Crystal structure of (2-{3-[4-(4′-cyano­biphenyl-4-yl­oxy)but­oxy]pyridin-2-yl-κN}-5-(dodec­yloxy)phenyl-κC (1))(9-oxo­tetra­cos-7-en-7-olato-κ(2) O,O′)platinum(II)

The central Pt(II) atom in the title compound, [Pt(C(40)H(47)N(2)O(3))(C(24)H(45)O(2))], has a slightly distorted square-planar coordination environment. The dihedral angle between the plane formed by Pt and the chelating C and N atoms and that formed by Pt and the chelating O atoms is 2.1 (3)°. The...

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Detalles Bibliográficos
Autores principales: Luo, Kaijun, Liu, Hanlin, Guo, Qing, Luo, Daibing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257408/
https://www.ncbi.nlm.nih.gov/pubmed/25553005
http://dx.doi.org/10.1107/S1600536814021928
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author Luo, Kaijun
Liu, Hanlin
Guo, Qing
Luo, Daibing
author_facet Luo, Kaijun
Liu, Hanlin
Guo, Qing
Luo, Daibing
author_sort Luo, Kaijun
collection PubMed
description The central Pt(II) atom in the title compound, [Pt(C(40)H(47)N(2)O(3))(C(24)H(45)O(2))], has a slightly distorted square-planar coordination environment. The dihedral angle between the plane formed by Pt and the chelating C and N atoms and that formed by Pt and the chelating O atoms is 2.1 (3)°. The angle between the planes of the two rings in the biphenyl-4-carbo­nitrile unit is 35.1 (5)°. One lateral alkane chain is disordered over two sets of sites with site occupancy factors in a 0.595 (7):0.405 (7) ratio.
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spelling pubmed-42574082014-12-31 Crystal structure of (2-{3-[4-(4′-cyano­biphenyl-4-yl­oxy)but­oxy]pyridin-2-yl-κN}-5-(dodec­yloxy)phenyl-κC (1))(9-oxo­tetra­cos-7-en-7-olato-κ(2) O,O′)platinum(II) Luo, Kaijun Liu, Hanlin Guo, Qing Luo, Daibing Acta Crystallogr Sect E Struct Rep Online Data Reports The central Pt(II) atom in the title compound, [Pt(C(40)H(47)N(2)O(3))(C(24)H(45)O(2))], has a slightly distorted square-planar coordination environment. The dihedral angle between the plane formed by Pt and the chelating C and N atoms and that formed by Pt and the chelating O atoms is 2.1 (3)°. The angle between the planes of the two rings in the biphenyl-4-carbo­nitrile unit is 35.1 (5)°. One lateral alkane chain is disordered over two sets of sites with site occupancy factors in a 0.595 (7):0.405 (7) ratio. International Union of Crystallography 2014-11-05 /pmc/articles/PMC4257408/ /pubmed/25553005 http://dx.doi.org/10.1107/S1600536814021928 Text en © Luo et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Luo, Kaijun
Liu, Hanlin
Guo, Qing
Luo, Daibing
Crystal structure of (2-{3-[4-(4′-cyano­biphenyl-4-yl­oxy)but­oxy]pyridin-2-yl-κN}-5-(dodec­yloxy)phenyl-κC (1))(9-oxo­tetra­cos-7-en-7-olato-κ(2) O,O′)platinum(II)
title Crystal structure of (2-{3-[4-(4′-cyano­biphenyl-4-yl­oxy)but­oxy]pyridin-2-yl-κN}-5-(dodec­yloxy)phenyl-κC (1))(9-oxo­tetra­cos-7-en-7-olato-κ(2) O,O′)platinum(II)
title_full Crystal structure of (2-{3-[4-(4′-cyano­biphenyl-4-yl­oxy)but­oxy]pyridin-2-yl-κN}-5-(dodec­yloxy)phenyl-κC (1))(9-oxo­tetra­cos-7-en-7-olato-κ(2) O,O′)platinum(II)
title_fullStr Crystal structure of (2-{3-[4-(4′-cyano­biphenyl-4-yl­oxy)but­oxy]pyridin-2-yl-κN}-5-(dodec­yloxy)phenyl-κC (1))(9-oxo­tetra­cos-7-en-7-olato-κ(2) O,O′)platinum(II)
title_full_unstemmed Crystal structure of (2-{3-[4-(4′-cyano­biphenyl-4-yl­oxy)but­oxy]pyridin-2-yl-κN}-5-(dodec­yloxy)phenyl-κC (1))(9-oxo­tetra­cos-7-en-7-olato-κ(2) O,O′)platinum(II)
title_short Crystal structure of (2-{3-[4-(4′-cyano­biphenyl-4-yl­oxy)but­oxy]pyridin-2-yl-κN}-5-(dodec­yloxy)phenyl-κC (1))(9-oxo­tetra­cos-7-en-7-olato-κ(2) O,O′)platinum(II)
title_sort crystal structure of (2-{3-[4-(4′-cyano­biphenyl-4-yl­oxy)but­oxy]pyridin-2-yl-κn}-5-(dodec­yloxy)phenyl-κc (1))(9-oxo­tetra­cos-7-en-7-olato-κ(2) o,o′)platinum(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257408/
https://www.ncbi.nlm.nih.gov/pubmed/25553005
http://dx.doi.org/10.1107/S1600536814021928
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