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Crystal structure of 1-(2,4-dimethylphenyl)-2-(4-trimethylsilyl-1H-1,2,3-triazol-1-yl)ethanone
The asymmetric unit of the title compound, C(15)H(21)N(3)OSi, contains two molecules with similar conformations (r.m.s. overlay fit for the 20 non-H atoms = 0.163 Å). The dihedral angles between the planes of the 1,2,3-triazole and 2,4-dimethylbenzene rings are 27.0 (3) and 19.5 (3)°. In the crys...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257412/ https://www.ncbi.nlm.nih.gov/pubmed/25553028 http://dx.doi.org/10.1107/S1600536814024313 |
| _version_ | 1782347745622753280 |
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| author | Venkatesh, G. B. Nagarajaiah, H. Prasad, N. L. HariPrasad, S. Begum, Noor Shahina |
| author_facet | Venkatesh, G. B. Nagarajaiah, H. Prasad, N. L. HariPrasad, S. Begum, Noor Shahina |
| author_sort | Venkatesh, G. B. |
| collection | PubMed |
| description | The asymmetric unit of the title compound, C(15)H(21)N(3)OSi, contains two molecules with similar conformations (r.m.s. overlay fit for the 20 non-H atoms = 0.163 Å). The dihedral angles between the planes of the 1,2,3-triazole and 2,4-dimethylbenzene rings are 27.0 (3) and 19.5 (3)°. In the crystal, molecules are linked by very weak C—H⋯O and C—H⋯N hydrogen bonds to generate [100] chains. The chains are cross-linked by C—H⋯π interactions. |
| format | Online Article Text |
| id | pubmed-4257412 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-42574122014-12-31 Crystal structure of 1-(2,4-dimethylphenyl)-2-(4-trimethylsilyl-1H-1,2,3-triazol-1-yl)ethanone Venkatesh, G. B. Nagarajaiah, H. Prasad, N. L. HariPrasad, S. Begum, Noor Shahina Acta Crystallogr Sect E Struct Rep Online Data Reports The asymmetric unit of the title compound, C(15)H(21)N(3)OSi, contains two molecules with similar conformations (r.m.s. overlay fit for the 20 non-H atoms = 0.163 Å). The dihedral angles between the planes of the 1,2,3-triazole and 2,4-dimethylbenzene rings are 27.0 (3) and 19.5 (3)°. In the crystal, molecules are linked by very weak C—H⋯O and C—H⋯N hydrogen bonds to generate [100] chains. The chains are cross-linked by C—H⋯π interactions. International Union of Crystallography 2014-11-12 /pmc/articles/PMC4257412/ /pubmed/25553028 http://dx.doi.org/10.1107/S1600536814024313 Text en © Venkatesh et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Data Reports Venkatesh, G. B. Nagarajaiah, H. Prasad, N. L. HariPrasad, S. Begum, Noor Shahina Crystal structure of 1-(2,4-dimethylphenyl)-2-(4-trimethylsilyl-1H-1,2,3-triazol-1-yl)ethanone |
| title | Crystal structure of 1-(2,4-dimethylphenyl)-2-(4-trimethylsilyl-1H-1,2,3-triazol-1-yl)ethanone |
| title_full | Crystal structure of 1-(2,4-dimethylphenyl)-2-(4-trimethylsilyl-1H-1,2,3-triazol-1-yl)ethanone |
| title_fullStr | Crystal structure of 1-(2,4-dimethylphenyl)-2-(4-trimethylsilyl-1H-1,2,3-triazol-1-yl)ethanone |
| title_full_unstemmed | Crystal structure of 1-(2,4-dimethylphenyl)-2-(4-trimethylsilyl-1H-1,2,3-triazol-1-yl)ethanone |
| title_short | Crystal structure of 1-(2,4-dimethylphenyl)-2-(4-trimethylsilyl-1H-1,2,3-triazol-1-yl)ethanone |
| title_sort | crystal structure of 1-(2,4-dimethylphenyl)-2-(4-trimethylsilyl-1h-1,2,3-triazol-1-yl)ethanone |
| topic | Data Reports |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257412/ https://www.ncbi.nlm.nih.gov/pubmed/25553028 http://dx.doi.org/10.1107/S1600536814024313 |
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