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Crystal structure of 1-(piperidin-1-yl)butane-1,3-dione
In the title compound, C(9)H(15)NO(2), the piperidine ring exhibits a chair conformation. The butanedione subunit exhibits a conformation with the ketone C atom in an eclipsed position with respect to the amide carbonyl group. In the crystal, a two-dimensional layered arrangement is formed by hydro...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257425/ https://www.ncbi.nlm.nih.gov/pubmed/25553056 http://dx.doi.org/10.1107/S1600536814025768 |
Sumario: | In the title compound, C(9)H(15)NO(2), the piperidine ring exhibits a chair conformation. The butanedione subunit exhibits a conformation with the ketone C atom in an eclipsed position with respect to the amide carbonyl group. In the crystal, a two-dimensional layered arrangement is formed by hydrogen bonds of the C—H⋯O type between the methyl group and the exocyclic methylene unit as donor sites and the amide carbonyl O atom as the acceptor of a bifurcated hydrogen bond. These layers are oriented parallel to the ab plane. |
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