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Crystal structure of bis{2,4-di-tert-butyl-6-[(isopropylimino)methyl]phenolato-κ(2) N,O}zinc dichloromethane monosolvate
In the title compound, [Zn(C(18)H(28)NO)(2)]·CH(2)Cl(2), the Zn(II) atom is N,O-chelated by two crystallographically independent salicylaldehyde imine ligands, leading to a distorted tetrahedral coordination sphere. The dihedral angle between the planes of the two metallacycles is 88.69 (6)°. Intr...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257443/ https://www.ncbi.nlm.nih.gov/pubmed/25553004 http://dx.doi.org/10.1107/S1600536814022636 |
Sumario: | In the title compound, [Zn(C(18)H(28)NO)(2)]·CH(2)Cl(2), the Zn(II) atom is N,O-chelated by two crystallographically independent salicylaldehyde imine ligands, leading to a distorted tetrahedral coordination sphere. The dihedral angle between the planes of the two metallacycles is 88.69 (6)°. Intramolecular non-classical C—H⋯O hydrogen-bonding interactions are observed. In the crystal, the complex molecules stack into columns along the a axis. Dichloromethane solvent molecules are situated in the voids of this arrangement. |
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