Crystal structure of tin(II) perchlorate trihydrate

The title compound, [Sn(H(2)O)(3)](ClO(4))(2), was synthesized by the redox reaction of copper(II) perchlorate hexa­hydrate and metallic tin in perchloric acid. Both the trigonal–pyramidal [Sn(H(2)O)(3)](2+) cations and tetra­hedral perchlorate anions lie on crystallographic threefold axes. In the c...

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Detalles Bibliográficos
Autores principales: Hennings, Erik, Schmidt, Horst, Köhler, Martin, Voigt, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257428/
https://www.ncbi.nlm.nih.gov/pubmed/25552969
http://dx.doi.org/10.1107/S1600536814024283
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author Hennings, Erik
Schmidt, Horst
Köhler, Martin
Voigt, Wolfgang
author_facet Hennings, Erik
Schmidt, Horst
Köhler, Martin
Voigt, Wolfgang
author_sort Hennings, Erik
collection PubMed
description The title compound, [Sn(H(2)O)(3)](ClO(4))(2), was synthesized by the redox reaction of copper(II) perchlorate hexa­hydrate and metallic tin in perchloric acid. Both the trigonal–pyramidal [Sn(H(2)O)(3)](2+) cations and tetra­hedral perchlorate anions lie on crystallographic threefold axes. In the crystal, the cations are linked to the anions by O—H⋯O hydrogen bonds, generating (001) sheets.
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spelling pubmed-42574282014-12-31 Crystal structure of tin(II) perchlorate trihydrate Hennings, Erik Schmidt, Horst Köhler, Martin Voigt, Wolfgang Acta Crystallogr Sect E Struct Rep Online Research Communications The title compound, [Sn(H(2)O)(3)](ClO(4))(2), was synthesized by the redox reaction of copper(II) perchlorate hexa­hydrate and metallic tin in perchloric acid. Both the trigonal–pyramidal [Sn(H(2)O)(3)](2+) cations and tetra­hedral perchlorate anions lie on crystallographic threefold axes. In the crystal, the cations are linked to the anions by O—H⋯O hydrogen bonds, generating (001) sheets. International Union of Crystallography 2014-11-12 /pmc/articles/PMC4257428/ /pubmed/25552969 http://dx.doi.org/10.1107/S1600536814024283 Text en © Hennings et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Hennings, Erik
Schmidt, Horst
Köhler, Martin
Voigt, Wolfgang
Crystal structure of tin(II) perchlorate trihydrate
title Crystal structure of tin(II) perchlorate trihydrate
title_full Crystal structure of tin(II) perchlorate trihydrate
title_fullStr Crystal structure of tin(II) perchlorate trihydrate
title_full_unstemmed Crystal structure of tin(II) perchlorate trihydrate
title_short Crystal structure of tin(II) perchlorate trihydrate
title_sort crystal structure of tin(ii) perchlorate trihydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257428/
https://www.ncbi.nlm.nih.gov/pubmed/25552969
http://dx.doi.org/10.1107/S1600536814024283
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AT voigtwolfgang crystalstructureoftiniiperchloratetrihydrate

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