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Crystal strucutre of rac-methyl (11aR*,12S*,13R*,15aS*,15bS*)-11-oxo-11,11a,12,13-tetra­hydro-9H,15bH-13,15a-ep­oxy­isoindolo[1,2-c]pyrrolo[1,2-a][1,4]benzodiazepine-12-carboxyl­ate

The title compound, C(21)H(18)N(2)O(4), obtained as a racemate, contains a novel heterocyclic system, viz. isoindolo[1,2-c]pyrrolo­[1,2-a][1,4]benzodiazepine. The central diazepane ring has a distorted boat conformation with two phenyl­ene-fused and one methine C atom deviating by 0.931 (1), 0.887 (...

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Detalles Bibliográficos
Autores principales: Zaytsev, Vladimir P., Orlova, Daria N., Gurbanov, Atash V., Zubkov, Fedor I., Khrustalev, Victor N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257400/
https://www.ncbi.nlm.nih.gov/pubmed/25553013
http://dx.doi.org/10.1107/S1600536814023344