Cargando…

Crystal structure of poly[[(2,2′-bi­pyridine)manganese(II)]-di-μ-thio­cyanato]

In the crystal structure of the polymeric title compound, [Mn(NCS)(2)(C(10)H(8)N(2))](n), the Mn(II) cations are coordinated by one chelating 2,2′-bi­pyridine ligand and four thio­cyanate anions (two N- and two S-coordinating), forming a distorted [MnN(4)S(2)] octa­hedron. The asymmetric unit consis...

Descripción completa

Detalles Bibliográficos
Autores principales: Suckert, Stefan, Wöhlert, Susanne, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257407/
https://www.ncbi.nlm.nih.gov/pubmed/25553010
http://dx.doi.org/10.1107/S1600536814024490
_version_ 1782347744456736768
author Suckert, Stefan
Wöhlert, Susanne
Jess, Inke
Näther, Christian
author_facet Suckert, Stefan
Wöhlert, Susanne
Jess, Inke
Näther, Christian
author_sort Suckert, Stefan
collection PubMed
description In the crystal structure of the polymeric title compound, [Mn(NCS)(2)(C(10)H(8)N(2))](n), the Mn(II) cations are coordinated by one chelating 2,2′-bi­pyridine ligand and four thio­cyanate anions (two N- and two S-coordinating), forming a distorted [MnN(4)S(2)] octa­hedron. The asymmetric unit consists of one manganese cation located on a twofold rotation axis and half of a 2,2′-bi­pyridine ligand, the other half being generated by the same twofold rotation axis, as well as one thio­cyanate anion in a general position. The Mn(II) cations are linked by two pairs of μ(1,3)-bridging thio­cyanate ligands into chains along the c axis; because the N atoms of the 2,2′-bi­pyridine ligands, as well as the N and the S atoms of the thio­cyanate anions, are each cis-coordinating, these chains show a zigzag arrangement.
format Online
Article
Text
id pubmed-4257407
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-42574072014-12-31 Crystal structure of poly[[(2,2′-bi­pyridine)manganese(II)]-di-μ-thio­cyanato] Suckert, Stefan Wöhlert, Susanne Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Data Reports In the crystal structure of the polymeric title compound, [Mn(NCS)(2)(C(10)H(8)N(2))](n), the Mn(II) cations are coordinated by one chelating 2,2′-bi­pyridine ligand and four thio­cyanate anions (two N- and two S-coordinating), forming a distorted [MnN(4)S(2)] octa­hedron. The asymmetric unit consists of one manganese cation located on a twofold rotation axis and half of a 2,2′-bi­pyridine ligand, the other half being generated by the same twofold rotation axis, as well as one thio­cyanate anion in a general position. The Mn(II) cations are linked by two pairs of μ(1,3)-bridging thio­cyanate ligands into chains along the c axis; because the N atoms of the 2,2′-bi­pyridine ligands, as well as the N and the S atoms of the thio­cyanate anions, are each cis-coordinating, these chains show a zigzag arrangement. International Union of Crystallography 2014-11-19 /pmc/articles/PMC4257407/ /pubmed/25553010 http://dx.doi.org/10.1107/S1600536814024490 Text en © Suckert et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Suckert, Stefan
Wöhlert, Susanne
Jess, Inke
Näther, Christian
Crystal structure of poly[[(2,2′-bi­pyridine)manganese(II)]-di-μ-thio­cyanato]
title Crystal structure of poly[[(2,2′-bi­pyridine)manganese(II)]-di-μ-thio­cyanato]
title_full Crystal structure of poly[[(2,2′-bi­pyridine)manganese(II)]-di-μ-thio­cyanato]
title_fullStr Crystal structure of poly[[(2,2′-bi­pyridine)manganese(II)]-di-μ-thio­cyanato]
title_full_unstemmed Crystal structure of poly[[(2,2′-bi­pyridine)manganese(II)]-di-μ-thio­cyanato]
title_short Crystal structure of poly[[(2,2′-bi­pyridine)manganese(II)]-di-μ-thio­cyanato]
title_sort crystal structure of poly[[(2,2′-bi­pyridine)manganese(ii)]-di-μ-thio­cyanato]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257407/
https://www.ncbi.nlm.nih.gov/pubmed/25553010
http://dx.doi.org/10.1107/S1600536814024490
work_keys_str_mv AT suckertstefan crystalstructureofpoly22bipyridinemanganeseiidimthiocyanato
AT wohlertsusanne crystalstructureofpoly22bipyridinemanganeseiidimthiocyanato
AT jessinke crystalstructureofpoly22bipyridinemanganeseiidimthiocyanato
AT natherchristian crystalstructureofpoly22bipyridinemanganeseiidimthiocyanato