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Crystal structure of 1-(piperidin-1-yl)butane-1,3-dione

In the title compound, C(9)H(15)NO(2), the piperidine ring exhibits a chair conformation. The butane­dione subunit exhibits a conformation with the ketone C atom in an eclipsed position with respect to the amide carbonyl group. In the crystal, a two-dimensional layered arrangement is formed by hydro...

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Detalles Bibliográficos
Autores principales: Schwierz, Markus, Görls, Helmar, Imhof, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257425/
https://www.ncbi.nlm.nih.gov/pubmed/25553056
http://dx.doi.org/10.1107/S1600536814025768
Descripción
Sumario:In the title compound, C(9)H(15)NO(2), the piperidine ring exhibits a chair conformation. The butane­dione subunit exhibits a conformation with the ketone C atom in an eclipsed position with respect to the amide carbonyl group. In the crystal, a two-dimensional layered arrangement is formed by hydrogen bonds of the C—H⋯O type between the methyl group and the exocyclic methyl­ene unit as donor sites and the amide carbonyl O atom as the acceptor of a bifurcated hydrogen bond. These layers are oriented parallel to the ab plane.