloxy)-2,2-dimethyl-1-benzofuran-3(2H)-one
por: Salas, Cristian O., et al.
Publicado: (2011)

(5S)-3-Chloro-4-(2,5-dihydro-1H-pyrrol-1-yl)-5-[(1R,2S,5R)-2-isopropyl-5-methylcyclohexyloxy]furan-2(5H)-one
por: Fu, Jian-Hua, et al.
Publicado: (2010)

rac-3-[(Anilino)(naphthalen-2-yl)methyl]thian-4-one
por: Harms, Klaus, et al.
Publicado: (2012)

2-(4-Nitrophenyl)-1,3-dithiane
por: Fun, Hoong-Kun, et al.
Publicado: (2009)

Crystal structure and absolute configuration of (3aS,4S,5R,7aR)-2,2,7-trimethyl-3a,4,5,7a-tetrahydro-1,3-benzodioxole-4,5-diol
por: Macías, Mario A., et al.
Publicado: (2015)

4-[(tert-Butyldiphenylsilyloxy)methyl]pyridazin-3(2H)-one
por: Costas-Lago, María Carmen, et al.
Publicado: (2013)

(3R,3aS,6R,6aR)-3-(1-Nitroethyl)perhydrofuro[3,2-b]furan-3,6-diol
por: Zhang, Jing-Yu, et al.
Publicado: (2010)

3,3′-Di-tert-butyl-5,5′-dimethoxybiphenyl-2,2′-diol
por: Du, Zhong-Xiang, et al.
Publicado: (2009)

(9H-Fluoren-9-yl)methyl N-{(2R,3R,4S)-4-hydroxy-2-[(2S,5R)-2-isopropyl-5-methylcyclohexyloxy]-5-oxooxolan-3-yl}carbamate propan-2-ol 0.334-solvate
por: Gainsford, Graeme J., et al.
Publicado: (2012)

5-{[(3R,5aS,6R,8aS,9R,10S,12R,12aR)-3,6,9-Trimethylperhydro-3,12-epoxy-1,2-dioxepino[4,3-i]isochromen-10-yl]oxymethyl}benzene-1,3-diol
por: Gul, Waseem, et al.
Publicado: (2009)

Cannot write session to /tmp/vufind_sessions/sess_0ks1lc8nnh2kcnr73668gud1kc