Crystal structure of piperidinium 4-nitro­phenolate

In the title mol­ecular salt, C(5)H(12)N(+)·C(6)H(4)NO(3) (−), the piperidine ring adopts a chair conformation and the cation is protonated at the N atom. In the anion, the nitro group is twisted at an angle of 10.30 (11)° with respect to the attached benzene ring. In the crystal, N—H⋯O hydrogen bon...

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Autores principales: Sowmya, N. Swarna, Sampathkrishnan, S., Sudhahar, S., Chakkaravarthi, G., Kumar, R. Mohan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257431/
https://www.ncbi.nlm.nih.gov/pubmed/25552992
http://dx.doi.org/10.1107/S1600536814025306
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author Sowmya, N. Swarna
Sampathkrishnan, S.
Sudhahar, S.
Chakkaravarthi, G.
Kumar, R. Mohan
author_facet Sowmya, N. Swarna
Sampathkrishnan, S.
Sudhahar, S.
Chakkaravarthi, G.
Kumar, R. Mohan
author_sort Sowmya, N. Swarna
collection PubMed
description In the title mol­ecular salt, C(5)H(12)N(+)·C(6)H(4)NO(3) (−), the piperidine ring adopts a chair conformation and the cation is protonated at the N atom. In the anion, the nitro group is twisted at an angle of 10.30 (11)° with respect to the attached benzene ring. In the crystal, N—H⋯O hydrogen bonds link adjacent anions and cations into infinite chains propagating along [100]. The chains are linked by C—H⋯π inter­actions, forming sheets lying parallel to (001).
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spelling pubmed-42574312014-12-31 Crystal structure of piperidinium 4-nitro­phenolate Sowmya, N. Swarna Sampathkrishnan, S. Sudhahar, S. Chakkaravarthi, G. Kumar, R. Mohan Acta Crystallogr Sect E Struct Rep Online Research Communications In the title mol­ecular salt, C(5)H(12)N(+)·C(6)H(4)NO(3) (−), the piperidine ring adopts a chair conformation and the cation is protonated at the N atom. In the anion, the nitro group is twisted at an angle of 10.30 (11)° with respect to the attached benzene ring. In the crystal, N—H⋯O hydrogen bonds link adjacent anions and cations into infinite chains propagating along [100]. The chains are linked by C—H⋯π inter­actions, forming sheets lying parallel to (001). International Union of Crystallography 2014-11-21 /pmc/articles/PMC4257431/ /pubmed/25552992 http://dx.doi.org/10.1107/S1600536814025306 Text en © Sowmya et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Sowmya, N. Swarna
Sampathkrishnan, S.
Sudhahar, S.
Chakkaravarthi, G.
Kumar, R. Mohan
Crystal structure of piperidinium 4-nitro­phenolate
title Crystal structure of piperidinium 4-nitro­phenolate
title_full Crystal structure of piperidinium 4-nitro­phenolate
title_fullStr Crystal structure of piperidinium 4-nitro­phenolate
title_full_unstemmed Crystal structure of piperidinium 4-nitro­phenolate
title_short Crystal structure of piperidinium 4-nitro­phenolate
title_sort crystal structure of piperidinium 4-nitro­phenolate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257431/
https://www.ncbi.nlm.nih.gov/pubmed/25552992
http://dx.doi.org/10.1107/S1600536814025306
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