Crystal structure of bis­[1,3,4,5-tetra­methyl-1H-imidazole-2(3H)-thione-κS]chlorido­copper(I)

The mol­ecular structure of the title compound, [CuCl(C(7)H(12)N(2)S)(2)], shows a slightly distorted trigonal–planar coordination geometry of the Cu atom. The Cu—Cl bond measures 2.2287 (9) Å, and the two Cu—S bonds are significantly different from each other, with values of 2.2270 (10) and 2.2662 ...

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Detalles Bibliográficos
Autores principales: Flörke, Ulrich, Ahmida, Aziza, Egold, Hans, Henkel, Gerald
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257435/
https://www.ncbi.nlm.nih.gov/pubmed/25553008
http://dx.doi.org/10.1107/S1600536814024404
Descripción
Sumario:The mol­ecular structure of the title compound, [CuCl(C(7)H(12)N(2)S)(2)], shows a slightly distorted trigonal–planar coordination geometry of the Cu atom. The Cu—Cl bond measures 2.2287 (9) Å, and the two Cu—S bonds are significantly different from each other, with values of 2.2270 (10) and 2.2662 (10) Å. Also, the S—Cu—Cl angles differ, with values of 113.80 (4) and 124.42 (4)°, while the S—Cu—S angle is 121.51 (4)°. The two imidazole rings are almost parallel, making a dihedral angle of 2.1 (2)°. In the crystal, the shortest C—H⋯Cl interactions stabilize a three-dimensional network with molecules linked into centrosymmetric dimers that are stacked along the b-axis direction.

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