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Crystal structure of (E)-4-{2-[4-(allyloxy)phenyl]diazenyl}benzoic acid
The title compound, C(16)H(14)N(2)O(3), has an E conformation about the azobenzene [—N=N– = 1.2481 (16) Å] linkage. The benzene rings are almost coplanar [dihedral angle = 1.36 (7)°]. The O atoms of the carboxylic acid group are disordered over two sets of sites and were refined with an occupancy...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257410/ https://www.ncbi.nlm.nih.gov/pubmed/25552976 http://dx.doi.org/10.1107/S1600536814023745 |
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author | Rahman, Md. Lutfor Mohd. Yusoff, Mashitah Ismail, Jamil Kwong, Huey Chong Quah, Ching Kheng |
author_facet | Rahman, Md. Lutfor Mohd. Yusoff, Mashitah Ismail, Jamil Kwong, Huey Chong Quah, Ching Kheng |
author_sort | Rahman, Md. Lutfor |
collection | PubMed |
description | The title compound, C(16)H(14)N(2)O(3), has an E conformation about the azobenzene [—N=N– = 1.2481 (16) Å] linkage. The benzene rings are almost coplanar [dihedral angle = 1.36 (7)°]. The O atoms of the carboxylic acid group are disordered over two sets of sites and were refined with an occupancy ratio of 0.5:0.5. The two disordered components of the carboxylic acid group make dihedral angles of 1.5 (14) and 3.8 (12)° with the benzene ring to which they are attached. In the crystal, molecules are linked via pairs of O—H⋯O hydrogen bonds, forming inversion dimers. The dimers are connected via C—H⋯O hydrogen bonds, forming ribbons lying parallel to [120]. These ribbons are linked via C—H⋯π interactions, forming slabs parallel to (001). |
format | Online Article Text |
id | pubmed-4257410 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42574102014-12-31 Crystal structure of (E)-4-{2-[4-(allyloxy)phenyl]diazenyl}benzoic acid Rahman, Md. Lutfor Mohd. Yusoff, Mashitah Ismail, Jamil Kwong, Huey Chong Quah, Ching Kheng Acta Crystallogr Sect E Struct Rep Online Research Communications The title compound, C(16)H(14)N(2)O(3), has an E conformation about the azobenzene [—N=N– = 1.2481 (16) Å] linkage. The benzene rings are almost coplanar [dihedral angle = 1.36 (7)°]. The O atoms of the carboxylic acid group are disordered over two sets of sites and were refined with an occupancy ratio of 0.5:0.5. The two disordered components of the carboxylic acid group make dihedral angles of 1.5 (14) and 3.8 (12)° with the benzene ring to which they are attached. In the crystal, molecules are linked via pairs of O—H⋯O hydrogen bonds, forming inversion dimers. The dimers are connected via C—H⋯O hydrogen bonds, forming ribbons lying parallel to [120]. These ribbons are linked via C—H⋯π interactions, forming slabs parallel to (001). International Union of Crystallography 2014-11-15 /pmc/articles/PMC4257410/ /pubmed/25552976 http://dx.doi.org/10.1107/S1600536814023745 Text en © Rahman et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Rahman, Md. Lutfor Mohd. Yusoff, Mashitah Ismail, Jamil Kwong, Huey Chong Quah, Ching Kheng Crystal structure of (E)-4-{2-[4-(allyloxy)phenyl]diazenyl}benzoic acid |
title | Crystal structure of (E)-4-{2-[4-(allyloxy)phenyl]diazenyl}benzoic acid |
title_full | Crystal structure of (E)-4-{2-[4-(allyloxy)phenyl]diazenyl}benzoic acid |
title_fullStr | Crystal structure of (E)-4-{2-[4-(allyloxy)phenyl]diazenyl}benzoic acid |
title_full_unstemmed | Crystal structure of (E)-4-{2-[4-(allyloxy)phenyl]diazenyl}benzoic acid |
title_short | Crystal structure of (E)-4-{2-[4-(allyloxy)phenyl]diazenyl}benzoic acid |
title_sort | crystal structure of (e)-4-{2-[4-(allyloxy)phenyl]diazenyl}benzoic acid |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257410/ https://www.ncbi.nlm.nih.gov/pubmed/25552976 http://dx.doi.org/10.1107/S1600536814023745 |
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