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Definitive crystal structure of 1,1′-bis[1,2-dicarba-closo-dodecaborane(11)]
In the title compound, C(4)H(22)B(20), the two {1,2-closo-C(2)B(10)H(11)} cages are linked across a centre of inversion with a C—C distance of 1.5339 (11) Å. By careful analysis of the structure, it is established that the non-linking cage C atom is equally disordered over cage vertices 2 and 3....
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257441/ https://www.ncbi.nlm.nih.gov/pubmed/25552965 http://dx.doi.org/10.1107/S1600536814023897 |
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| author | Man, Wing Y. Rosair, Georgina M. Welch, Alan J. |
| author_facet | Man, Wing Y. Rosair, Georgina M. Welch, Alan J. |
| author_sort | Man, Wing Y. |
| collection | PubMed |
| description | In the title compound, C(4)H(22)B(20), the two {1,2-closo-C(2)B(10)H(11)} cages are linked across a centre of inversion with a C—C distance of 1.5339 (11) Å. By careful analysis of the structure, it is established that the non-linking cage C atom is equally disordered over cage vertices 2 and 3. |
| format | Online Article Text |
| id | pubmed-4257441 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-42574412014-12-31 Definitive crystal structure of 1,1′-bis[1,2-dicarba-closo-dodecaborane(11)] Man, Wing Y. Rosair, Georgina M. Welch, Alan J. Acta Crystallogr Sect E Struct Rep Online Research Communications In the title compound, C(4)H(22)B(20), the two {1,2-closo-C(2)B(10)H(11)} cages are linked across a centre of inversion with a C—C distance of 1.5339 (11) Å. By careful analysis of the structure, it is established that the non-linking cage C atom is equally disordered over cage vertices 2 and 3. International Union of Crystallography 2014-11-05 /pmc/articles/PMC4257441/ /pubmed/25552965 http://dx.doi.org/10.1107/S1600536814023897 Text en © Man et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Man, Wing Y. Rosair, Georgina M. Welch, Alan J. Definitive crystal structure of 1,1′-bis[1,2-dicarba-closo-dodecaborane(11)] |
| title | Definitive crystal structure of 1,1′-bis[1,2-dicarba-closo-dodecaborane(11)] |
| title_full | Definitive crystal structure of 1,1′-bis[1,2-dicarba-closo-dodecaborane(11)] |
| title_fullStr | Definitive crystal structure of 1,1′-bis[1,2-dicarba-closo-dodecaborane(11)] |
| title_full_unstemmed | Definitive crystal structure of 1,1′-bis[1,2-dicarba-closo-dodecaborane(11)] |
| title_short | Definitive crystal structure of 1,1′-bis[1,2-dicarba-closo-dodecaborane(11)] |
| title_sort | definitive crystal structure of 1,1′-bis[1,2-dicarba-closo-dodecaborane(11)] |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257441/ https://www.ncbi.nlm.nih.gov/pubmed/25552965 http://dx.doi.org/10.1107/S1600536814023897 |
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