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Crystal structure of (E)-4-{2-[4-(all­yloxy)phen­yl]diazen­yl}benzoic acid

The title compound, C(16)H(14)N(2)O(3), has an E conformation about the azo­benzene [—N=N– = 1.2481 (16) Å] linkage. The benzene rings are almost coplanar [dihedral angle = 1.36 (7)°]. The O atoms of the carb­oxy­lic acid group are disordered over two sets of sites and were refined with an occupancy...

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Autores principales: Rahman, Md. Lutfor, Mohd. Yusoff, Mashitah, Ismail, Jamil, Kwong, Huey Chong, Quah, Ching Kheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257410/
https://www.ncbi.nlm.nih.gov/pubmed/25552976
http://dx.doi.org/10.1107/S1600536814023745
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author Rahman, Md. Lutfor
Mohd. Yusoff, Mashitah
Ismail, Jamil
Kwong, Huey Chong
Quah, Ching Kheng
author_facet Rahman, Md. Lutfor
Mohd. Yusoff, Mashitah
Ismail, Jamil
Kwong, Huey Chong
Quah, Ching Kheng
author_sort Rahman, Md. Lutfor
collection PubMed
description The title compound, C(16)H(14)N(2)O(3), has an E conformation about the azo­benzene [—N=N– = 1.2481 (16) Å] linkage. The benzene rings are almost coplanar [dihedral angle = 1.36 (7)°]. The O atoms of the carb­oxy­lic acid group are disordered over two sets of sites and were refined with an occupancy ratio of 0.5:0.5. The two disordered components of the carb­oxy­lic acid group make dihedral angles of 1.5 (14) and 3.8 (12)° with the benzene ring to which they are attached. In the crystal, mol­ecules are linked via pairs of O—H⋯O hydrogen bonds, forming inversion dimers. The dimers are connected via C—H⋯O hydrogen bonds, forming ribbons lying parallel to [120]. These ribbons are linked via C—H⋯π inter­actions, forming slabs parallel to (001).
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spelling pubmed-42574102014-12-31 Crystal structure of (E)-4-{2-[4-(all­yloxy)phen­yl]diazen­yl}benzoic acid Rahman, Md. Lutfor Mohd. Yusoff, Mashitah Ismail, Jamil Kwong, Huey Chong Quah, Ching Kheng Acta Crystallogr Sect E Struct Rep Online Research Communications The title compound, C(16)H(14)N(2)O(3), has an E conformation about the azo­benzene [—N=N– = 1.2481 (16) Å] linkage. The benzene rings are almost coplanar [dihedral angle = 1.36 (7)°]. The O atoms of the carb­oxy­lic acid group are disordered over two sets of sites and were refined with an occupancy ratio of 0.5:0.5. The two disordered components of the carb­oxy­lic acid group make dihedral angles of 1.5 (14) and 3.8 (12)° with the benzene ring to which they are attached. In the crystal, mol­ecules are linked via pairs of O—H⋯O hydrogen bonds, forming inversion dimers. The dimers are connected via C—H⋯O hydrogen bonds, forming ribbons lying parallel to [120]. These ribbons are linked via C—H⋯π inter­actions, forming slabs parallel to (001). International Union of Crystallography 2014-11-15 /pmc/articles/PMC4257410/ /pubmed/25552976 http://dx.doi.org/10.1107/S1600536814023745 Text en © Rahman et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Rahman, Md. Lutfor
Mohd. Yusoff, Mashitah
Ismail, Jamil
Kwong, Huey Chong
Quah, Ching Kheng
Crystal structure of (E)-4-{2-[4-(all­yloxy)phen­yl]diazen­yl}benzoic acid
title Crystal structure of (E)-4-{2-[4-(all­yloxy)phen­yl]diazen­yl}benzoic acid
title_full Crystal structure of (E)-4-{2-[4-(all­yloxy)phen­yl]diazen­yl}benzoic acid
title_fullStr Crystal structure of (E)-4-{2-[4-(all­yloxy)phen­yl]diazen­yl}benzoic acid
title_full_unstemmed Crystal structure of (E)-4-{2-[4-(all­yloxy)phen­yl]diazen­yl}benzoic acid
title_short Crystal structure of (E)-4-{2-[4-(all­yloxy)phen­yl]diazen­yl}benzoic acid
title_sort crystal structure of (e)-4-{2-[4-(all­yloxy)phen­yl]diazen­yl}benzoic acid
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257410/
https://www.ncbi.nlm.nih.gov/pubmed/25552976
http://dx.doi.org/10.1107/S1600536814023745
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