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Crystal structure of 2-hy­droxy­imino-2-(pyridin-2-yl)-N′-[1-(pyridin-2-yl)ethyl­idene]acetohydrazide

The mol­ecule of the title compound, C(14)H(13)N(5)O(2), is approximately planar (r.m.s deviation for all non-H atoms = 0.093 Å), with the planes of the two pyridine rings inclined to one another by 5.51 (7)°. The oxime group is syn to the amide group, probably due to the formation of an intra­molec...

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Autores principales: Plutenko, Maxym O., Lampeka, Rostislav D., Haukka, Matti, Nordlander, Ebbe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257442/
https://www.ncbi.nlm.nih.gov/pubmed/25552998
http://dx.doi.org/10.1107/S1600536814025793
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author Plutenko, Maxym O.
Lampeka, Rostislav D.
Haukka, Matti
Nordlander, Ebbe
author_facet Plutenko, Maxym O.
Lampeka, Rostislav D.
Haukka, Matti
Nordlander, Ebbe
author_sort Plutenko, Maxym O.
collection PubMed
description The mol­ecule of the title compound, C(14)H(13)N(5)O(2), is approximately planar (r.m.s deviation for all non-H atoms = 0.093 Å), with the planes of the two pyridine rings inclined to one another by 5.51 (7)°. The oxime group is syn to the amide group, probably due to the formation of an intra­molecular N—H⋯N hydrogen bond that forms an S(6) ring motif. In the crystal, mol­ecules are linked by pairs of bifurcated O—H⋯(O,N) hydrogen bonds, forming inversion dimers. The latter are linked via C—H⋯O and C—H⋯N hydrogen bonds, forming sheets lying parallel to (502). The sheets are linked via π–π stacking inter­actions [inter-centroid distance = 3.7588 (9) Å], involving the pyridine rings of inversion-related mol­ecules, forming a three-dimensional structure.
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spelling pubmed-42574422014-12-31 Crystal structure of 2-hy­droxy­imino-2-(pyridin-2-yl)-N′-[1-(pyridin-2-yl)ethyl­idene]acetohydrazide Plutenko, Maxym O. Lampeka, Rostislav D. Haukka, Matti Nordlander, Ebbe Acta Crystallogr Sect E Struct Rep Online Research Communications The mol­ecule of the title compound, C(14)H(13)N(5)O(2), is approximately planar (r.m.s deviation for all non-H atoms = 0.093 Å), with the planes of the two pyridine rings inclined to one another by 5.51 (7)°. The oxime group is syn to the amide group, probably due to the formation of an intra­molecular N—H⋯N hydrogen bond that forms an S(6) ring motif. In the crystal, mol­ecules are linked by pairs of bifurcated O—H⋯(O,N) hydrogen bonds, forming inversion dimers. The latter are linked via C—H⋯O and C—H⋯N hydrogen bonds, forming sheets lying parallel to (502). The sheets are linked via π–π stacking inter­actions [inter-centroid distance = 3.7588 (9) Å], involving the pyridine rings of inversion-related mol­ecules, forming a three-dimensional structure. International Union of Crystallography 2014-11-29 /pmc/articles/PMC4257442/ /pubmed/25552998 http://dx.doi.org/10.1107/S1600536814025793 Text en © Plutenko et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Plutenko, Maxym O.
Lampeka, Rostislav D.
Haukka, Matti
Nordlander, Ebbe
Crystal structure of 2-hy­droxy­imino-2-(pyridin-2-yl)-N′-[1-(pyridin-2-yl)ethyl­idene]acetohydrazide
title Crystal structure of 2-hy­droxy­imino-2-(pyridin-2-yl)-N′-[1-(pyridin-2-yl)ethyl­idene]acetohydrazide
title_full Crystal structure of 2-hy­droxy­imino-2-(pyridin-2-yl)-N′-[1-(pyridin-2-yl)ethyl­idene]acetohydrazide
title_fullStr Crystal structure of 2-hy­droxy­imino-2-(pyridin-2-yl)-N′-[1-(pyridin-2-yl)ethyl­idene]acetohydrazide
title_full_unstemmed Crystal structure of 2-hy­droxy­imino-2-(pyridin-2-yl)-N′-[1-(pyridin-2-yl)ethyl­idene]acetohydrazide
title_short Crystal structure of 2-hy­droxy­imino-2-(pyridin-2-yl)-N′-[1-(pyridin-2-yl)ethyl­idene]acetohydrazide
title_sort crystal structure of 2-hy­droxy­imino-2-(pyridin-2-yl)-n′-[1-(pyridin-2-yl)ethyl­idene]acetohydrazide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257442/
https://www.ncbi.nlm.nih.gov/pubmed/25552998
http://dx.doi.org/10.1107/S1600536814025793
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