Crystal structures of bis­[2-(di­phenyl­phosphino­thio­yl)phen­yl] ether and bis­{2-[diphen­yl(selanyl­idene)phosphan­yl]phen­yl} ether

The title compounds, C(36)H(28)OP(2)S(2), (1), and C(36)H(28)OP(2)Se(2), (2), exhibit remarkably similar structures although they are not isomorphous. The whole mol­ecule of compound (2) is generated by twofold symmetry, with the ether O atom located on the twofold axis. Both compounds have intra­mo...

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Autores principales: Janzen, Daron E., Kooyman, Arianna M., Lange, Kayla A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257402/
https://www.ncbi.nlm.nih.gov/pubmed/25552986
http://dx.doi.org/10.1107/S1600536814023988
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author Janzen, Daron E.
Kooyman, Arianna M.
Lange, Kayla A.
author_facet Janzen, Daron E.
Kooyman, Arianna M.
Lange, Kayla A.
author_sort Janzen, Daron E.
collection PubMed
description The title compounds, C(36)H(28)OP(2)S(2), (1), and C(36)H(28)OP(2)Se(2), (2), exhibit remarkably similar structures although they are not isomorphous. The whole mol­ecule of compound (2) is generated by twofold symmetry, with the ether O atom located on the twofold axis. Both compounds have intra­molecular π–π inter­actions between terminal phenyl rings with centroid–centroid distances of 3.6214 (16) and 3.8027 (14) Å in (1) and (2), respectively. In the crystal of (1), short C—H⋯S hydrogen bonds link the mol­ecules, forming chains along [001], while in (2) there are no analogous C—H⋯Se inter­actions present.
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spelling pubmed-42574022014-12-31 Crystal structures of bis­[2-(di­phenyl­phosphino­thio­yl)phen­yl] ether and bis­{2-[diphen­yl(selanyl­idene)phosphan­yl]phen­yl} ether Janzen, Daron E. Kooyman, Arianna M. Lange, Kayla A. Acta Crystallogr Sect E Struct Rep Online Research Communications The title compounds, C(36)H(28)OP(2)S(2), (1), and C(36)H(28)OP(2)Se(2), (2), exhibit remarkably similar structures although they are not isomorphous. The whole mol­ecule of compound (2) is generated by twofold symmetry, with the ether O atom located on the twofold axis. Both compounds have intra­molecular π–π inter­actions between terminal phenyl rings with centroid–centroid distances of 3.6214 (16) and 3.8027 (14) Å in (1) and (2), respectively. In the crystal of (1), short C—H⋯S hydrogen bonds link the mol­ecules, forming chains along [001], while in (2) there are no analogous C—H⋯Se inter­actions present. International Union of Crystallography 2014-11-19 /pmc/articles/PMC4257402/ /pubmed/25552986 http://dx.doi.org/10.1107/S1600536814023988 Text en © Janzen et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Janzen, Daron E.
Kooyman, Arianna M.
Lange, Kayla A.
Crystal structures of bis­[2-(di­phenyl­phosphino­thio­yl)phen­yl] ether and bis­{2-[diphen­yl(selanyl­idene)phosphan­yl]phen­yl} ether
title Crystal structures of bis­[2-(di­phenyl­phosphino­thio­yl)phen­yl] ether and bis­{2-[diphen­yl(selanyl­idene)phosphan­yl]phen­yl} ether
title_full Crystal structures of bis­[2-(di­phenyl­phosphino­thio­yl)phen­yl] ether and bis­{2-[diphen­yl(selanyl­idene)phosphan­yl]phen­yl} ether
title_fullStr Crystal structures of bis­[2-(di­phenyl­phosphino­thio­yl)phen­yl] ether and bis­{2-[diphen­yl(selanyl­idene)phosphan­yl]phen­yl} ether
title_full_unstemmed Crystal structures of bis­[2-(di­phenyl­phosphino­thio­yl)phen­yl] ether and bis­{2-[diphen­yl(selanyl­idene)phosphan­yl]phen­yl} ether
title_short Crystal structures of bis­[2-(di­phenyl­phosphino­thio­yl)phen­yl] ether and bis­{2-[diphen­yl(selanyl­idene)phosphan­yl]phen­yl} ether
title_sort crystal structures of bis­[2-(di­phenyl­phosphino­thio­yl)phen­yl] ether and bis­{2-[diphen­yl(selanyl­idene)phosphan­yl]phen­yl} ether
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257402/
https://www.ncbi.nlm.nih.gov/pubmed/25552986
http://dx.doi.org/10.1107/S1600536814023988
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