Crystal structure of (2S,4S)-5,5-dimethyl-2-(pyridin-2-yl)-1,3-thia­zolidine-4-carb­oxy­lic acid

In the title compound, C(11)H(14)N(2)O(2)S, the thia­zolidine ring has an envelope conformation with the C atom bonded to the carb­oxy­lic acid group at the flap. Two C atoms of the thia­zolidine ring adopt S conformations. In the crystal, O—H⋯N hydrogen bonds between the amine and carb­oxy­lic acid...

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Detalles Bibliográficos
Autores principales: Laskar, Payel, Kuwamura, Naoto, Yoshinari, Nobuto, Konno, Takumi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257406/
https://www.ncbi.nlm.nih.gov/pubmed/25553035
http://dx.doi.org/10.1107/S1600536814024854
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author Laskar, Payel
Kuwamura, Naoto
Yoshinari, Nobuto
Konno, Takumi
author_facet Laskar, Payel
Kuwamura, Naoto
Yoshinari, Nobuto
Konno, Takumi
author_sort Laskar, Payel
collection PubMed
description In the title compound, C(11)H(14)N(2)O(2)S, the thia­zolidine ring has an envelope conformation with the C atom bonded to the carb­oxy­lic acid group at the flap. Two C atoms of the thia­zolidine ring adopt S conformations. In the crystal, O—H⋯N hydrogen bonds between the amine and carb­oxy­lic acid groups construct a helical chain structure along the a-axis direction. The chains are further connected via weak C—H⋯π contacts, forming a layer parallel to the ac plane.
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spelling pubmed-42574062014-12-31 Crystal structure of (2S,4S)-5,5-dimethyl-2-(pyridin-2-yl)-1,3-thia­zolidine-4-carb­oxy­lic acid Laskar, Payel Kuwamura, Naoto Yoshinari, Nobuto Konno, Takumi Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(11)H(14)N(2)O(2)S, the thia­zolidine ring has an envelope conformation with the C atom bonded to the carb­oxy­lic acid group at the flap. Two C atoms of the thia­zolidine ring adopt S conformations. In the crystal, O—H⋯N hydrogen bonds between the amine and carb­oxy­lic acid groups construct a helical chain structure along the a-axis direction. The chains are further connected via weak C—H⋯π contacts, forming a layer parallel to the ac plane. International Union of Crystallography 2014-11-15 /pmc/articles/PMC4257406/ /pubmed/25553035 http://dx.doi.org/10.1107/S1600536814024854 Text en © Laskar et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Laskar, Payel
Kuwamura, Naoto
Yoshinari, Nobuto
Konno, Takumi
Crystal structure of (2S,4S)-5,5-dimethyl-2-(pyridin-2-yl)-1,3-thia­zolidine-4-carb­oxy­lic acid
title Crystal structure of (2S,4S)-5,5-dimethyl-2-(pyridin-2-yl)-1,3-thia­zolidine-4-carb­oxy­lic acid
title_full Crystal structure of (2S,4S)-5,5-dimethyl-2-(pyridin-2-yl)-1,3-thia­zolidine-4-carb­oxy­lic acid
title_fullStr Crystal structure of (2S,4S)-5,5-dimethyl-2-(pyridin-2-yl)-1,3-thia­zolidine-4-carb­oxy­lic acid
title_full_unstemmed Crystal structure of (2S,4S)-5,5-dimethyl-2-(pyridin-2-yl)-1,3-thia­zolidine-4-carb­oxy­lic acid
title_short Crystal structure of (2S,4S)-5,5-dimethyl-2-(pyridin-2-yl)-1,3-thia­zolidine-4-carb­oxy­lic acid
title_sort crystal structure of (2s,4s)-5,5-dimethyl-2-(pyridin-2-yl)-1,3-thia­zolidine-4-carb­oxy­lic acid
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257406/
https://www.ncbi.nlm.nih.gov/pubmed/25553035
http://dx.doi.org/10.1107/S1600536814024854
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