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Crystal structure of poly[[(2,2′-bipyridine)manganese(II)]-di-μ-thiocyanato]
In the crystal structure of the polymeric title compound, [Mn(NCS)(2)(C(10)H(8)N(2))](n), the Mn(II) cations are coordinated by one chelating 2,2′-bipyridine ligand and four thiocyanate anions (two N- and two S-coordinating), forming a distorted [MnN(4)S(2)] octahedron. The asymmetric unit consis...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257407/ https://www.ncbi.nlm.nih.gov/pubmed/25553010 http://dx.doi.org/10.1107/S1600536814024490 |
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author | Suckert, Stefan Wöhlert, Susanne Jess, Inke Näther, Christian |
author_facet | Suckert, Stefan Wöhlert, Susanne Jess, Inke Näther, Christian |
author_sort | Suckert, Stefan |
collection | PubMed |
description | In the crystal structure of the polymeric title compound, [Mn(NCS)(2)(C(10)H(8)N(2))](n), the Mn(II) cations are coordinated by one chelating 2,2′-bipyridine ligand and four thiocyanate anions (two N- and two S-coordinating), forming a distorted [MnN(4)S(2)] octahedron. The asymmetric unit consists of one manganese cation located on a twofold rotation axis and half of a 2,2′-bipyridine ligand, the other half being generated by the same twofold rotation axis, as well as one thiocyanate anion in a general position. The Mn(II) cations are linked by two pairs of μ(1,3)-bridging thiocyanate ligands into chains along the c axis; because the N atoms of the 2,2′-bipyridine ligands, as well as the N and the S atoms of the thiocyanate anions, are each cis-coordinating, these chains show a zigzag arrangement. |
format | Online Article Text |
id | pubmed-4257407 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42574072014-12-31 Crystal structure of poly[[(2,2′-bipyridine)manganese(II)]-di-μ-thiocyanato] Suckert, Stefan Wöhlert, Susanne Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Data Reports In the crystal structure of the polymeric title compound, [Mn(NCS)(2)(C(10)H(8)N(2))](n), the Mn(II) cations are coordinated by one chelating 2,2′-bipyridine ligand and four thiocyanate anions (two N- and two S-coordinating), forming a distorted [MnN(4)S(2)] octahedron. The asymmetric unit consists of one manganese cation located on a twofold rotation axis and half of a 2,2′-bipyridine ligand, the other half being generated by the same twofold rotation axis, as well as one thiocyanate anion in a general position. The Mn(II) cations are linked by two pairs of μ(1,3)-bridging thiocyanate ligands into chains along the c axis; because the N atoms of the 2,2′-bipyridine ligands, as well as the N and the S atoms of the thiocyanate anions, are each cis-coordinating, these chains show a zigzag arrangement. International Union of Crystallography 2014-11-19 /pmc/articles/PMC4257407/ /pubmed/25553010 http://dx.doi.org/10.1107/S1600536814024490 Text en © Suckert et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Suckert, Stefan Wöhlert, Susanne Jess, Inke Näther, Christian Crystal structure of poly[[(2,2′-bipyridine)manganese(II)]-di-μ-thiocyanato] |
title | Crystal structure of poly[[(2,2′-bipyridine)manganese(II)]-di-μ-thiocyanato] |
title_full | Crystal structure of poly[[(2,2′-bipyridine)manganese(II)]-di-μ-thiocyanato] |
title_fullStr | Crystal structure of poly[[(2,2′-bipyridine)manganese(II)]-di-μ-thiocyanato] |
title_full_unstemmed | Crystal structure of poly[[(2,2′-bipyridine)manganese(II)]-di-μ-thiocyanato] |
title_short | Crystal structure of poly[[(2,2′-bipyridine)manganese(II)]-di-μ-thiocyanato] |
title_sort | crystal structure of poly[[(2,2′-bipyridine)manganese(ii)]-di-μ-thiocyanato] |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257407/ https://www.ncbi.nlm.nih.gov/pubmed/25553010 http://dx.doi.org/10.1107/S1600536814024490 |
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