Crystal structure of 1-(piperidin-1-yl)butane-1,3-dione

In the title compound, C(9)H(15)NO(2), the piperidine ring exhibits a chair conformation. The butane­dione subunit exhibits a conformation with the ketone C atom in an eclipsed position with respect to the amide carbonyl group. In the crystal, a two-dimensional layered arrangement is formed by hydro...

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Detalles Bibliográficos
Autores principales: Schwierz, Markus, Görls, Helmar, Imhof, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257425/
https://www.ncbi.nlm.nih.gov/pubmed/25553056
http://dx.doi.org/10.1107/S1600536814025768
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author Schwierz, Markus
Görls, Helmar
Imhof, Wolfgang
author_facet Schwierz, Markus
Görls, Helmar
Imhof, Wolfgang
author_sort Schwierz, Markus
collection PubMed
description In the title compound, C(9)H(15)NO(2), the piperidine ring exhibits a chair conformation. The butane­dione subunit exhibits a conformation with the ketone C atom in an eclipsed position with respect to the amide carbonyl group. In the crystal, a two-dimensional layered arrangement is formed by hydrogen bonds of the C—H⋯O type between the methyl group and the exocyclic methyl­ene unit as donor sites and the amide carbonyl O atom as the acceptor of a bifurcated hydrogen bond. These layers are oriented parallel to the ab plane.
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spelling pubmed-42574252014-12-31 Crystal structure of 1-(piperidin-1-yl)butane-1,3-dione Schwierz, Markus Görls, Helmar Imhof, Wolfgang Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(9)H(15)NO(2), the piperidine ring exhibits a chair conformation. The butane­dione subunit exhibits a conformation with the ketone C atom in an eclipsed position with respect to the amide carbonyl group. In the crystal, a two-dimensional layered arrangement is formed by hydrogen bonds of the C—H⋯O type between the methyl group and the exocyclic methyl­ene unit as donor sites and the amide carbonyl O atom as the acceptor of a bifurcated hydrogen bond. These layers are oriented parallel to the ab plane. International Union of Crystallography 2014-11-29 /pmc/articles/PMC4257425/ /pubmed/25553056 http://dx.doi.org/10.1107/S1600536814025768 Text en © Schwierz et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Schwierz, Markus
Görls, Helmar
Imhof, Wolfgang
Crystal structure of 1-(piperidin-1-yl)butane-1,3-dione
title Crystal structure of 1-(piperidin-1-yl)butane-1,3-dione
title_full Crystal structure of 1-(piperidin-1-yl)butane-1,3-dione
title_fullStr Crystal structure of 1-(piperidin-1-yl)butane-1,3-dione
title_full_unstemmed Crystal structure of 1-(piperidin-1-yl)butane-1,3-dione
title_short Crystal structure of 1-(piperidin-1-yl)butane-1,3-dione
title_sort crystal structure of 1-(piperidin-1-yl)butane-1,3-dione
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257425/
https://www.ncbi.nlm.nih.gov/pubmed/25553056
http://dx.doi.org/10.1107/S1600536814025768
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