Crystal structure of fenpropathrin

In the title compound [systematic name: cyano­(3-phen­oxy­phen­yl)methyl 2,2,3,3-tetra­methyl­cyclo­propane­carboxyl­ate], C(22)H(23)NO(3), which is the pyrethroid insecticide fenpropathrin, the dihedral angle between the cyclo­propane ring plane and the carboxyl­ate group plane is 88.25 (11)°. The...

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Autores principales: Kang, Gihaeng, Jeon, Youngeun, Lee, Sangjin, Kim, Tae Ho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257423/
https://www.ncbi.nlm.nih.gov/pubmed/25553036
http://dx.doi.org/10.1107/S160053681402474X
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author Kang, Gihaeng
Jeon, Youngeun
Lee, Sangjin
Kim, Tae Ho
author_facet Kang, Gihaeng
Jeon, Youngeun
Lee, Sangjin
Kim, Tae Ho
author_sort Kang, Gihaeng
collection PubMed
description In the title compound [systematic name: cyano­(3-phen­oxy­phen­yl)methyl 2,2,3,3-tetra­methyl­cyclo­propane­carboxyl­ate], C(22)H(23)NO(3), which is the pyrethroid insecticide fenpropathrin, the dihedral angle between the cyclo­propane ring plane and the carboxyl­ate group plane is 88.25 (11)°. The dihedral angle between the benzene and phenyl rings in the phen­oxy­benzyl group is 82.99 (4)°. In the crystal, C—H⋯N hydrogen bonds and weak C—H⋯π inter­actions link adjacent mol­ecules, forming loop chains along the b-axis direction.
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spelling pubmed-42574232014-12-31 Crystal structure of fenpropathrin Kang, Gihaeng Jeon, Youngeun Lee, Sangjin Kim, Tae Ho Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound [systematic name: cyano­(3-phen­oxy­phen­yl)methyl 2,2,3,3-tetra­methyl­cyclo­propane­carboxyl­ate], C(22)H(23)NO(3), which is the pyrethroid insecticide fenpropathrin, the dihedral angle between the cyclo­propane ring plane and the carboxyl­ate group plane is 88.25 (11)°. The dihedral angle between the benzene and phenyl rings in the phen­oxy­benzyl group is 82.99 (4)°. In the crystal, C—H⋯N hydrogen bonds and weak C—H⋯π inter­actions link adjacent mol­ecules, forming loop chains along the b-axis direction. International Union of Crystallography 2014-11-19 /pmc/articles/PMC4257423/ /pubmed/25553036 http://dx.doi.org/10.1107/S160053681402474X Text en © Kang et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Kang, Gihaeng
Jeon, Youngeun
Lee, Sangjin
Kim, Tae Ho
Crystal structure of fenpropathrin
title Crystal structure of fenpropathrin
title_full Crystal structure of fenpropathrin
title_fullStr Crystal structure of fenpropathrin
title_full_unstemmed Crystal structure of fenpropathrin
title_short Crystal structure of fenpropathrin
title_sort crystal structure of fenpropathrin
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257423/
https://www.ncbi.nlm.nih.gov/pubmed/25553036
http://dx.doi.org/10.1107/S160053681402474X
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AT jeonyoungeun crystalstructureoffenpropathrin
AT leesangjin crystalstructureoffenpropathrin
AT kimtaeho crystalstructureoffenpropathrin

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