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Crystal structure of (E)-4-{[2-(2,4-dinitrophenyl)hydrazin-1-ylidene]methyl}-3-methyl-1-phenyl-5-(1H-pyrrol-1-yl)-1H-pyrazole
The title compound, C(21)H(17)N(7)O(4), is in an ‘extended’ conformation aided by an intramolecular N—H⋯O hydrogen bond. The pyrazole ring makes dihedral angles of 29.17 (6), 65.47 (4) and 9.91 (7)°, respectively, with the phenyl, pyrrole and benzene rings. In the crystal, molecules are connected...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257438/ https://www.ncbi.nlm.nih.gov/pubmed/25553024 http://dx.doi.org/10.1107/S1600536814024039 |
Sumario: | The title compound, C(21)H(17)N(7)O(4), is in an ‘extended’ conformation aided by an intramolecular N—H⋯O hydrogen bond. The pyrazole ring makes dihedral angles of 29.17 (6), 65.47 (4) and 9.91 (7)°, respectively, with the phenyl, pyrrole and benzene rings. In the crystal, molecules are connected by pairs of N—H⋯O and C—H⋯O hydrogen bonds, forming inversion dimers which associate into ribbons running along the b axis through complementary C—H⋯O interactions. |
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