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Crystal structure of bis­{2,4-di-tert-butyl-6-[(iso­propyl­imino)­meth­yl]phenolato-κ(2) N,O}zinc di­chloro­methane mono­solvate

In the title compound, [Zn(C(18)H(28)NO)(2)]·CH(2)Cl(2), the Zn(II) atom is N,O-chelated by two crystallographically independent salicyl­aldehyde imine ligands, leading to a distorted tetra­hedral coordination sphere. The dihedral angle between the planes of the two metallacycles is 88.69 (6)°. Intr...

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Detalles Bibliográficos
Autor principal: Hao, Yuan-Zeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257443/
https://www.ncbi.nlm.nih.gov/pubmed/25553004
http://dx.doi.org/10.1107/S1600536814022636
Descripción
Sumario:In the title compound, [Zn(C(18)H(28)NO)(2)]·CH(2)Cl(2), the Zn(II) atom is N,O-chelated by two crystallographically independent salicyl­aldehyde imine ligands, leading to a distorted tetra­hedral coordination sphere. The dihedral angle between the planes of the two metallacycles is 88.69 (6)°. Intra­molecular non-classical C—H⋯O hydrogen-bonding inter­actions are observed. In the crystal, the complex mol­ecules stack into columns along the a axis. Di­chloro­methane solvent mol­ecules are situated in the voids of this arrangement.