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Crystal structure of 2-hydroxyimino-2-(pyridin-2-yl)-N′-[1-(pyridin-2-yl)ethylidene]acetohydrazide
The molecule of the title compound, C(14)H(13)N(5)O(2), is approximately planar (r.m.s deviation for all non-H atoms = 0.093 Å), with the planes of the two pyridine rings inclined to one another by 5.51 (7)°. The oxime group is syn to the amide group, probably due to the formation of an intramolec...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257442/ https://www.ncbi.nlm.nih.gov/pubmed/25552998 http://dx.doi.org/10.1107/S1600536814025793 |
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author | Plutenko, Maxym O. Lampeka, Rostislav D. Haukka, Matti Nordlander, Ebbe |
author_facet | Plutenko, Maxym O. Lampeka, Rostislav D. Haukka, Matti Nordlander, Ebbe |
author_sort | Plutenko, Maxym O. |
collection | PubMed |
description | The molecule of the title compound, C(14)H(13)N(5)O(2), is approximately planar (r.m.s deviation for all non-H atoms = 0.093 Å), with the planes of the two pyridine rings inclined to one another by 5.51 (7)°. The oxime group is syn to the amide group, probably due to the formation of an intramolecular N—H⋯N hydrogen bond that forms an S(6) ring motif. In the crystal, molecules are linked by pairs of bifurcated O—H⋯(O,N) hydrogen bonds, forming inversion dimers. The latter are linked via C—H⋯O and C—H⋯N hydrogen bonds, forming sheets lying parallel to (502). The sheets are linked via π–π stacking interactions [inter-centroid distance = 3.7588 (9) Å], involving the pyridine rings of inversion-related molecules, forming a three-dimensional structure. |
format | Online Article Text |
id | pubmed-4257442 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42574422014-12-31 Crystal structure of 2-hydroxyimino-2-(pyridin-2-yl)-N′-[1-(pyridin-2-yl)ethylidene]acetohydrazide Plutenko, Maxym O. Lampeka, Rostislav D. Haukka, Matti Nordlander, Ebbe Acta Crystallogr Sect E Struct Rep Online Research Communications The molecule of the title compound, C(14)H(13)N(5)O(2), is approximately planar (r.m.s deviation for all non-H atoms = 0.093 Å), with the planes of the two pyridine rings inclined to one another by 5.51 (7)°. The oxime group is syn to the amide group, probably due to the formation of an intramolecular N—H⋯N hydrogen bond that forms an S(6) ring motif. In the crystal, molecules are linked by pairs of bifurcated O—H⋯(O,N) hydrogen bonds, forming inversion dimers. The latter are linked via C—H⋯O and C—H⋯N hydrogen bonds, forming sheets lying parallel to (502). The sheets are linked via π–π stacking interactions [inter-centroid distance = 3.7588 (9) Å], involving the pyridine rings of inversion-related molecules, forming a three-dimensional structure. International Union of Crystallography 2014-11-29 /pmc/articles/PMC4257442/ /pubmed/25552998 http://dx.doi.org/10.1107/S1600536814025793 Text en © Plutenko et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Plutenko, Maxym O. Lampeka, Rostislav D. Haukka, Matti Nordlander, Ebbe Crystal structure of 2-hydroxyimino-2-(pyridin-2-yl)-N′-[1-(pyridin-2-yl)ethylidene]acetohydrazide |
title | Crystal structure of 2-hydroxyimino-2-(pyridin-2-yl)-N′-[1-(pyridin-2-yl)ethylidene]acetohydrazide |
title_full | Crystal structure of 2-hydroxyimino-2-(pyridin-2-yl)-N′-[1-(pyridin-2-yl)ethylidene]acetohydrazide |
title_fullStr | Crystal structure of 2-hydroxyimino-2-(pyridin-2-yl)-N′-[1-(pyridin-2-yl)ethylidene]acetohydrazide |
title_full_unstemmed | Crystal structure of 2-hydroxyimino-2-(pyridin-2-yl)-N′-[1-(pyridin-2-yl)ethylidene]acetohydrazide |
title_short | Crystal structure of 2-hydroxyimino-2-(pyridin-2-yl)-N′-[1-(pyridin-2-yl)ethylidene]acetohydrazide |
title_sort | crystal structure of 2-hydroxyimino-2-(pyridin-2-yl)-n′-[1-(pyridin-2-yl)ethylidene]acetohydrazide |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257442/ https://www.ncbi.nlm.nih.gov/pubmed/25552998 http://dx.doi.org/10.1107/S1600536814025793 |
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