Crystal structure of 2-(2,4-di­chloro­phen­yl)-4-hydroxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde

In the title compound, C(25)H(15)Cl(2)NO(4)S, the di­chloro­phenyl ring is twisted by 68.69 (11)° from the mean plane of the carbazole ring system [r.m.s. deviation = 0.084 (2)°]. The hy­droxy group is involved in an intra­molecular O—H⋯O hydrogen bond, which generates an S(6) graph-set motif. In th...

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Autores principales: Umadevi, M., Ramalingam, B. M., Yamuna, R., Mohanakrishnan, A. K., Chakkaravarthi, G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257421/
https://www.ncbi.nlm.nih.gov/pubmed/25552966
http://dx.doi.org/10.1107/S1600536814024064
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author Umadevi, M.
Ramalingam, B. M.
Yamuna, R.
Mohanakrishnan, A. K.
Chakkaravarthi, G.
author_facet Umadevi, M.
Ramalingam, B. M.
Yamuna, R.
Mohanakrishnan, A. K.
Chakkaravarthi, G.
author_sort Umadevi, M.
collection PubMed
description In the title compound, C(25)H(15)Cl(2)NO(4)S, the di­chloro­phenyl ring is twisted by 68.69 (11)° from the mean plane of the carbazole ring system [r.m.s. deviation = 0.084 (2)°]. The hy­droxy group is involved in an intra­molecular O—H⋯O hydrogen bond, which generates an S(6) graph-set motif. In the crystal, pairs of C—H⋯Cl hydrogen bonds link mol­ecules into inversion dimers with an R (2) (2)(26) motif. Weak C—H⋯O inter­actions further link these dimers into ribbons propagating in [100].
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spelling pubmed-42574212014-12-31 Crystal structure of 2-(2,4-di­chloro­phen­yl)-4-hydroxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde Umadevi, M. Ramalingam, B. M. Yamuna, R. Mohanakrishnan, A. K. Chakkaravarthi, G. Acta Crystallogr Sect E Struct Rep Online Research Communications In the title compound, C(25)H(15)Cl(2)NO(4)S, the di­chloro­phenyl ring is twisted by 68.69 (11)° from the mean plane of the carbazole ring system [r.m.s. deviation = 0.084 (2)°]. The hy­droxy group is involved in an intra­molecular O—H⋯O hydrogen bond, which generates an S(6) graph-set motif. In the crystal, pairs of C—H⋯Cl hydrogen bonds link mol­ecules into inversion dimers with an R (2) (2)(26) motif. Weak C—H⋯O inter­actions further link these dimers into ribbons propagating in [100]. International Union of Crystallography 2014-11-08 /pmc/articles/PMC4257421/ /pubmed/25552966 http://dx.doi.org/10.1107/S1600536814024064 Text en © Umadevi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Umadevi, M.
Ramalingam, B. M.
Yamuna, R.
Mohanakrishnan, A. K.
Chakkaravarthi, G.
Crystal structure of 2-(2,4-di­chloro­phen­yl)-4-hydroxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title Crystal structure of 2-(2,4-di­chloro­phen­yl)-4-hydroxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_full Crystal structure of 2-(2,4-di­chloro­phen­yl)-4-hydroxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_fullStr Crystal structure of 2-(2,4-di­chloro­phen­yl)-4-hydroxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_full_unstemmed Crystal structure of 2-(2,4-di­chloro­phen­yl)-4-hydroxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_short Crystal structure of 2-(2,4-di­chloro­phen­yl)-4-hydroxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_sort crystal structure of 2-(2,4-di­chloro­phen­yl)-4-hydroxy-9-phenyl­sulfonyl-9h-carbazole-3-carbaldehyde
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257421/
https://www.ncbi.nlm.nih.gov/pubmed/25552966
http://dx.doi.org/10.1107/S1600536814024064
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