Crystal structure of 1-benzyl-3-methyl-1H-imidazolium hexa­fluorido­phosphate

In the title salt, C(11)H(13)N(2) (+)·PF(6) (−), the dihedral angle between the planes of the imidazole and benzene rings is 84.72 (4)°. In the crystal, C—H⋯F inter­actions connect the cation and anion pairs into a three-dimensional network. Weak π–π inter­actions are observed between the imidazoliu...

Descripción completa

Detalles Bibliográficos
Autores principales: Hillesheim, Patrick C., Scipione, Kent A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257422/
https://www.ncbi.nlm.nih.gov/pubmed/25553025
http://dx.doi.org/10.1107/S1600536814024301
_version_ 1782347747948494848
author Hillesheim, Patrick C.
Scipione, Kent A.
author_facet Hillesheim, Patrick C.
Scipione, Kent A.
author_sort Hillesheim, Patrick C.
collection PubMed
description In the title salt, C(11)H(13)N(2) (+)·PF(6) (−), the dihedral angle between the planes of the imidazole and benzene rings is 84.72 (4)°. In the crystal, C—H⋯F inter­actions connect the cation and anion pairs into a three-dimensional network. Weak π–π inter­actions are observed between the imidazolium ring and the aromatic benzene ring of an adjacent mol­ecule with C⋯C and C⋯N distances ranging from 3.3714 (16) to 3.4389 (15) Å.
format Online
Article
Text
id pubmed-4257422
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-42574222014-12-31 Crystal structure of 1-benzyl-3-methyl-1H-imidazolium hexa­fluorido­phosphate Hillesheim, Patrick C. Scipione, Kent A. Acta Crystallogr Sect E Struct Rep Online Data Reports In the title salt, C(11)H(13)N(2) (+)·PF(6) (−), the dihedral angle between the planes of the imidazole and benzene rings is 84.72 (4)°. In the crystal, C—H⋯F inter­actions connect the cation and anion pairs into a three-dimensional network. Weak π–π inter­actions are observed between the imidazolium ring and the aromatic benzene ring of an adjacent mol­ecule with C⋯C and C⋯N distances ranging from 3.3714 (16) to 3.4389 (15) Å. International Union of Crystallography 2014-11-12 /pmc/articles/PMC4257422/ /pubmed/25553025 http://dx.doi.org/10.1107/S1600536814024301 Text en © Hillesheim and Scipione 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Hillesheim, Patrick C.
Scipione, Kent A.
Crystal structure of 1-benzyl-3-methyl-1H-imidazolium hexa­fluorido­phosphate
title Crystal structure of 1-benzyl-3-methyl-1H-imidazolium hexa­fluorido­phosphate
title_full Crystal structure of 1-benzyl-3-methyl-1H-imidazolium hexa­fluorido­phosphate
title_fullStr Crystal structure of 1-benzyl-3-methyl-1H-imidazolium hexa­fluorido­phosphate
title_full_unstemmed Crystal structure of 1-benzyl-3-methyl-1H-imidazolium hexa­fluorido­phosphate
title_short Crystal structure of 1-benzyl-3-methyl-1H-imidazolium hexa­fluorido­phosphate
title_sort crystal structure of 1-benzyl-3-methyl-1h-imidazolium hexa­fluorido­phosphate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257422/
https://www.ncbi.nlm.nih.gov/pubmed/25553025
http://dx.doi.org/10.1107/S1600536814024301
work_keys_str_mv AT hillesheimpatrickc crystalstructureof1benzyl3methyl1himidazoliumhexafluoridophosphate
AT scipionekenta crystalstructureof1benzyl3methyl1himidazoliumhexafluoridophosphate

Ejemplares similares